A New Lithostratigraphic Framework for the Cretaceous Colorado Group in the Cold Lake Heavy Oil Area,East-Central Alberta,Canada

The Albian to Santonian Colorado Group in the heavy oil area of Cold Lake, east-central Alberta represents a relatively condensed section of shale-dominated sedimentation within the Western Interior Sea. These shales form the cap rock to the underlying Clearwater and Grand Rapids formations that are exploited for bitumen extraction. Two cores covering the entire Colorado Group provide a unique opportunity for establishment of a stratigraphic reference in an area that has received attention only for its heavy oil-bearing Mannville Group. Based on sedimentology, geochemistry, micropaleontology, nannofossils, and wireline log data, the Colorado Group was subdivided into the Joli Fou, Viking, Westgate, Fish Scales, Belle Fourche, Second White Specks, and Niobrara formations. The Niobrara Formation was subdivided further into the Verger Member, informal Cold Lake member, and First White Specks Member. Because of this region’s small accommodation space and distance to sources of coarse clastic sediment, disconformities are indicated lithologically by bioclastic layers and missing biozones. Foraminiferal subzones revealed two erosional boundaries associated with the Viking Formation. Faunal and floral evidence coupled with wireline log correlations suggest that the Middle to Upper Turonian Carlile Formation, as described from southeastern Alberta, is missing. That extends the Middle Turonian to Coniacian unconformity, as recognized in central Saskatchewan, westwards into Alberta.     

Oxygen isotope evidence for short-lived high-temperature fluid flow in the lower oceanic crust at fast-spreading ridges

Millimeter-scale amphibole veins in the lower oceanic crust record fracture-controlled fluid flow at high-temperatures but the importance of this fluid flow for the thermal and chemical evolution of the lower oceanic crust is unclear. In the section of lower oceanic crust recovered at Hess Deep from ODP Hole 894G, which formed at the fast-spreading East Pacific Rise, these veins are randomly distributed with an average spacing of  1 m. We unravel the history of fluid flow through one of these veins by combining in situ O-isotope analyses of wall-rock plagioclase with major element analyses, geothermometry and diffusion modeling. Thermometry indicates vein sealing by amphibole at  720 °C over a narrow temperature interval (± 20 °C). In situ O-isotope analyses by ion microprobe, with a precision of < 0.5‰, reveal zoning of O-isotopes in plagioclase adjacent to the vein. The zoning profiles can be reproduced using a diffusion model if the duration of O-isotope exchange was ≤ 100 yr. A similar interval of fluid–rock exchange is suggested by modeling potassium depletion in plagioclase adjacent to the vein. If representative of fracture controlled fluid flow in the lower oceanic crust the limited duration of fluid flow, and its occurrence over a narrow temperature interval, suggest that high-temperature fluid flow in this porosity network does not transport significant heat.     

Assessment of radionuclide transport uncertainty in the unsaturated zone of Yucca Mountain

The present study assesses the uncertainty of flow and radionuclide transport in the unsaturated zone at Yucca Mountain using a Monte Carlo method. Matrix permeability, porosity, and sorption coefficient are considered random. Different from previous studies that assume distributions of the parameters, the distributions are determined in this study by applying comprehensive transformations and rigorous statistics to on-site measurements of the parameters. The distribution of permeability is further adjusted based on model calibration results. Correlation between matrix permeability and porosity is incorporated using the Latin Hypercube Sampling method. After conducting 200 Monte Carlo simulations of three-dimensional unsaturated flow and radionuclide transport for conservative and reactive tracers, the mean, variances, and 5th, 50th, and 95th percentiles for quantities of interest (e.g., matrix liquid saturation and water potential) are evaluated. The mean and 50th percentile are used as the mean predictions, and their associated predictive uncertainties are measured by the variances and the 5th and 95th percentiles (also known as uncertainty bounds). The mean predictions of matrix liquid saturation and water potential are in reasonable agreement with corresponding measurements. The uncertainty bounds include a large portion of the measurements, suggesting that the data variability can be partially explained by parameter uncertainty. The study illustrates propagation of predictive uncertainty of percolation flux, increasing downward from repository horizon to water table. Statistics from the breakthrough curves indicate that transport of the reactive tracer is delayed significantly by the sorption process, and prediction on the reactive tracer is of greater uncertainty than on the conservative tracer because randomness in the sorption coefficient increases the prediction uncertainty. Uncertainty in radionuclide transport is related to uncertainty in the percolation flux, suggesting that reducing the former entails reduction in the latter.     

