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91.
Systematic trends in the geometry of 149 oxide and 80 sulfide binary and ternary spinels have been examined from the standpoint of ionic radius and electronegativity. The mean ionic radii of the octahedral and tetrahedral cations, taken together, account for 96.9 and 90.5% of the variation in the unit cell parameter, a, of the oxides and sulfides, respectively, with the octahedral cation exerting by far the dominant influence in sulfides. The mean electronegativity of the octahedral cation exerts an additional, but small, influence on the cell edge of the sulfides. The equation a=(8/3√d)d tet+(8/3)d oct, where d tet and d oct are the tetrahedral and octahedral bond lengths obained from the sum of the ionic radii, accounts for 96.7 and 83.2% of the variation in a in the oxides and sulfides, respectively, again testifying to the applicability of the hard-sphere ionic model in the case of the spinel structure. Comparison of observed and calculated u values for 94 spinels indicates that up to 40% of the experimentally measured anion coordinates may be significantly in error. In addition to these compounds, u values are given for 52 spinels for which no data have previously been determined. Diagrams are presented for the rapid interpretation of the internal consistency of published data and the prediction of the structural parameters of hypothetical or partially studied spinels. 相似文献
92.
93.
94.
Craig Amerigian 《Earth and Planetary Science Letters》1977,36(3):434-442
Deposition experiments have been carried out to measure the effect of particle size variation on the relationship between detrital remanent magnetization (DRM), anhysteretic remanent magnetization (ARM), and geomagnetic field intensity in sediments.Foraminiferal ooze from a box core taken in the Columbian Basin south of Jamaica was separated into several particle size ranges and redeposited in the laboratory in known magnetic fields. The intensity and alternating field (AF) demagnetization characteristics of the DRM and a subsequently applied ARM were compared for the various particle size ranges.The results show a variation of DRM/ARM ratios with particle size. The DRM intensities and directions indicate that particle sizes greater than 38 μm do not contribute significantly to the DRM of the total sediment. ARM intensities for larger particle sizes and particle size analysis of the whole sediment indicate that the fraction greater than 38 μm does make a significant contribution to the total ARM of a sample. Use of the DRM/ARM ratio in experimental measurements of magnetic paleointensity indicates that the method is unsatisfactory for sediments having a significant fraction of magnetic particles larger than 38 μm. It is also shown that, for sediments having a significant fraction of high-coercivity magnetic grains, the relative orientation of the ARM and DRM will affect ARM intensities, making necessary the use of corrected ARM and DRM intensities for ratio calculations. 相似文献
95.
Chantal M. Swan David A. Siegel Norman B. Nelson Craig A. Carlson Elora Nasir 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(12):2175-2192
Recent in situ observations of chromophoric dissolved organic material (CDOM) in the Pacific Ocean reveal the biogeochemical controls on CDOM and indicate predictive potential for open-ocean CDOM in diagnosing particulate organic matter (POM) remineralization rates within ocean basins. Relationships between CDOM and concentrations of dissolved oxygen, nutrients and inorganic carbon in the subthermocline waters of the Pacific reflect the relative influences of water mass ventilation and water-column oxidative remineralization. Apparent in situ oxygen utilization (AOU) accounts for 86% and 61% of variance in CDOM abundance, respectively, in Antarctic Intermediate Water and North Pacific Intermediate Water. In the deep waters of the Pacific below the zone of remineralization, AOU explains 26% of CDOM variability. The AOU–CDOM relationship results from competing biogeochemical and advective processes within the ocean interior. Dissolved organic carbon (DOC) is not statistically linked to the CDOM or AOU distributions, indicating that the majority of CDOM production occurs during the remineralization of sinking POM and thus potentially provides key information about carbon export. Once formed in the ocean interior, CDOM is relatively stable until it reaches the surface ocean where it is destroyed by solar bleaching. Susceptibility to bleaching confers an additional tracer-like quality for CDOM in water masses with active convection, such as mode waters that appear as subsurface CDOM minima. In the surface ocean, atypically low CDOM abundance highlights a region of unusually extreme oligotrophy: the subtropical South Pacific gyre. For these hyper-oligotrophic waters, the present CDOM observations are consistent with analysis of in situ radiometric observations of light attenuation and reflectance, demonstrating the accuracy of the CDOM spectrophotometric observations. Overall, we illustrate how CDOM abundance in the ocean interior can potentially diagnose rates of thermohaline overturning as they affect regional biogeochemistry and export. We further show how relative surface ocean CDOM abundances are driven in large part by processes occurring in the deep layers of the ocean. This is particularly significant for the interpretation of the global surface distribution of CDOM using satellite remote sensing. 相似文献
96.
