Response of suspended sediment particle size distributions to changes in water chemistry at an Andean mountain stream confluence receiving arsenic rich acid drainage

Acid drainage is an important water quality issue in Andean watersheds, affecting the sustainability of urban, agricultural, and industrial activities. Mixing zones receiving acid drainage are critical sites where changes in pH and chemical environment promote the formation and dissolution of iron and aluminum oxy/hydroxides. These particles can significantly change the speciation of toxic metals and metalloids throughout drainage networks via sorption, desorption, and settling processes. However, little is known about the behavior of particle size distributions (PSDs) in streams affected by acid drainage and their relationship to metal speciation. This work studied: (a) the PSDs for a wide range of mixing ratios found at a fluvial confluence affected by acid drainage, and (b) the response of PSDs and arsenic speciation to environmental changes found when the particles approach complete mixing conditions. The confluence between the Azufre River (pH ~ 2, high concentration of dissolved metals) and Caracarani River (pH = 8.6, low concentration of dissolved metals) was used as a representative model for study. Field measurements show a bimodal PSD with modal diameters of ~50 and 300 μm. At shorter distances from the junction, the smaller modes with smaller particle volumes were dominant across the stream cross‐sections. A systematic shift towards larger particle sizes and larger particle volumes occurred downstream. The analysis of laboratory PSDs for Azufre/Caracarani mixing ratios between 0.01 and 0.5 (pH from 6.2 to 2.3) showed a bimodal trend with ~15 and 50 μm characteristic diameters; larger particles formed at pH>4. When particle suspensions were transferred in laboratory experiments from very low pH to full mixing conditions (pH ~ 2.8 and mixing ratio ~ 0.25) particle sizes varied, and the dissolved arsenic concentration decreased. The observed reaction kinetics were slow compared to the time scale of advective transport, creating opportunities for engineered controls for arsenic. This work contributes to a better understanding of the chemical‐hydrodynamic interactions in watersheds affected by mining, and identifying opportunities to improve water quality at points of use.     

Importance of mixotrophic nanoplankton in Aysén Fjord (Southern Chile) during austral winter

Mixotrophy, the combination of autotrophic and heterotrophic nutrition in the same organism, is widespread in planktonic algae. Several reports from temperate and high-latitude fjords in Scandinavia suggest the occurrence of a niche in late summer and autumn during post-bloom conditions in which mixotrophic algae can become important grazers in pelagic ecosystems, accessing the nutrients bound in their prey to overcome nutrient limitation. Here, we experimentally determined the trophic modes and bacterivory rates for the nanoplankton community (2–20 μm) in Aysén Fjord located in the Chilean Northern Patagonia during two contrasting seasons: winter and spring. While mixotrophic nanoplankton was virtually absent from the system in spring, in winter at occasions it even constituted the dominant trophic group of the nanoplankton with abundances of >900 cells mL^?1. This indicates a second niche for mixotrophs in winter, when mixotrophy allows overcoming light limitation.     

Assessing shallow landslide hazards using the TRIGRS and SHALSTAB models,Serra do Mar,Brazil

The hillslopes of the Serra do Mar, a system of escarpments and mountains that extend more than 1500 km along the southern and southeastern Brazilian coast, are regularly affected by heavy rainfall that generates widespread mass movements, causing large numbers of casualties and economic losses. This paper evaluates the efficiency of susceptibility mapping for shallow translational landslides in one basin in the Serra do Mar, using the physically based landslide susceptibility models SHALSTAB and TRIGRS. Two groups of scenarios were simulated using different geotechnical and hydrological soil parameters, and for each group of scenarios (A and B), three subgroups were created using soil thickness values of 1, 2, and 3 m. Simulation results were compared to the locations of 356 landslide scars from the 1985 event. The susceptibility maps for scenarios A1, A2, and A3 were similar between the models regarding the spatial distribution of susceptibility classes. Changes in soil cohesion and specific weight parameters caused changes in the area of predicted instability in the B scenarios. Both models were effective in predicting areas susceptible to shallow landslides through comparison of areas predicted to be unstable and locations of mapped landslides. Such models can be used to reduce costs or to define potentially unstable areas in regions like the Serra do Mar where field data are costly and difficult to obtain.     

Direct and Indirect pCO2 Measurements in a Wide Range of pCO2 and Salinity Values (The Scheldt Estuary)

Recent improvements in both Infra-red spectroscopy and equilibrator techniqueshave allowed to determine, for the first time, pCO₂using simultaneously and continuously both the direct and indirect methods in an estuary where pCO₂ values range from 500 to 8500 atm and salinity from 0 to 30. Our results show that both methods are in excellent agreement in the wholeestuary (r² = 0.999, n = 1075, p < 0.0001). Thus, the NBS (US National Bureau of Standards) scale, although inadequate for seawater samples, is appropriate for estuarine waters and can be applied with confidence to calculate pCO₂.     

Dynamical Properties of a Sample of Ellipticals

On the basis of Jeans equations we study some dynamical properties of a sample of E galaxies considered as oblate and prolate spheroids. Although the results emphasize the anisotropy as the dominant dynamical factor both for oblate and prolate configurations, the sample contains some oblate galaxies apparently isotropic consistent with full rotational support. Comparisons of the mass-to-luminosity ratios obtained from our models with ratios derived from recent evolutionary synthesis models do not seem to leave room for nonluminous matter within the ranges (of the order of one de Vaucouleurs' radius) of the kinematical observations. Such comparisons suggest that a flatter than the classical Salpeter IMF would lead to better agreement with the dynamical results obtained within the framework of our models.