The Effects of Inner- and Outer-Layer Turbulence in a Convective Boundary Layer on the Near-Neutral Inertial Sublayer Over an Urban-Like Surface

A large-eddy simulation of the atmospheric boundary layer, large enough to contain both an urban surface layer and a convective mixed layer, was performed to investigate inner-layer and outer-layer scale motions. The objective was to determine the applicability of Monin–Obukhov similarity theory to inner-layer motions, to investigate the influence of outer-layer motions on surface-layer structure, as well as to assess the interaction of the two scales of motion. The urban surface roughness consisted of square-patterned cubic buildings of dimension H (40 m). A spatial filter was used to decompose the two scales in the inertial sublayer. The horizontal square filter of size 10H was effective in separating the inner-layer (surface-layer height ≈ 2 H) and outer-layer scales (boundary-layer height δ ≈ 30H), where the Reynolds stress contribution of the inner layer dominates in the logarithmic layer (depth 2H). Similarity coefficients for velocity fluctuations were successfully determined for inner-layer motions in the surface layer, proving the robustness of Monin–Obukhov similarity for surface-layer turbulence. The inner-layer structures exhibit streaky structures that have similar streamwise length but narrower spanwise width relative to the streamwise velocity fluctuation field, consistent with observations from an outdoor scale model. The outer-layer motions to some extent influence the location of ejections and sweeps through updraft and downdraft motions, respectively, thus, disturbing the homogeneity and similarity of inner-layer motions. Although the horizontal averages of the variances and covariance of motions reveal that the Reynolds stresses are dominated by inner-layer structures, the localized influence of the interaction of outer-layer horizontal and inner-layer vertical motions on the Reynolds stress is not insignificant.     

Biostratigraphy versus isotope geochronology: Testing the Urals island arc model

Formation of the Urals volcanic-hosted massive sulphide(VHMS) deposits is considered to be related with the intra-oceanic stage of island arc(s) development in the Upper Ordoviciane Middle Devonian based on the biostratigraphic record of ore-hosting sedimentary rocks. However, the direct Re-Os dating of four known VHMS systems in the Urals gives significantly younger Re-Os isochron ages ranging from355 ± 15 Ma up to 366 ± 2 Ma. To address this discrepancy, we performed SHRIMP U-Pb dating on zircons extracted from rhyodacites(Eifelian biostratigraphic age of 393 -388 Ma) from the footwall of the Alexandrinka VHMS deposit which has a Re-Os isochron age of sulphides of 355 ± 15 Ma.New ²⁰⁶ Pb/²³⁸ U mean age of 374 ± 3 Ma(MSWD ? 1.4 and probability ? 0.11) is considered to be the crystallisation age of the host volcanic rock. This age is ca. 15 Ma younger than the Eifelian(393 -388 Ma)biostratigraphic age and overlaps the Frasniane Famennian boundary(372 ± 2 Ma), characterised by the final stages of Magnitogorsk Arc e East European continent collision. Such an inconsistency with geochronological age may be due to a reburial of conodonts during resedimentation as a result of erosion of older rocks in younger sedimentary sequences.     

The impact of climatic and non-climatic factors on land surface temperature in southwestern Romania

Land surface temperature is one of the most important parameters related to global warming. It depends mainly on soil type, discontinuous vegetation cover, or lack of precipitation. The main purpose of this paper is to investigate the relationship between high LST, synoptic conditions and air masses trajectories, vegetation cover, and soil type in one of the driest region in Romania. In order to calculate the land surface temperature and normalized difference vegetation index, five satellite images of LANDSAT missions 5 and 7, covering a period of 26 years (1986–2011), were selected, all of them collected in the month of June. The areas with low vegetation density were derived from normalized difference vegetation index, while soil types have been extracted from Corine Land Cover database. HYSPLIT application was employed to identify the air masses origin based on their backward trajectories for each of the five study cases. Pearson, logarithmic, and quadratic correlations were used to detect the relationships between land surface temperature and observed ground temperatures, as well as between land surface temperature and normalized difference vegetation index. The most important findings are: strong correlation between land surface temperature derived from satellite images and maximum ground temperature recorded in a weather station located in the area, as well as between areas with land surface temperature equal to or higher than 40.0 °C and those with lack of vegetation; the sandy soils are the most prone to high land surface temperature and lack of vegetation, followed by the chernozems and brown soils; extremely severe drought events may occur in the region.     

