Correcting airborne flux measurements for aircraft speed variation

Airplane aerodynamic characteristics correlate aircraft speed with vertical wind velocity, making the time average inappropriate for estimating the ensemble average in airborne eddy-correlation flux computations. The space average, the proper form, is implemented as a time integral by a transformation of variables, which can be interpreted as a ground-speed correction to the time average. The mathematical forms are presented, and the importance of the speed correction is illustrated with airborne data. The computed correction is found to be highly variable, depending on both the turbulent flow encountered and the aircraft used. In general, the speed connection becomes more important as airplane size is reduced. For a small, single-engine Long-EZ airplane, used as an example, the straight time average erred, half the time, by 12%, 10%, 20%, and 15%, respectively, for computed fluxes of momentum, heat, moisture, and CO₂. For a much heavier Twin Otter airplane, also used as an example, the straight time average erred, half the time by only 1%. These errors increased with decreasing altitude for the Long-EZ and with increasing altitude for the Twin Otter.Oak Ridge Associated Universities, assigned to NOAA/ATDD.     

Petrology, geochemistry and tectonic implications of volcanics dredged from the intersection of the Yap and Mariana trenches

Rocks dredged from the forearc very close to the intersection of the Yap and Mariana trenches include a suite of highly depleted arc tholeiites, and several samples of transitional to slightly alkaline basalt. The tholeiites range from magnesian quartz tholeiites with 0.46–0.6% TiO₂, to andesites with up to 62% SiO₂ and 8.2% FeO^*. All show pronounced LREE depletion and have very low contents of Ba and Sr. They are postulated to have been produced by partial melting of upper mantle peridotite residual after MORB extraction, following influx of hydrous fluids from the subducted slab. While these fluids were responsible for small enrichments in Ba, K, Rb and Sr in melts generated, LREE were not involved in the metasomatism, and the strong LREE depletion probably reflects the unmodified, depleted source peridotite.

The second lava suite includes slightly Ne-normative, Ti-augite-bearing basalts with convex-upward REE patterns, showing slight LREE depletion ((La/Sm)_N = 0.76). The chemical features of these basalts support affinities with basalts erupted during the earliest stages of backarc basin opening. A KAr age on one sample(7.8 ± 1.3m.y.) is in good agreement with the initial opening of the Mariana Trough.

The tectonic significance of the dredged arc tholeiite suite is less obvious. A KAr age of10.8 ± 0.4 My on one andesite, and the occurrence of similar lavas in dredges from at least 300 km along the length of the Yap arc, suggest that subduction was occurring beneath the Yap arc in the Late Miocene, after overthrusting of the Yap greenschist allochthon, and while calc-alkaline arc magmatism was occurring further north on the West Mariana Ridge. We suggest that the depleted arc tholeiites in dredge 1438 were generated by abnormally shallow melting of upper mantle beneath the Yap forearc following subduction beneath this area of young, hot Sorol Trough crust. These arc tholeiites represent a magma type transitional between more typical arc tholeiites (e.g. Tongan) and high-Mg andesites and boninites.     

Biological markers from Green River kerogen decomposition

Isoprenoid and other carbon skeletons that are formed in living organisms and preserved essentially intact in ancient sediments are often called biological markers. The purpose of this paper is to develop improved methods of using isoprenoid hydrocarbons to relate petroleum or shale oil to its source rock. It is demonstrated that most, but not all, of the isoprenoid hydrocarbon structures are chemically bonded in kerogen (or to minerals) in Green River oil shale. The rate constant for thermally producing isoprenoid, cyclic, and aromatic hydrocarbons is substantially greater than for the bulk of shale oil. This may be related to the substantial quantity of CO₂ which is evolved coincident with the isoprenoid hydrocarbons but prior to substantial oil evolution. Although formation of isoprenoid alkenes is enhanced by rapid heating and high pyrolysis temperatures, the ratio of isoprenoid alkenes plus alkanes to normal alkenes plus alkanes is independent of heating rate. High-temperature laboratory pyrolysis experiments can thus be used to predict the distribution of aliphatic hydrocarbons in low temperature processes such as in situ shale oil production and perhaps petroleum formation. Finally, we demonstrate that significant variation in biological marker ratios occurs as a function of stratigraphy in the Green River formation. This information, combined with methods for measuring process yield from oil composition, enables one to relate time-dependent processing conditions to the corresponding time-dependent oil yield in a vertical modified-in situ retort even if there is a substantial and previously undetermined delay in drainage of shale oil from the retort.