A large epeiric methanogenic Bambuí sea in the core of Gondwana supercontinent?

Carbon isotope compositions of both sedimentary carbonate and organic matter can be used as key proxies of the global carbon cycle and of its evolution through time,as long as they are acquired from waters where the dissolved inorganic carbon(DIC)is in isotope equilibrium with the atmospheric CO2.However,in shallow water platforms and epeiric settings,the influence of local to regional parameters on carbon cycling may lead to DIG isotope variations unrelated to the global carbon cycle.This may be especially true for the terminal Neoproterozoic,when Gondwana assembly isolated waters masses from the global ocean,and extreme positive and negative carbon isotope excursions are recorded,potentially decoupled from global signals.To improve our understanding on the type of information recorded by these excursions,we investigate the pairedδ^13Ccarb andδ^13Corg evolution for an increasingly restricted late Ediacaran-Cambrian foreland system in the West Gondwana interior:the basal Bambui Group.This succession represents a 1~(st)-order sedimentary sequence and records two majorδ^13Ccarb excursions in its two lowermost lower-rank sequences.The basal cap carbonate interval at the base of the first sequence,deposited when the basin was connected to the ocean,hosts antithetical negative and positive excursions forδ^13Ccarb andδ^13Corg,respectively,resulting inΔ^13C values lower than 25‰.From the top of the basal sequence upwards,an extremely positiveδ^13Ccarb excursion is coupled toδ^13Corg,reaching values of+14‰and-14‰,respectively.This positive excursion represents a remarkable basin-wide carbon isotope feature of the Bambui Group that occurs with only minor changes inΔ^13C values,suggesting change in the DIC isotope composition.We argue that this regional isotopic excursion is related to a disconnection between the intrabasinal and the global carbon cycles.This extreme carbon isotope excursion may have been a product of a disequilibria between the basin DIC and atmospheric CO2 induced by an active methanogenesis,favored by the basin restriction.The drawdown of sulfate reservoir by microbial sulfate reduction in a poorly ventilated and dominantly anoxic basin would have triggered methanogenesis and ultimately methane escape to the atmosphere,resulting in a^13C-enriched DIC influenced by methanogenic CO2.Isolated basins in the interior of the Gondwana supercontinent may have represented a significant source of methane inputs to the atmosphere,potentially affecting both the global carbon cycle and the climate.     

Pattern Variability in Arctic Air Temperature Records

The goal of this paper is to provide an overview of recent progress regarding the acquisition and processing of surface air temperature data in the Arctic. It highlights potential methodological contributions to the identification and characterization of pattern change, focusing on spatial and temporal correlations and scale-symmetry properties of time series. The presented methods include L-moments, climate network analysis, detrended fluctuations analysis, and Haar wavelet analysis. New results concerning data from high-latitude Arctic stations illustrate some of the presented methodological aspects.     

Out-of-plane shaking table tests of full-scale historic adobe corner walls retrofitted with timber elements

Historic adobe structures pose a high seismic risk mainly because of the poor out-of-plane bending response of their walls that may produce fatalities and significant economic, cultural, and heritage losses. In this paper, we propose a retrofitting technique that increases the wall strength for both in-plane and out-of-plane directions. This technique consists of vertical and horizontal timber elements symmetrically installed on each face of the wall to form a confining wood frame, supplemented with vertical tensors that pre-compress the wall. This study evaluates the performance of this retrofitting technique with a two-set experimental program on full-scale historic adobe walls. On the first set, four specimens were subjected to a static overturning test with boundary conditions representing the confinement effect at both ends by orthogonal walls. On the second set, three full-scale specimens, one unretrofitted and two retrofitted, were subjected to four ground motion records on a shaking table to assess the out-of-plane dynamic behavior of typical corner walls. The unretrofitted specimen collapsed during the second motion (peak ground acceleration [PGA] = 0.39 g), while both retrofitted walls survived all four motions (maximum PGA of 0.75 g) proving the high effectiveness of the proposed retrofitting. The addition of base anchors as a variation of the retrofitting technique significantly reduced the rocking effects and the residual drifts of the system, thus improving its overall seismic performance. Further research is needed to develop guidelines for seismic retrofit of heritage buildings including multistory full-scale tests of specimens with various types of openings and retrofitting strategies that minimize their architectural impact.     

Northwest Africa 6232: Visible–near infrared reflectance spectra variability of an olivine diogenite

Visible and near-infrared (VNIR) reflectance is an important spectroscopic technique to identify minerals, and their associations, on planetary body surfaces. Howardites, eucrites, and diogenites (HED) are a class of igneous-like meteorites whose genetic connection with asteroid 4 Vesta has since long been inferred and recently confirmed by Dawn mission results. Pyroxene and olivine are the two major mafic minerals present in HED which can be identified with VNIR reflectance measurements. Thus, studying the compositional variability of those phases and their mixtures by means of laboratory spectroscopic measurements on different diogenitic or eucritic samples is one of the prime methods to better understand the evolution of 4 Vesta's crust. Here, we report the VNIR reflectance spectral analysis of a harzburgitic olivine diogenite, Northwest Africa 6232 (probably paired with Northwest Africa 5480), containing variable amounts of olivine as small grains or aggregates. We found that the olivine diogenite spectral parameters (e.g., band position) of powdered samples and polished slabs are in agreement. Moreover, the olivine diogenite band position shifts from synthetic orthopyroxene in accordance with the presence of olivine and chromite. In particular, the presence of a large olivine clast permits us to determine a linear variation of the band position from synthetic orthopyroxene and olivine, but underestimates the presence of olivine in the olivine diogenite spot.     

