Phosphorite-hosted zinc and lead mineralization in the Sekarna deposit (Central Tunisia)

The Sekarna Zn–Pb deposit is located in Central Tunisia at the northeastern edge of the Cenozoic Rohia graben. Mineralization comprises two major ore types: (1) disseminated Zn–Pb sulfides that occur as lenses in sedimentary phosphorite layers and (2) cavity-filling zinc oxides (calamine-type ores) that crosscut Late Cretaceous and Early Eocene limestone. We studied Zn sulfide mineralization in the Saint Pierre ore body, which is hosted in a 5-m-thick sedimentary phosphorite unit of Early Eocene age. The sulfide mineralization occurs as replacements of carbonate cement in phosphorite. The ores comprise stratiform lenses rich in sphalerite with minor galena, Fe sulfides, and earlier diagenetic barite. Laser ablation–inductively coupled plasma mass spectrometry analyses of sphalerite and galena show a wide range of minor element contents with significant enrichment of cadmium in both sphalerite (6,000–20,000 ppm) and galena (12–189 ppm). The minor element enrichments likely reflect the influence of the immediate organic-rich host rocks. Fluid inclusions in sphalerite give homogenization temperatures of 80–130°C. The final ice melting temperatures range from −22°C to −11°C, which correspond to salinities of 15–24 wt.% NaCl eq. and suggest a basinal brine origin for the fluids. Sulfur isotope analyses show uniformly negative values for sphalerite (−11.2‰ to −9.3‰) and galena (−16‰ to −12.3‰). The δ³⁴S of barite, which averages 25.1‰, is 4‰ higher than the value for Eocene seawater sulfate. The sulfur isotopic compositions are inferred to reflect sulfur derivation through bacterial reduction of contemporaneous seawater sulfate, possibly in restricted basins where organic matter was abundant. The Pb isotopes suggest an upper crustal lead source.     

Conceptual and numerical models for sustainable groundwater management in the Thaphra area, Chi River Basin, Thailand

Sustainable management of groundwater resources is vital for development of areas at risk from water-resource over-exploitation. In northeast Thailand, the Phu Thok aquifer is an important water source, particularly in the Thaphra area, where increased groundwater withdrawals may result in water-level decline and saline-water upconing. Three-dimensional finite-difference flow models were developed with MODFLOW to predict the impacts of future pumping on hydraulic heads. Four scenarios of pumping and recharge were defined to evaluate the system response to future usage and climate conditions. Primary model simulations show that groundwater heads will continue to decrease by 4–12?m by the year 2040 at the center of the highly exploited area, under conditions of both increasing pumping and drought. To quantify predictive uncertainty in these estimates, in addition to the primary conceptual model, three alternative conceptual models were used in the simulation of sustainable yields. These alternative models show that, for this case study, a reasonable degree of uncertainty in hydrostratigraphic interpretation is more impactful than uncertainty in recharge distribution or boundary conditions. The uncertainty-analysis results strongly support addressing conceptual-model uncertainty in the practice of groundwater-management modeling. Doing so will better assist decision makers in selecting and implementing robust sustainable strategies.     

Groundwater recharge to a sedimentary aquifer in the topographically closed Uley South Basin, South Australia

The chloride mass balance (CMB) and water-table fluctuation (WTF) analysis methods were used to estimate recharge rates in the Uley South Basin, South Australia. Groundwater hydrochemistry and isotope data were used to infer the nature of recharge pathways and evapotranspiration processes. These data indicate that some combination of two plausible processes is occurring: (1) complete evaporation of rainfall occurs, and the precipitated salts are washed down and redissolved when recharge occurs, and (2) transpiration dominates over evaporation. It is surmised that sinkholes predominantly serve to by-pass the shallow soil zone and redistribute infiltration into the deeper unsaturated zone, rather than transferring rainfall directly to the water table. Chlorofluorocarbon measurements were used in approximating recharge origins to account for coastal proximity effects in the CMB method and pumping seasonality was accounted for in the WTF-based recharge estimates. Best estimates of spatially and temporally averaged recharge rates for the basin are 52?C63 and 47?C129?mm/year from the CMB and WTF analyses, respectively. Adaptations of both the CMB and WTF analyses to account for nuances of the system were necessary, demonstrating the need for careful application of these methods.     

