Primary fractionation of elements among iron meteorites

The primary fractionation process in iron meteorites is that responsible for the distribution of elements between the groups, most notably Ga and Ge, which show concentration ranges of 10³ and 10⁴ respectively. To investigate the cause of the primary fractionation, concentrations of 16 elements were converted to relative abundances by dividing the element/Ni ratio by the CI chondrite ratio. These abundances were plotted on logarithmic graphs with data for each group (except IB and IIICD) and each cluster of closely related anomalous irons averaged.Co, P, Au, As, Cu, Sb, Ge and Zn are positively correlated with Ga. For most groups (except IA, IC and IIAB) relative abundances of these elements tend to decrease from about 1 in approximately the order listed above. This is the expected order in which these elements will condense into Fe, Ni during equilibrium nebular condensation. Mean relative abundances of refractory elements in groups generally lie within a narrow range of 0.5–2, and are uncorrelated with Ga. Although the equilibrium model may be only a gross approximation, it suggests that most primary fractionation did occur during nebular condensation.The anomalous irons are essential for defining many of the primary fractionation trends. On several element-Ga graphs the displacements of the anomalous irons from the primary curves indicate that these irons experienced the same secondary fractionation process (probably fractional crystallization) that produced the trends within most groups. The anomalous irons appear to be samples from over 50 minor groups, which have similar histories to the 12 major groups.     

Chemical exchange during hydrothermal alteration of basalt by seawater—I. Experimental results for major and minor components of seawater

Fresh mid-ocean ridge basalt of varying crystallinity has been powdered and reacted with seawater and an artificial Na-K-Ca-Cl solution at 200–500°C and 500–1000 bar in sealed gold capsules. Water/rock mass ratios of 1–3 were used and durations ranged from 2 to 20 months.These time periods were sufficient for most elements to approach a steady-state concentration in solution which was determined by equilibrium with alteration minerals (Mg, SiO₂, SO₄), by rate of formation of these minerals (Na, Ca), or by depletion from the rock (K, B, Ba). The resulting solutions closely resemble the brines from the basalt-seawater geothermal system at Reykjanes, Iceland. Mg was almost completely removed from seawater into the alteration products smectite, tremolite-actinolite, or talc. Sulfate also was removed to low concentrations, both by precipitation of anyhydrite and by reduction to sulfide. Net transfer of Na from seawater into solids occurred in most experiments by formation of sodic feldspar and possibly analcime. Sr was removed from seawater in some experiments but showed no change or a small gain in others. SiO₂, Ca, K, Ba, B and CO₂ were leached from basalt and enriched in solution. SiO₂ concentrations were controlled by saturation with quartz at 300°C and above. The principal Ca-bearing phases which formed were anhydrite, the hydrated Ca-silicate truscottite, tremolite-actinolite, and possibly wairakite. No K-rich phases formed. For some minerals the crystallinity of the starting basalt affected the amount which formed.Removal of Mg from seawater into solid alteration products occurred rapidly and was balanced largely by leaching of Ca from basalt. Net transfer of Na from seawater into solids occurred more slowly and was balanced mainly by leaching of additional Ca from basalt. Thus, reaction between seawater and basalt at low water/rock ratios can be considered to consist of two exchanges: Mg for Ca, and Na for Ca.     

Determination of the sources and circulation paths of thermal fluids: the Abano region,northern Italy

Water samples from natural springs and artesian wells in the Abano region of northern Italy are characterized by anomalous temperatures and compositions. Concentrations of major components and oxygen isotopes in samples of these fluids have been interpreted in the context of the regional geologic environment, circulation of groundwaters, and reactions between rocks and circulating groundwaters. These considerations define sourceregions and pathlines of the groundwaters.Circulation of fluids in the Abano region is interpreted to be the result of meteoric water infiltration into outcrops of Permian and Mesozoic aquifers in the pre-Alps, which lie north of the Abano region. These aquifers have southerly dips and, therefore, extend under the Abano region at depths between 0.5 and 2.5 km. This aquifer geometry is conducive to forced convection both of aqueous ions derived from the evaporate, limestone and dolomite bearing formations, and of thermal energy along flow paths which extend from the outcrops in the sourceregions to depths of 2 km below the Abano region and upward along high angle faults to thermal springs. Local variation in compositions of water samples is consistent with the mixing of local meteoric waters and formation fluids that were ultimately derived from Alpine sources.     

