The Impact of Sediment and Carbon Fluxes on the Biogeochemistry of Methane and Sulfur in Littoral Baltic Sea Sediments (Himmerfjärden, Sweden)

Three sediment stations in Himmerfjärden estuary (Baltic Sea, Sweden) were sampled in May 2009 and June 2010 to test how low salinity (5–7 ‰), high primary productivity partially induced by nutrient input from an upstream waste water treatment plant, and high overall sedimentation rates impact the sedimentary cycling of methane and sulfur. Rates of sediment accumulation determined using ²¹⁰Pb_excess and ¹³⁷Cs were very high (0.65–0.95 cm?year^?1), as were the corresponding rates of organic matter accumulation (8.9–9.5 mol C?m^?2?year^?1) at all three sites. Dissolved sulfate penetrated <20 cm below the sediment surface. Although measured rates of bicarbonate methanogenesis integrated over 1 m depth were low (0.96–1.09 mol?m^?2?year^?1), methane concentrations increased to >2 mmol?L^?1 below the sulfate–methane transition. A steep gradient of methane through the entire sulfate zone led to upward (diffusive and bio-irrigative) fluxes of 0.32 to 0.78 mol?m^?2?year^?1 methane to the sediment–water interface. Areal rates of sulfate reduction (1.46–1.92 mol?m^?2?year^?1) integrated over the upper 0–14 cm of sediment appeared to be limited by the restricted diffusive supply of sulfate, low bio-irrigation (α?=?2.8–3.1 year^?1), and limited residence time of the sedimentary organic carbon in the sulfate zone. A large fraction of reduced sulfur as pyrite and organic-bound sulfur was buried and thus escaped reoxidation in the surface sediment. The presence of ferrous iron in the pore water (with concentrations up to 110 μM) suggests that iron reduction plays an important role in surface sediments, as well as in sediment layers deep below the sulfate–methane transition. We conclude that high rates of sediment accumulation and shallow sulfate penetration are the master variables for biogeochemistry of methane and sulfur cycling; in particular, they may significantly allow for release of methane into the water column in the Himmerfjärden estuary.     

Settlement Prediction of Surcharge Preloaded Low Embankment on Soft Ground Subjected to Cyclic Loading

This article studies the effect of dynamic cyclic loading and surcharge preloading method on the post-construction settlement of low embankments. Soil samples obtained from the soft ground under an embankment were consolidated by surcharge preloading followed by static and dynamic cyclic loading in the odometer. The results show that the consolidation deformation of the soil samples is independent of the frequency of the dynamic cyclic loading, which was simulated to follow the half-sine wave, and this is consistent with the energy concept. The post-construction settlement increases with increasing amplitude of cyclic load and the effectiveness of surcharge preloading depends on the difference between magnitude of surcharge and amplitude of the cyclic load. Based on the consolidation theory combined with the test results, a formula has been proposed to compute the post-construction settlement of a low embankment under cyclic loading.     

Identification of anthropogenic radionuclides in the Song Hong (Red) and Song Da (Black) river basins of Vietnam

The concentration and distribution of U were measured in zircon samples separated from the streambed sediments collected at different sites along the rivers of northern Vietnam using semiconductor alpha spectrometry and alpha- and fission-track autoradiography. Based on the absolute U content and distribution, we distinguished two groups of zircon grains of different origin. Group 1 zircons have relatively low and uniform U contents ranging from 280 to 440 μg/g. Group 2 zircons are characterized by heterogeneous U distribution and U contents ranging from 490 to 2040μg/g. The determination of absolute alpha activity values and alpha spectrometric characteristics for a number of group 2 zircon grains indicated the presence of relatively short-lived alpha-emitters. These radionuclides are probably ²¹⁰Po, ²³²U, ²³⁶Pu, ²⁴¹Am, and ²⁴³Am, and all of them can originate exclusively from anthropogenic sources. A comparison of the observed alpha activity values for group 2 zircons with those of group 1 zircons and zircons separated from the suspended colloids in river water samples provided conclusive evidence for traces of anthropogenic radioactive contamination in the Lao Cai, Yen Bai, Tuyen Quang, Thac Ba, Viet Tri, and Hanoi streams flowing in the Song Hong (Red) and Song Da (Black) river basins of northern Vietnam and sourced in the southern regions of the neighboring state.