Managed Retreat of Saline Coastal Wetlands: Challenges and Opportunities Identified from the Hunter River Estuary,Australia

We analyse the potential impacts of sea-level rise on the management of saline coastal wetlands in the Hunter River estuary, NSW, Australia. We model two management options: leaving all floodgates open, facilitating retreat of mangrove and saltmarsh into low-lying coastal lands; and leaving floodgates closed. For both management options we modelled the potential extent of saline coastal wetland to 2100 under a low sea-level rise scenario (based on 5 % minima of SRES B1 emissions scenario) and a high sea-level rise scenario (based on 95 % maxima of SRES A1FI emissions scenario). In both instances we quantified the carbon burial benefits associated with those actions. Using a dynamic elevation model, which factored in the accretion and vertical elevation responses of mangrove and saltmarsh to rising sea levels, we projected the distribution of saline coastal wetlands, and estimated the volume of sediment and carbon burial across the estuary under each scenario. We found that the management of floodgates is the primary determinant of potential saline coastal wetland extent to 2100, with only 33 % of the potential wetland area remaining under the high sea-level rise scenario, with floodgates closed, and with a 127 % expansion of potential wetland extent with floodgates open and levees breached. Carbon burial was an additional benefit of accommodating landward retreat of wetlands, with an additional 280,000 tonnes of carbon buried under the high sea-level rise scenario with floodgates open (775,075 tonnes with floodgates open and 490,280 tonnes with floodgates closed). Nearly all of the Hunter Wetlands National Park, a Ramsar wetland, will be lost under the high sea-level rise scenario, while there is potential for expansion of the wetland area by 35 % under the low sea-level rise scenario, regardless of floodgate management. We recommend that National Parks, Reserves, Ramsar sites and other static conservation mechanisms employed to protect significant coastal wetlands must begin to employ dynamic buffers to accommodate sea-level rise change impacts, which will likely require land purchase or other agreements with private landholders. The costs of facilitating adaptation may be offset by carbon sequestration gains.     

A nested-cell approach for in situ remediation

We characterize the hydraulics of an extraction-injection well pair in arbitrarily oriented regional flow by the recirculation ratio, area, and average residence time in the recirculation zone. Erratic regional flow conditions may compromise the performance of the reactor between a single well pair. We propose an alternative four-well system: two downgradient extraction and two upgradient injection wells creating an inner cell nested within an outer cell. The outer cell protects the inner cell from the influence of regional flow. Compared to a two-well system, the proposed four-well system has several advantages: (1) the recirculation ratio within the nested inner cell is less sensitive to the regional flow direction; (2) a transitional recirculation zone between the inner and outer cells can capture flow leakage from the inner cell, minimizing the release of untreated contaminants; and (3) the size of the recirculation zone and residence times can be better controlled within the inner cell by changing the pumping rates. The system is applied at the Field Research Center in Oak Ridge, Tennessee, where experiments on microbial in situ reduction of uranium (VI) are under way.     

Extremely alkaline (pH > 12) ground water hosts diverse microbial community

Chemically unusual ground water can provide an environment for novel communities of bacteria to develop. Here, we describe a diverse microbial community that inhabits extremely alkaline (pH > 12) ground water from the Lake Calumet area of Chicago, Illinois, where historic dumping of steel slag has filled in a wetland. Using microbial 16S ribosomal ribonucleic acid gene sequencing and microcosm experiments, we confirmed the presence and growth of a variety of alkaliphilic beta-Proteobacteria, Bacillus, and Clostridium species at pH up to 13.2. Many of the bacterial sequences most closely matched those of other alkaliphiles found in more moderately alkaline water around the world. Oxidation of dihydrogen produced by reaction of water with steel slag is likely a primary energy source to the community. The widespread occurrence of iron-oxidizing bacteria suggests that reduced iron serves as an additional energy source. These results extend upward the known range of pH tolerance for a microbial community by as much as 2 pH units. The community may provide a source of novel microbes and enzymes that can be exploited under alkaline conditions.     