This benchmark for three-dimensional (3D) numerical simulators of variable-density groundwater flow and solute or energy transport consists of matching simulation results with the semi-analytical solution for the transition from one steady-state convective mode to another in a porous box. Previous experimental and analytical studies of natural convective flow in an inclined porous layer have shown that there are a variety of convective modes possible depending on system parameters, geometry and inclination. In particular, there is a well-defined transition from the helicoidal mode consisting of downslope longitudinal rolls superimposed upon an upslope unicellular roll to a mode consisting of purely an upslope unicellular roll. Three-dimensional benchmarks for variable-density simulators are currently (2009) lacking and comparison of simulation results with this transition locus provides an unambiguous means to test the ability of such simulators to represent steady-state unstable 3D variable-density physics. 相似文献
97.
Site assessment and monitoring data were analyzed for 26 stream restoration projects in North Carolina where the channel was
reconfigured. Post-project changes in channel capacity were highly variable from site to site, but more than 60% of the projects
underwent, on average at a given site, at least a 20% change in channel capacity. An analysis of site and basin geomorphology
revealed that large post-construction adjustments were associated with highly dynamic stream channels characterized by a combination
of high sediment transport capacity, large sediment supply, and/or easily eroded bank materials. In-stream structures along
dynamic, reconfigured channels also exhibited high incidences of damage. Thus, the design and construction of channels in
a state of equilibrium, which do not exhibit excessive erosion or deposition along highly dynamic rivers is currently problematic.
In light of these findings, a conceptual framework based on geomorphic parameters is put forth to assess the likelihood of
project success early in the design process to (1) eliminate high risk sites from consideration of channel reconfiguration
and (2) improve upon the implemented management strategies that are ultimately used. It is also argued that where space permits
an enhanced natural channel, adjustment approach is likely to be more effective than projects based on natural channel design. 相似文献
98.
Aaron P. Potito Craig A. Woodward Michelle McKeown David W. Beilman 《Journal of Paleolimnology》2014,52(4):385-404
Ireland provides a unique setting for the study of past climates, as its climate is dominated by westerly airflow from the North Atlantic and readily responsive to changes in North Atlantic circulation patterns. Although there has been substantial research on Ireland’s past environments, quantitative palaeolimnological research, especially chironomid-based research, has been lacking. In order to further develop chironomid-based palaeolimnological investigations, a calibration set was constructed to determine the dominant environmental controls on modern chironomids in western Ireland. Chironomid subfossils were collected from surface sediments of 50 lakes. The lakes were characterised with 36 environmental variables, including physical attributes, lake water characteristics, lake sediment characteristics and land cover within each catchment. In this exploratory study, no specific environmental variable was targeted and lakes were chosen to span gradients of latitude, elevation, depth and trophic status. Redundancy analysis showed that six environmental variables—mean July air temperature, lake depth, dissolved organic carbon, and percentage catchment land cover of agriculture, peat bog and scrubland—captured a large and statistically significant portion of the variance in the chironomid data. July temperature and agricultural land cover were the most dominant environmental variables, with July temperature proving the most suitable for inference model development. A classical weighted-averaging model was developed to estimate July air temperature, with a coefficient of determination (r jack 2 ) of 0.60 and root mean square error of prediction (RMSEP) of 0.57 °C. Results suggest that summer temperature is the dominant influence on chironomid distribution across a wide variety of lake types, and the relatively small RMSEP should allow for more accurate reconstructions of Ireland’s relatively subdued Holocene temperature fluctuations. 相似文献
99.
