Plate tectonic model for the oligo-miocene evolution of the western Mediterranean

This paper outlines a plate tectonic model for the Oligo-Miocene evolution of the western Mediterranean which incorporates recent data from several tectonic domains (Corsica, Sardinia, the Kabylies, Balearic promontory, Iberia, Algero-Provençal Basin and Tunisian Atlas). Following late Mesozoic anticlockwise rotation of the Iberian peninsula (including the Balearic promontory and Sardinia), late Eocene collision occurred between the Kabylies and Balearic promontory forming a NE-trending suture with NW-tectonic polarity. As a result of continued convergence between the African and European plates, a polarity flip occurred and a southward-facing trench formed south of the Kabylie—Balearic promontory suture. During late Oligocene time an E-W-trending arc and marginal basin developed behind the southward-facing trench in the area of the present-day Gulf of Lion. Opening of this basin moved the Corsica—Sardinia—Calabria—Petit Kabylie—Menorca plate southward, relative to the African plate. Early Miocene back-arc spreading in the area between the Balearic promontory and Grand Kabylie emplaced the latter in northern Algeria and formed the South Balearic Basin. Coeval with early Miocene back-arc basin development, the N-S-extension in the Gulf of Lion marginal basin changed to a more NW-SE direction causing short-lived extension in the area of the present-day Valencia trough and a 30° anticlockwise rotation of the Corsica-Sardinia-Calabria—Petit Kabylie plate away from the European plate. Early—middle Miocene deformation along the western Italian and northeastern African continental margins resulted from this rotation. During the early late Miocene (Tortonian), spreading within a sphenochasm to the southwest of Sardinia resulted in the emplacement of Petit Kabylie in northeastern Algeria.     

Trace element behavior in the zoned metasomatic bodies of Unst,Shetland

An earlier investigation of metasomatic alteration (Curtis and Brown, 1969) is extended to trace element distribution. Most element profiles may be linked simply with diffusive mixing. Between element differentiation is slight, but certain elements are selectively concentrated in particular mineral phases.Trace elements never exhibit the spectacular unmixing shown by some major elements as monomineralic zones develop. Local equilibrium considerations still contribute materially to an understanding of overall behavior.     

Paleosols and the forest border in Keewatin,N.W.T.

The morphology of paleosols and radiocarbon-dated charcoal from buried surface horizons of soils provide evidence to suggest that between periods of northward forest encroachment tundra climate has dominated areas at least 50 km south of the present forest/tundra border in southwest Keewatin. The present forest/tundra border climate is nearly as severe as any climate that has prevailed in the area since deglaciation.     

Three-dimensional geologic modeling and visualization of the Virttaankangas aquifer,southwestern Finland

A need exists for a reliable and long-term water supply for the 285,000 inhabitants of the Turku area in southwestern Finland. In response to this need, there are plans to replace the present water supply from the surface sources with artificially infiltrated groundwater from a Quaternary esker aquifer called the Virttaankangas aquifer. New sedimentological studies of the Virttaankangas area have revealed the complexities of the esker system and its surrounding glacial, glaciofluvial, and glaciolacustrine geology. This led to the characterization of the hydrogeological units of the aquifer, the result of which has been a three-dimensional (3-D) truly integrated solids model that represents the geometry, interrelationships, and hydrostratigraphy of the study area. The 3-D model was made with EarthVision geologic modeling software. The 3-D geological model of the Virttaankangas aquifer can be used for planning the infiltration of river water into the aquifer and to understand the geologic and geographic boundaries of the hydrogeologic units hosting the groundwater reserve and the geologic relationships between the units. Another major outcome of this study is a powerful visualization tool that will be provided to municipal and government authorities who must understand the geologic complexities involved with water-resource planning prior to their decision making. Electronic Publication     

Impact of high herbivore densities on introduced smooth cordgrass,Spartina alterniflora,invading San Francisco Bay,California

