The Potential for Environmentally Sound Development of Marine Deposits of Potassic and Phosphatic Minerals Offshore, Southern Africa

Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits.     

Effects of organic toxicants on the anoxic energy metabolism of the mussel Mytilus edulis

The anoxic rates of heat dissipation by mussels (Mytilus edulis) were enhanced after exposure to pentachlorophenol (PCP) and tributyltin (TBT), both known uncouplers of oxidative phosphorylation. The degree of metabolic activation under anoxia was dependent upon the amount of toxicant accumulated in the tissues, but the concentration-response relationship was different to that under aerobic conditions. Biochemical measurements indicated that the anaerobic metabolic pathways were significantly disturbed by PCP and TBT. There was a decline in succinate, an increase in the fumarate: succinate ratio, and an increase in the accumulation of lactate, indicating a shift from succinate to lactate anaerobic pathways. A consequence of organic toxicant exposure was a reduction in anoxic survival time of mussels.     

Incorporating Māori values into land management decision tools

ABSTRACT

Environmental sustainability and the long-term wellbeing of Māori (the indigenous people of New Zealand) are interdependent and degradation of landscapes risks the progressive degradation of Māori wellbeing. The present study developed an analysis framework based on Ki Uta Ki Tai (holistic-mountains to the sea- management philosophy advocated by Ngāi Tahu) for exploring relationships between landcover and Māori values to enable predictions of cultural values through space and time. We used this framework to predict how two Māori values (Overall Health and Cultural Land Use) have been altered as a result of landcover change between 2001–2012 in three Canterbury catchments. The area of native vegetation declined while exotic pasture increased between 2001–2012, and there were corresponding declines in both cultural health scores. These results suggest that the change in landcover has reduced the ability of the landscape to support Māori values. This framework for assessing changes in Māori values with respect to changing environmental conditions may identify opportunities for Māori to better engage in land use management decisions.     

Standard facies models to incorporate all heterogeneity levels in a reservoir model

The construction of reservoir models is frustrated by the fact that core and well cover only a fraction of the reservoir volume and it is therefore difficult to determine features like facies shape, -size, and -distribution, inter- and intra-facies boundaries and lateral trends from them. These features are, however, critical to fluid flow and they should necessarily be incorporated in the reservoir model and we therefore propose to systematically describe geometry and distribution of facies. To this end we make use of “standard facies models” that a priori contain all elements and boundaries of facies for a number of typical depositional environments.     

The effect of low level supplementary heating on diving duration

The exothermic reaction which proceeds when small sachets containing particulate mixtures of iron and magnesium are flooded with sea water, has been used for thermal support of free divers. Initial application of such generators to heating of the hands (Burton and Chan, 1981), and later extension to heating of the torso, have been described previously (Chan and Burton, 1981, 1982). Of considerable interest during field trials of the torso heating system was a strong subjective impression among those taking part, that significant increases of dive duration and decreases of perceived discomfort could be obtained with relatively low levels of power generation, for example less than 50% of that required for thermal balance. In this paper, a simple mathematical model of human stored heat loss is used to rationalize this observation. Also it successfully predicts voluntary exposure times of unheated divers who become cold. When used to estimate body heat debt, the model enables documented dives by this laboratory and by others, including recent exposures in Antarctica using low level supplementary heating, to be analysed.     

Semisubmersible response to transient ice forces

The paper presents an analytical and experimental study on the transient response of semisubmersibles to bergybit impact and the strength of bergybit ice to high strain-rate loadings. Two approaches have been proposed for the solution of the semisubmersible-bergybit interaction problem, one using the energy approach and the other using the conventional structural dynamics approach with initial velocity conditions. In addition the local behaviour of the impacted regions have been analysed for deformation and failure. Numerical results have been given for local behaviour of an impacted column and global behaviour of semisubmersible-bergybit system. Experimental study has been reported on the impact strength of iceberg ice at strain rates of 10⁻³, 10⁻² and 10⁻¹; the indentation impact strength of ice is found to be 3–4 times the unaixial compressive strength, at the same strain rate.     

Parallel experiments with Thalassiosira rotula in outdoor plastic tanks: Development of dissolved free amino acids during an algae bloom

Three outdoor plastic tanks were filled with North Sea water. The water was filtered free of algae and inoculated with the diatom Thalassiosira rotula. Under nearly natural nutrient supply an exponential plankton growth occurred with realistic cell concentrations. The flexible tanks (3–4 m³, 4–5 m deep) were exposed in the German Bight at a station in the outer harbour of Helgoland. The concentration changes of dissolved free amino acids (DFAA) were determined. The direct determination method applied permitted an analysis in picomole range without loss and with good reproducibility. The preliminary concentration of DFAA amounted to 0.2 μmol dm⁻³ in all three cultures, increasing during the development of T. rotula to 0.9–1.3 μmol dm⁻³ and decreasing in the stationary phase back again to smaller values. A high degree of temporal variation in DFAA was observed in all three cultures. In spite of these rapid changes in concentration, a good parallel development could be shown for all cultures, which extended as far as the spectra of the amino acids. Relationships between DFAA and other parameters of the culture-systems were examined.     

Effect of native and invasive cordgrass on Macoma petalum density, growth, and isotopic signatures

Ecosystem engineers can influence community and ecosystem dynamics by controlling resources, modifying the flow of energy or biomass, or changing physical characteristics of the habitat. Invasive hybrid cordgrass (Spartina alterniflora × Spartina foliosa) is an ecosystem engineer in salt marshes in San Francisco Bay, California, U.S.A. that raises intertidal elevations and may be either increasing C₄ plant carbon input into food webs or tying up carbon in a form that is not usable by consumers. A manipulative experiment compared abundance, growth, and stable isotope (δ¹³C and δ¹⁵N) composition of the clam Macoma petalum (=M. balthica) among native marsh, hybrid Spartina, and mudflats in central San Francisco Bay. We found higher densities (individuals m⁻²) of M. petalum on mudflats compared to either native or hybrid Spartina (p < 0.001). Macoma petalum shell growth was significantly greater in mudflats than in either vegetation type in 2002 (p = 0.005) but not 2003. Differences in shell growth between native and hybrid Spartina were not significant. Stable isotope results showed differences between habitats in δ¹³C but not δ¹⁵N. Carbon signatures of M. petalum placed in Spartina were much more depleted than the isotopic signature of Spartina. Neither native nor hybrid Spartina appears to be a significant carbon source for M. petalum in San Francisco Bay, and we found no evidence that hybrid Spartina contributes carbon to M. petalum beyond what is provided by S. foliosa, despite the hybrid's much greater biomass. Our results show that loss of mudflat habitat, rather than increased input of C₄ carbon, is the greatest effect of the invasion of hybrid Spartina on M. petalum.