The deep‐sea bivalve Acesta oophaga lives attached to the anterior end of the vestimentiferan tubeworm, Lamellibrachia luymesi, at cold methane seeps. The bivalve is found almost exclusively on female tubeworms, where it consumes the lipid‐rich eggs of L. luymesi that are spawned year round (Biological Bulletin, 209, 2005, 87). It is apparent that A. oophaga benefits directly from this close association, but the consequences for the tubeworm host may be more complicated than just a simple predator–prey interaction. Since A. oophaga completely surrounds the tube opening and plume of the worm, it is likely that its presence would limit oxygen uptake by L. luymesi, thereby inhibiting worm growth and reproduction. We hypothesized that occupied tubeworms would compensate for this by growing larger plumes for oxygen uptake. To explore the effects of bivalve presence/absence on female tubeworms, several morphological features, including body size, plume length, tube diameter, and tube segment length, as well as instantaneous fecundity, were compared. Results suggest that the mere presence of A. oophaga has a significant impact on the morphology of its host worm, as all measures of worm size, except for tube segment length, were significantly greater with clams present. Additionally, instantaneous fecundity was 3.5 times higher in occupied worms, implying that tubeworms are not oxygen‐deprived or energy limited as a result of bivalve presence. Our findings suggest that the association between these two deep‐sea organisms may be a more complex form of symbiosis than the simple predator–prey relationship, as previously thought. 相似文献
100.
The Little Ice Age climate of New Zealand reconstructed from Southern Alps cirque glaciers: a synoptic type approach 总被引:2,自引:1,他引:1
Andrew Lorrey Nicolas Fauchereau Craig Stanton Petra Chappell Steven Phipps Andrew Mackintosh James Renwick Ian Goodwin Anthony Fowler 《Climate Dynamics》2014,42(11-12):3039-3060
Little Ice Age (LIA) austral summer temperature anomalies were derived from palaeoequilibrium line altitudes at 22 cirque glacier sites across the Southern Alps of New Zealand. Modern analog seasons with temperature anomalies akin to the LIA reconstructions were selected, and then applied in a sampling of high-resolution gridded New Zealand climate data and global reanalysis data to generate LIA climate composites at local, regional and hemispheric scales. The composite anomaly patterns assist in improving our understanding of atmospheric circulation contributions to the LIA climate state, allow an interrogation of synoptic type frequency changes for the LIA relative to present, and provide a hemispheric context of the past conditions in New Zealand. An LIA summer temperature anomaly of ?0.56 °C (±0.29 °C) for the Southern Alps based on palaeo-equilibrium lines compares well with local tree-ring reconstructions of austral summer temperature. Reconstructed geopotential height at 1,000 hPa (z1000) suggests enhanced southwesterly flow across New Zealand occurred during the LIA to generate the terrestrial temperature anomalies. The mean atmospheric circulation pattern for summer resulted from a crucial reduction of the ‘HSE’-blocking synoptic type (highs over and to the west of NZ; largely settled conditions) and increases in both the ‘T’- and ‘SW’-trough synoptic types (lows passing over NZ; enhanced southerly and southwesterly flow) relative to normal. Associated land-based temperature and precipitation anomalies suggest both colder- and wetter-than-normal conditions were a pervasive component of the base climate state across New Zealand during the LIA, as were colder-than-normal Tasman Sea surface temperatures. Proxy temperature and circulation evidence were used to corroborate the spatially heterogeneous Southern Hemisphere composite z1000 and sea surface temperature patterns generated in this study. A comparison of the composites to climate mode archetypes suggests LIA summer climate and atmospheric circulation over New Zealand was driven by increased frequency of weak El Niño-Modoki in the tropical Pacific and negative Southern Annular Mode activity. 相似文献