Petrogenesis of the Paleoproterozoic basalt–andesite–rhyolite dyke association in the Carajás region, Amazonian craton

Paleoproterozoic basaltic, andesitic and rhyolitic dykes crosscut the Archaean Carajás basement. Basalts are distinguished into a high and a low TiO₂ group (HTi and LTi), each group consisting of geochemically distinct NE- and NW-trending swarms. The HTi dykes are evolved transitional basalts having essentially EMORB-type geochemistry. The LTi basalts are tholeiites (NE-trending swarm) and high-Al basalts (NW-trending swarm) displaying incompatible trace elements patterns with variably negative Nb anomaly, enrichment in Rb, Ba, K (LILE) and La, Ce and Nd (LREE) and positive Sr anomaly. With respect to orogenic analogues, andesites have lower Al₂O₃, CaO and Ni, higher FeO, LILE, LREE, Nb, Zr and Ti and negative Sr anomaly. Rhyolites have geochemical characteristics comparable with those of A-type granites. At 1.8 Ga, ranges from 0.700 to 0.705 in the HTi basalts and from 0.700 to 0.704 in the LTi group. Andesites define an isochron of 1874±110 Ma (Sr_o=0.7038±0.0010). Rhyolites from Southern and Northern Carajás define two isochrons of 1802±130 Ma (Sr_o=0.7062±0.0046) and 1535±82 Ga (Sr_o=0.7625) respectively, the younger date being interpreted as resetting of the Rb–Sr isotopic system. We propose a petrogenetic model relating LTi basalts with melting of lithospheric mantle metasomatized by acid melts derived from incipient melting of eclogites, representing in turn the subsolidus product of basaltic batches trapped in the mantle. The HTi basalts are explained by melting of the lithospheric mantle containing the complementary residual eclogite. Andesite petrogenesis is consistent with crystal fractionation from a high-Mg andesite parent derived from a mantle source more extensively metasomatized by eclogite-derived melts. Rhyolite composition is consistent with low melting degree of the basement rocks. The basalt–andesite–rhyolite dykes may represent the effects of crustal extension and arching in Carajás, which produced the anorogenic acid to intermediate magmatism (Uatumã group) and affecting a large part of the Amazon craton between 1.85 and 1.7 Ga.     

Primary Production and Growth Dynamics in Posidonia oceanica

Abstract. Studies on leaf growth and production were performed in two stands, at depths of 5 m and 22m, in the Posidonia oceanica (L.) D elile bed off Lacco Ameno, Ischia (Gulf of Naples). Experiments were carried out in situ from May 1988 to August 1989 at monthly intervals.
Leaf growth and production profiles differed in the two stands investigated. Growth rates were higher at 5 m, with a peak in autumn (5.8 mg · shoot^-1· d^-1) and another in March (3.8 mg · shoot^-1· d^-1). At 22 m the maximum rate occurred in May (3.9 mg · shoot^-1· d^-1). These differential growth rates resulted in a delayed maximum leaf surface and biomass at the deep stand, where lower irradiance values and different temperature patterns were also found. The biomass of epiphytic algae showed trends similar to those of leaves; however, there were remarkable differences in the values between the two stations and for the two investigated years.
The production data of the present study are compared with those of other reports, and it is shown that growth processes are greatly influenced by physical factors.     

Predicting twenty-first century recession of architectural limestone in European cities

Cities of the twenty-first century will expose buildings to environments that are quite different from those experienced over preceding periods. The recent reduction in sulfur dioxide in cities and continued pressure to lower the emissions of combustion generated pollutants creates a potential for climate induced deterioration, by contrast, to be more important. Given that climate will likely change over the next hundred years, recession rates of calcareous stones have been predicted for Oviedo (Spain), Paris and Prague over the period 1981–2099. This can give guidance as to the likely change in balance of future threat. The Lipfert, ICP, and MULTI-ASSESS functions were used to calculate recession from estimates of climate and air quality. It is likely that under a continued decline or stable levels of pollution, recession rates having reached low values will remain largely unchanged over the coming century, despite likely changes in climate. Although the functions adopted disagree in a quantitative sense, there is evidence that they were reasonably concordant in the last decades of the twentieth century. In a cleaner future their different underlying assumptions lead to poorer agreement.