Whole-watershed mercury balance at Sagehen Creek, Sierra Nevada, CA

Few data are available on mercury (Hg) dynamics at high-elevation mountain sites. In this project, a whole-watershed approach was used to quantify major fluxes and pools of Hg in Sagehen basin, a closed basin in the Sierra Nevada mountains in California. Over a period spanning 9 months (January-September 2009), we estimated wet deposition inputs to the watershed at 3.8 μg m⁻². Dry deposition added additional Hg in the range of 0.30-2.45 μg m⁻² during this time period, and was the dominant deposition process during summer time. Seasonal snowpack accounted for only half of the Hg deposited by wet deposition. We suggest that photo-induced reduction of Hg(II) in snow and subsequent volatilization was responsible for this loss. Thus, snowpacks in the Sierra Nevada mountains likely reduce the effective atmospheric mercury flux via wet deposition due to significant emission fluxes prior to snowmelt. As such, wet Hg deposition could be of lesser importance as a Hg source in snow-dominated systems. Finally, stream runoff collected at the outlet of the watershed could account for only 4% of total Hg wet deposition suggesting that a large fraction of mercury deposition was sequestered in the ecosystem, specifically in the soils.     

An Evaluation of the Inter‐Method Discrepancies in Ferromanganese Nodule Proficiency Test GeoPT 23A

Round 23 of the GeoPT international proficiency testing scheme included the ferromanganese nodule powder FeMn‐1 which was distributed as an additional sample (23A). The aim of this initiative was to assess overall analytical performance for such a challenging oxide matrix with a view to the possible certification of such a material in accordance with ISO Guide requirements. To investigate inter‐method discrepancies, precision data and the method means for the most frequently used analytical methods (XRF, ICP‐MS and ICP‐AES) and sample preparation techniques were calculated and then compared using statistical tests of equivalence. For most major elements, XRF and ICP‐AES data dominated and these were found to give equivalent results. In contrast, for most trace elements significant discrepancies were detected between data obtained by different analytical methods. Possible causes are discussed with a view to attributing their origin to calibration strategy, sensitivity or interferences. It is assumed that the unusual oxide matrix generated unexpected interferences and thus method bias. Discrepancies observed between data from different analytical methods provide valuable information for the participating analysts, helping them to avoid systematic errors and thus minimising bias. They also suggest actions necessary to improve results for any future certification of such a material.     

The Recovery as an Important Part of NEA Astrometric Follow-up

The number of known near-Earth asteroids (NEAs) has increased rapidly in recent years due to large surveys. This discovery process has to be followed by follow-up observations to obtain a sufficient number of precise astrometric data needed for an accurate orbit determination of newly discovered bodies.Accurate orbit determination requires observations from at least two oppositions. If asteroids are not found in the next apparition, different from the discovery apparition, then they can be considered lost. This is particularly embarrassing for NEAs. If data for different apparitions are not found in the course of precovery surveys or in other archive data, then it is necessary to prepare targeted observations of a particular NEA in the second convenient apparition. Therefore NEA recovery is a very important part of NEA follow-up.We discuss here methods, techniques, and results of planned recoveries at the Klet' Observatory using a 0.57-m telescope equipped with a CCD detector. The Klet' NEA recovery subprogram has brought 21 planned NEA recoveries since 1997, including seven NEAs belonging to the potentially hazardous asteroid category.We briefly mention the overall work on NEA recoveries provided by several NEO follow-up programs as well as the need for communication resources supporting astrometric observers. Finally we present here a planned extension of the Klet' NEA recovery subprogram to fainter objects by means of a new 1.06-m reflector.     

The Turkish Dilatancy Project (TDP3): multidisciplinary studies of a potential earthquake source region

Summary. The section of the North Anatolian Fault lying near the city of Izmit, at the east of the Marmara Sea, has been identified as a seismic gap and the possible site of a future major earthquake. Previously published studies of records from an earthquake swarm within the gap (TDP1 and TDP2) provided the first evidence that shear-wave splitting occurs in earthquake source regions, a conclusion since verified by many studies at other locations. A third field study (TDP3) was mounted in the Izmit region during the summer of 1984. Observations were made over an eight-month period and included geomagnetic and geoelectric measurements in addition to a series of observations utilising dense arrays of three-component seismometers. Earthquake activity in the principal study area was monitored over a period of eight months. Records showed features similar to those observed in the earlier studies. In particular: (1) almost all shear waves emerging within the shear-wave window displayed shear-wave splitting; and (2) the polarizations of the first arriving (faster) split shear-waves showed sub-parallel alignments, characteristic of propagation through a distribution of parallel vertical cracks striking perpendicular to the minimum compressional stress.
These and other observations support the conclusion of earlier studies – that the upper crust is pervaded by distributions of micro-cracks aligned by stress, known as extensive-dilatancy anisotropy. A search for time dependence in shear-wave phenomena has revealed temporal variations in the delays between the split shear-waves throughout the course of the TDP3 study, but as yet this has not been correlated with specific earthquake activity.     