Use of chemical tracers in assessing the diet and foraging regions of eastern North Pacific killer whales

Top predators in the marine environment integrate chemical signals acquired from their prey that reflect both the species consumed and the regions from which the prey were taken. These chemical tracers-stable isotope ratios of carbon and nitrogen; persistent organic pollutant (POP) concentrations, patterns and ratios; and fatty acid profiles-were measured in blubber biopsy samples from North Pacific killer whales (Orcinus orca) (n=84) and were used to provide further insight into their diet, particularly for the offshore group, about which little dietary information is available. The offshore killer whales were shown to consume prey species that were distinctly different from those of sympatric resident and transient killer whales. In addition, it was confirmed that the offshores forage as far south as California. Thus, these results provide evidence that the offshores belong to a third killer whale ecotype. Resident killer whale populations showed a gradient in stable isotope profiles from west (central Aleutians) to east (Gulf of Alaska) that, in part, can be attributed to a shift from off-shelf to continental shelf-based prey. Finally, stable isotope ratio results, supported by field observations, showed that the diet in spring and summer of eastern Aleutian Island transient killer whales is apparently not composed exclusively of Steller sea lions.     

Thermal imaging of sedimentary features on alluvial fans

Aerial thermal imaging is used to study grain-size distributions and induration on a wide variety of alluvial fans in the desert southwest of the United States. High-resolution aerial thermal images reveal evidence of sedimentary processes that rework and build alluvial fans, as preserved in the grain-size distributions and surface induration those processes leave behind. A catalog of constituent sedimentary features that can be identified using aerial thermal and visible imaging is provided. These features include clast-rich and clast-poor debris flows, incised channel deposits, headward-eroding gullies, sheetflood, lag surfaces, active/inactive lobes, distal sand-skirts and basin-related salt pans. Ground-based field observations of surface grain-size distributions, as well as morphologic, cross-cutting and topographic relationships were used to confirm the identifications of these feature types in remotely acquired thermal and visible images. Thermal images can also reveal trends in grain sizes between neighboring alluvial fans on a regional scale. Although inferences can be made using thermal images alone, the results from this study demonstrate that a more thorough geological interpretation of sedimentary features on an alluvial fan can be made using a combination of thermal and visible images. The results of this study have potential applications for Mars, where orbital thermal imaging might be used as a tool for evaluating constituent sedimentary processes on proposed alluvial fans.     

Localized zones of denitrification in a floodplain aquifer in southern Wisconsin, USA

A floodplain aquifer within an agricultural watershed near Madison, Wisconsin (USA), was studied to determine whether denitrification was occurring below the surface organic layer. Groundwater levels and concentrations of O₂, Cl^?, NO ₃ ^? , SO ₄ ^2? , dissolved organic carbon (DOC), and major cations were monitored over a 1-year period along a 230-m transect between an agricultural field and a stream discharge point. Seventeen groundwater samples were analyzed for δ¹⁵N_NO3 and δ¹⁸O_NO3 composition. Samples in which NO ₃ ^? was too low for stable isotope analysis were analyzed for excess dissolved N₂. Groundwater NO ₃ ^? concentrations declined between the agricultural field and the discharge point. Chloride and δ¹⁵N_NO3/δ¹⁸O_NO3 data indicated that the drop in NO ₃ ^? was caused primarily by dilution of shallow NO ₃ ^? -rich water with deeper, NO ₃ ^? -depleted groundwater. Two localized zones of denitrification were identified in the upland-wetland transition by their δ¹⁵N_NO3 and δ¹⁸O_NO3 signatures, and two in the stream hyporheic zone by the presence of excess dissolved N₂. The combined stratigraphic, hydrologic, and geochemical data in these locations correspond to groundwater mixing zones where NO ₃ ^? is delivered to subsurface layers that support denitrification fueled by dissolved (e.g. DOC or dissolved Fe(II)) and/or solid-phase (e.g. particulate organic carbon, solid-associated Fe(II), or pyrite) electron donors.