Adaptive variability to low‐pH river discharges in Acartia tonsa and stress responses to high PCO2 conditions

Environmental transitions leading to spatial physical–chemical gradients are of ecological and evolutionary interest because they are able to induce variations in phenotypic plasticity. Thus, the adaptive variability to low‐pH river discharges may drive divergent stress responses [ingestion rates (IR) and expression of stress‐related genes such as Heat shock protein 70 (Hsp70) and Ferritin] in the neritic copepod Acartia tonsa facing changes in the marine chemistry associated to ocean acidification (OA). These responses were tested in copepod populations inhabiting two environments with contrasting carbonate system parameters (an estuarine versus coastal area) in the Southern Pacific Ocean, and assessing an in situ and 96‐h experimental incubation under conditions of high pressure of CO₂ (_PCO₂ 1200 ppm). Adaptive variability was a determining factor in driving variability of copepods' responses. Thus, the food‐rich but colder and corrosive estuary induced a traits trade‐off expressed as depressed IR under in situ conditions. However, this experience allowed these copepods to tolerate further exposure to high _PCO₂ levels better, as their IRs were on average 43% higher than those of the coastal individuals. Indeed, expression of both the Hsp70 and Ferritin genes in coastal copepods was significantly higher after acclimation to high _PCO₂ conditions. Along with other recent evidence, our findings confirm that adaptation to local fluctuations in seawater pH seems to play a significant role in the response of planktonic populations to OA‐associated conditions. Facing the environmental threat represented by the inter‐play between multiple drivers of climate change, this biological feature should be examined in detail as a potential tool for risk mitigation policies in coastal management arrangements.     

Allochthonous subsidies of organic matter across a lake–river–fjord landscape in the Chilean Patagonia: Implications for marine zooplankton in inner fjord areas

Ecosystems can act as both sources and sinks of allochthonous nutrients and organic matter. In this sense, fjord ecosystems are a typical interface and buffer zone between freshwater systems, glaciated continents, and the coastal ocean. In order to evaluate the potential sources and composition of organic matter across fjord ecosystems, we characterized particulate organic matter along a lake–river–fjord corridor in the Chilean Patagonia using stable isotope (δ¹³C) and lipid (fatty acid composition) biomarker analyses. Furthermore, estimates of zooplankton carbon ingestion rates and measurements of δ¹³C and δ¹⁵N in zooplankton (copepods) were used to evaluate the implications of allochthonous subsidies for copepods inhabiting inner fjord areas. Our results showed that riverine freshwater flows contributed an important amount of dissolved silicon but, scarce nitrate and phosphate to the brackish surface layer of the fjord ecosystem. Isotopic signatures of particulate organic matter from lakes and rivers were distinct from their counterparts in oceanic influenced stations. Terrestrial allochthonous sources could support around 68–86% of the particulate organic carbon in the river plume and glacier melting areas, whereas fatty acid concentrations were maximal in the surface waters of the Pascua and Baker river plumes. Estimates of carbon ingestion rates and δ¹³C in copepods from the river plume areas indicated that terrestrial carbon could account for a significant percentage of the copepod body carbon (20–50%) during periods of food limitation. Particulate organic matter from the Pascua River showed a greater allochthonous contribution of terrigenous/vascular plant sources. Rivers may provide fjord ecosystems with allochthonous contributions from different sources because of the distinct vegetation coverage and land use along each river’s watershed. These observations have significant implications for the management of local riverine areas in the context of any human project that may modify terrestrial habitats as well as the productivity, food webs, and community structure of rivers, lakes, fjords, and the coastal ocean in the Chilean Patagonia.     

The early interaction between the Caribbean Plateau and the NW South American Plate

The determination of accurate and precise ages for the timing of collision between oceanic plateaus and continental crust requires an understanding of how the indenting and buttressing plates respond to the collision. We present geochronological, thermochronological, geochemical and isotopic analyses of magmatic rocks from the Ecuadorian Andes, which relate to the collision of the Late Cretaceous Caribbean Plateau and Great Arc sequence with NW South America. The cessation of subduction magmatism during 65–64 Ma beneath the eastern edge of Caribbean Plateau was synchronous with accelerated surface uplift and exhumation within the buttressing continental margin during 75–65 Ma. We interpret this as the collision of the leading edge of the Caribbean Plateau and arc sequence with the South American Plate at 75–65 Ma. A U/Pb (zircon) SHRIMP age of 87.10 ± 1.66 (2σ) Ma, yielded by an accreted fragment of the plateau, precludes previous estimates of collision at 85–80 Ma if the plateau erupted above the Galápagos hotspot. Terra Nova, 18, 264–269, 2006