Effective temperatures,radii and bolometric magnitudes of Ap and Am stars

The effective temperatures radii and bolometric magnitudes of Ap, Am and normal A stars have been estimated from their energy distribution curves between 478 nm and 680 nm. All the Am stars and one Ap star (i.e. CrB) were found to be affected by line blanketing, a rough estimation of which in the respective (B-V) colours has been found out in each case.The range in effective temperature is 0.45–0.60 in terms of (=5040/T _e), while it is 1.8–4.8R in the case of radius, that in bolometric magnitude being from-0^m.67 to+1^m.61. An approximate estimate of the masses shows that they are between 1.5 and 3.0M . All these estimates are in agreement with those of the normal A stars. The Ap and Am stars are found to be slightly evolved and, therefore, are probably in the hydrogen shell-burning phase.     

Photoelectron fluxes in cometary atmospheres

The photoelectron fluxes in cometary atmospheres are calculated by a Monte Carlo method. This is the first quantitative model calculation of this kind. A pure H₂O atmosphere is assumed with a sublimation rate of 10³⁰ molecules sec^?1 at 1 AU. Discussions of the energetics of electron gas and of the elementary collisional processes in determining the fluxes largely concern this water atmosphere. Influences on the photoelectron fluxes are also investigated for CO, another possible constituent. The excitation rate of the ${}^1\text{D}$ level of atomic oxygen in electron impacts is evaluated. It is highly improbable that the photoelectrons are responsible for the observed 6300 Å emission of the order of 1 kR at a heliocentric distance of 1 AU. The structure of the heat equation for thermal electrons is analyzed and a drastic change of the plasma behavior within the coma region is expected.     

Reflectance spectra for sodium and potassium doped ammonia frosts: Implications for Io's surface

This paper reports measurements of the reflection spectra of sodium and potassium doped ammonia frosts as a function of alkali metal concentration which cover the wavelength range 0.35–2.5 μm. The purpose of the measurements was to determine whether or not the reflection spectra for such a solid was compatible with the spectral albedo of Io. The data show that with a sufficiently large alkali metal concentration, the reflection spectra of the doped ammonia frost do not display the characteristic ammonia features at 2.0 and 2.25 μm. The high reflectance of the more concentrated samples and the character of the observed reflection spectrum make it difficult to rule out sodium doped ammonia frost as a surface constituent on Io on the basis of existing data.     

Formation of whistler ducts

A theory of whistler duct formation is presented. By means of order of magnitude calculations it is shown that, when the ring current overlaps the outer plasmasphere, irregularities will cause field-aligned currents to flow, which are below the threshold sensitivity of satellite-borne magnetometers. These currents must be continuous with horizontal ionospheric currents, which produce horizontal electric fields. These fields map up to the equatorial plane and are large enough to produce flux tube interchange and hence the formation of whistler ducts in the outer plasmasphere.     

Linear force-free fields in the lower corona

We have computed the surface Green's function for linear force-free magnetic fields, where × B = B and is a constant, for application to low coronal levels of the solar atmosphere. Boundary conditions are imposed on the normal component of B on two parallel planes which delineate the force-free volume. This procedure ensures that the magnetic field energy remains bounded, and that the field lines have a smooth behavior. A simple bipolar source distribution is treated and representative field line tracings are shown.     

Observations of coronal polarization at the solar eclipse of 7 March, 1970

Polarigraphic observations of the 7 March, 1970 eclipse were made at Miahuatlán (Mexico) with a camera of 120 cm focal length. A polarizing filter in front of the objective could be adjusted at 8 different positions, 22.5° apart. Reduction of eight photographs of the white light corona yields polarization at 72 position angles and from r = 1.1 up to 2.1. High polarization which cannot be explained with Thomson scattering was not observed. An analysation of the measuring accuracy shows, that it is not possible to determine exactly the direction of polarization in the outer corona with the classical method of measuring polarization with a small number of photographs. The coronal hole in the south-west quadrant is analysed. The low intensity and polarization can be explained by a hole with an extent in longitude between 1 and 2 times its extent in latitude and with a minimum electron density between 0 and 0.3 of that outside the hole.Astronomische Mitteilungen der Eidgenössischen Sternwarte Zürich, No. 347.