Spartina alterniflora, smooth cordgrass, invading San Francisco Bay, California (USA), is attacked by high densities of a plant hopper, Prokelisia marginata, and a mirid bug, Trigonotylus uhleri. Both herbivores are sap-feeders. We investigated the impact of these herbivores on S. alterniflora's growth rate, vegetative spread, and seed production by manipulating herbivore densities in the field and in a greenhouse. Herbivore densities in the field peaked in early fall, with P. marginata averaging more than 300 individuals per mature culm of S. alterniflora (about 100,000 per m²) and T. uhleri densities exceeding 10 per culm (about 3,000 per m²). Field reductions of herbivore densities by approximately 70% with insecticidal soap did not result in greater vegetative growth rates or lateral spread of plants; plants grew vigorously with the highest densities of insects. In the greenhouse study, conducted with seedlings, herbivory significantly reduced plant mass and tiller number in some but not all replicate herbivory treatments. In both field and greenhouse, there were significant differences between some clones' growth rates independent of herbivory. Inflorescence production in the field was not affected by reduced-herbivory treatments. Seed set was low under conditions of both natural and reduced herbivory, averaging 0.4%. Despite densities of P. marginata and T. uhleri that are much higher than typically observed in areas where S. alterniflora is native, herbivory by these particular insects appears to have little impact and in unlikely to limit S. alterniflora’s spread through San Francisco Bay. *** DIRECT SUPPORT *** A01BY070 00009     

Kerogen-mineral reactions at raised temperatures in the presence of water

Kerogen has been artificially matured under “hydrous pyrolysis” conditions in the presence of various minerals in order to investigate the influence of the latter on the organic products. In addition to three clay minerals (montmorillonite, illite, kaolinite), calcium carbonate and limonite were also employed as inorganic substrates. Kerogen (Type II) isolated from the Kimmeridge Blackstone band was heated in the presence of water and a 20-fold excess of mineral phase at two different temperatures (280 and 330°C) for 72 hr. Control experiments were also carried out using kerogen and water only and kerogen under anhydrous conditions. This preliminary study describes the bulk composition of the pyrolysates with detailed analyses of the aliphatic hydrocarbon distributions being provided by gas chromatography and combined gas chromatography-mass spectrometry.In the 280°C experiments, considerably more organic-soluble pyrolysate (15% by weight of original kerogen) was produced when calcium carbonate was the inorganic phase. At 330°C, all samples generated much greater amounts of organic-soluble products with calcium carbonate again producing a large yield (40% wt/wt). Biomarker epimerisation reactions have also proceeded further in the 330°C pyrolysate formed in the presence of calcium carbonate than with other inorganic phases. Implications of these and other observations are discussed.     

Mechanisms for Organic Matter and Phosphorus Burial in Sedimentsof a Shallow, Subtropical, Macrophyte-Dominated Lake

We studied the role that submersed aquatic vegetation (SAV) plays in the sedimentation of organic matter (OM) and phosphorus (P) in Lake Panasoffkee, Florida (USA), a shallow, hard-water, macrophyte-dominated water body. Carbon/Nitrogen ratios (C/N) and stable isotope signatures (δ¹³C and δ¹⁵N) in algae, higher plants, and surface sediments were measured to identify sources of OM to the lake mud. Pollen, plant macrofossils, and geochemistry in sediment cores indicated that primary productivity and SAV abundance in Lake Panasoffkee increased in the late 1800s, probably as a response to increased P loading from human settlement and forest clearance. SAV and associated periphyton served as temporary sinks for soluble P, maintaining relatively clear-water, low-nutrient conditions in the lake. P accumulation in Lake Panasoffkee sediments increased together with indicators for greater SAV presence. This suggests that SAV and associated epiphytes promote P burial and retention in sediments. Although it might be assumed that rooted submersed macrophytes are directly responsible for P uptake from water and transfer to sediments, C/N and stable carbon isotope results argue for the importance of other macrophyte growth forms, and perhaps epiphytic algae, in permanent OM and P sequestration. For instance, high rates of photosynthesis by epiphytes in hard-water systems consume CO₂ and promote CaCO₃ precipitation. Sloughing of accumulated carbonates from macrophyte leaves transfers epiphytes and associated P to the sediment. Our paleolimnological findings are relevant to restoration efforts in the Florida Everglades and support the claim that constructed SAV wetlands remove P from waters effectively.