Monitoring Changes of Ice Streams Using Time Series of Satellite-Altimetry-Based Digital Terrain Models

The Antarctic Ice Sheet plays a major role in the global system, and the large ice streams discharging into the circumpolar sea represent its gateways to the world's oceans. Satellite radar altimeter data provide an opportunity for mapping surface elevation at kilometer-resolution with meter-accuracy. Geostatistical methods have been developed for the analysis of these data. Applications to Seasat data and data from the Geosat Exact Repeat Mission indicate that the grounding line of Lambert Glacier/Amery Ice Shelf, the largest ice stream in East Antarctica, has advanced 10–12 km between 1978 and 1987–89. The objectives of this paper are to explore possibilities and limitations of satellite-altimetry-based mapping to capture changes for shorter time windows and for smaller areas, and to investigate some methodological aspects of the data analysis. We establish that one season of radar altimeter data is sufficient for constructing a map. This allows study of interannual variation and is the key for a time-series analysis approach to study changes in ice streams. Maps of the lower Lambert Glacier and the entire Amery Ice Shelf are presented for austral winters 1978, 1987, 1988, and 1989. As a first step toward understanding the dynamics of the ice-stream/ice-shelf system, elevation changes are calculated for grounded ice, the grounding zone, and floating ice. In the absence of (sufficient) surface gravity control for the Lambert Glacier/Amery Ice Shelf area, altimetry-based maps may facilitate improvement of geoid models as they provide constraints on the terrain correction in the inverse gravimetric problem.     

Geochemistry of extremely alkaline (pH>12) ground water in slag-fill aquifers

Extremely alkaline ground water has been found underneath many shuttered steel mills and slag dumps and has been an impediment to the cleanup and economic redevelopment of these sites because little is known about the geochemistry. A large number of these sites occur in the Lake Calumet region of Chicago, Illinois, where large-scale infilling of the wetlands with steel slag has created an aquifer with pH values as high as 12.8. To understand the geochemistry of the alkaline ground water system, we analyzed samples of ground water and the associated slag and weathering products from four sites. We also considered several potential remediation schemes to lower the pH and toxicity of the water. The principal cause of the alkaline conditions is the weathering of calcium silicates within the slag. The resulting ground water at most of the sites is dominated by Ca2+ and OH- in equilibrium with Ca(OH)2. Where the alkaline ground water discharges in springs, atmospheric CO2 dissolves into the water and thick layers of calcite form. Iron, manganese, and other metals in the metallic portion of the slag have corroded to form more stable low-temperature oxides and sulfides and have not accumulated in large concentrations in the ground water. Calcite precipitated at the springs is rich in a number of heavy metals, suggesting that metals can move through the system as particulate matter. Air sparging appears to be an effective remediation strategy for reducing the toxicity of discharging alkaline water.     

A classification of magnetic field configurations associated with solar flares

On the assumption that solar flares are due to instabilities which occur in current sheets in the Sun's atmosphere, one may classify magnetic-field configurations associated with flares into two types. One is characterized by closed current sheets, magnetic-field lines adjacent to these sheets beginning and ending at the Sun's surface. The other is characterized by open current sheets, magnetic-field lines adjacent to these sheets beginning at the Sun's surface but extending out into interplanetary space. Flares associated with open current sheets can produce Type III radio bursts and high-energy-particle events, but flares associated with closed current sheets cannot. The flare of July 6, 1966 apparently consisted of one flare of each type.