Metasomatism of the Pan-African lithospheric mantle beneath the Damara Belt,Namibia, by the Tristan mantle plume: geochemical evidence from mantle xenoliths

In situ trace element analyses of constituent minerals in mantle xenoliths occurring in an alnöite diatreme and in nephelinite plugs emplaced within the central zone of the Damara Belt have been determined by laser ablation ICP-MS. Primitive mantle-normalized trace element patterns of clinopyroxene and amphibole indicate the presence of both depleted MORB-like mantle and variably enriched mantle beneath this region. Clinopyroxenes showing geochemical depletion have low La/Sm_n ratios (0.02–0.2), whereas those showing variable enrichment have La/Sm_n ranging up to 3.8 and La/Yb_n to 9.1. The most enriched clinopyroxenes coexist with amphibole showing similar REE patterns (La/Sm_n = 1.3–4.1; La/Yb_n = 4.5–9). Primitive mantle-normalized trace element patterns allow further groups to be distinguished amongst the variably enriched clinopyroxenes: one having strong relative depletion in Rb–Ba, Ta–Nb and relative enrichment in Th–U; another with similar characteristics but with additional strong relative depletion in Zr–Hf; and one showing no significant anomalies. Amphiboles show similar normalized trace element patterns to co-existing clinopyroxene. Clinopyroxene and amphiboles showing LREE_N enrichment have high Sr and low Nd isotope ratios compared to clinopyroxene with LREE-depleted patterns. Numerical simulation of melt percolation through the mantle via reactive porous flow is used to show that the chromatographic affect associated with such a melt migration process is able to account for the fractionation seen in La–Ce–Nd in cryptically metasomatized clinopyroxenes in Type 1 xenoliths, where melt–matrix interactions occur near the percolation front, whereas REE patterns in clinopyroxenes proximal to the source of metasomatic melt/fluid match those found in modally metasomatized Type 2 xenoliths. The strong fractionation between Rb–Ba, Th–U and Ta–Nb shown by some cryptically metasomatized xenoliths can be also accounted for by reactive porous flow, provided amphibole crystallizes from the percolating melt/fluid close to its source. The presence of amphibole in vein-like structures in some xenoliths is consistent with this interpretation. The strong depletion in Zr–Hf in clinopyroxene and amphibole in some xenoliths cannot be accounted for by melt migration processes and requires metasomatism by a separate carbonate-rich melt/fluid. When taken together with published isotope data on these same xenoliths, the source of metasomatic enrichment of the previously depleted (MORB-like) sub-Damaran lithospheric mantle is attributed to the upwelling Tristan plume head at the time of continental breakup.     

Sabatier-based CO2-methanation by catalytic conversion

The catalytic conversion of CO₂ is an important component for the reintegration of secondary products like CO₂ or H₂ into the energy supply. An example is the “power to gas” concept with a conversion of CO₂ into CH₄. The CO₂ is transferred into a carrier of chemical energy, with the possibility to feed the produced CH₄ into the existing network of natural gas. At temperatures of around 350 °C, hydrogenation of CO₂ to CH₄ is possible by the Sabatier reaction CO₂ + 4H₂ → CH₄ + 2H₂O. One prerequisite for efficient kinetics of the Sabatier reaction is the application and optimization of catalysts. The focus of catalyst development is given to their performance under the conditions to be expected in the special application. As a part of the project Geoenergy-Research (GeoEn), we address questions related to the catalytic utilization of CO₂ produced in the course of the oxyfuel combustion of lignite. In this contribution, we report on the experimental setup in laboratory scale, which enables an advanced characterization of the catalytic performance, including thermodesorption measurements at atmospheric pressure in order to determine the amount of adsorbed CO₂ under real conditions. We also show data for activation energies, the catalytic performance as function of temperature and the long time stability of a commercial Ru-based catalyst.     

Relations between denudation,glaciation, and sediment deposition: implications from the Plio‐Pleistocene Central Alps

Despite abundant data on the early evolution of the Central Alps, the latest stage exhumation history, potentially related to relief formation, is still poorly constrained. We aim for a better understanding of the relation between glaciation, erosion and sediment deposition. Addressing both topics, we analysed late Pliocene to recent deposits from the Upper Rhine Graben and two modern river sands by apatite fission‐track and (U‐Th‐Sm)/He thermochronology. From the observed age patterns we extracted the sediment provenance and paleo‐erosion history of the Alpine‐derived detritus. Due to their pollen and fossil record, the Rhine Graben deposits also provide information on climatic evolution, so that the erosion history can be related to glacial evolution during the Plio‐Pleistocene. Our data show that Rhine Graben deposits were derived from Variscan basement, Hegau volcanics, Swiss Molasse Basin, and the Central Alps. The relations between glaciation, Alpine erosion, and thermochronological age signals in sedimentary rocks are more complex than assumed. The first Alpine glaciation during the early Pleistocene did not disturb the long‐term exhumational equilibrium of the Alps. Recent findings indicate that main Alpine glaciation occurred at ca. 1 Ma. If true, then main Alpine glaciation was coeval with an apparent decrease of hinterland erosion rates, contrary to the expected trend. We suggest that glaciers effectively sealed the landscape, thus reducing the surface exposed to erosion and shifting the area of main erosion north toward the Molasse basin, causing sediment recycling. At around 0.4 Ma, erosion rates increased again, which seems to be a delayed response to main glaciation. The present‐day erosion regime seems to be dominated by mass‐wasting processes. Generally, glacial erosion rates did not exceed the pre‐glacial long‐term erosion rates of the Central Alps.     

A methodology for dealing with regional change in integrated water resources management

The paper presents a methodology on how to consistently deal with the future change and management options in integrated water resources management (IWRM). It is based on a conceptual framework with a five step procedure for the formulation and analysis of a so-called ‘parameterised regional futures’. Developing and testing the approach for IWRM is realised for the upper part of the Western Bug River catchment (Ukraine). Special attention is paid to scenarios of change covering climate and land use. The future regional climate is downscaled with the model CCLM. Land cover is projected after retrospective change detection and the derivation of prospective algorithms. Parameters of the interrelations between land use and the water cycle are tackled through using the concept of the model PWF-LU. The methodology is currently being tested to analyse the impacts of mid-term regional change and management options on the water cycle of the catchment.