The effect of welding degree on geotechnical properties of an ignimbrite flow unit: the Bitlis castle case (eastern Turkey)

Ignimbrites are associated with nearly most of the world’s volcanoes and are defined as a deposit from pyroclastic density currents. They consist predominantly of pumiceous lapilli and blocks, and glass shards, which shows evidence of having been emplaced as a concentrated hot and dry particulate flow. These rocks are widely used as building stone especially in ancient buildings. Bitlis valley is covered by ignimbritic products, derived from Nemrut stratovolcano, one of the significant volcanic centers in Eastern Anatolia. The Bitlis ignimbrite is separated into lower level (LL), middle level (ML) and upper level (UL) according to color, welding degree and structural features. All three levels were used extensively in many parts of the Bitlis castle as masonry materials. Studies were carried out on mineralogical and geochemical composition and on physical and mechanical properties of the ignimbrites. In addition, a freeze–thaw cycle test was executed. There are no considerable differences in mineralogical composition among the levels of ignimbrite. All levels contain plagioclase, sanidine, pyroxene, and opaque mineral. In addition, anorthoclase and quartz are seen. In general, the LL of ignimbrite shows relic perlitic and eutaxitic texture, whereas eutaxitic and vesicular texture are commonly developed in the ML and UL, respectively. Lower, middle, and upper level ignimbrite samples display similar and limited compositional spread in terms of major oxide elements. They have trachyte composition. Building stones can be classified according to mineralogy, mechanical and physical properties and processing types. Mechanical and physical properties are very important with respect to stone quality/durability. The mechanical and physical properties of the ignimbrites are controlled by the welding degree. It was found that increasing welding degree from UL to LL correlates with increasing density, compressive strength and slake durability index and with decreasing porosity. The Bitlis ignimbrites have turned out as susceptible to freeze–thaw cycles.     

Chemistry of the Ferraria thermal water, S. Miguel Island, Azores: mixing and precipitation processes

The Ferraria thermal water emerges at the sea level in the Ferraria lava delta (western edge of S. Miguel Island, Azores) with temperature of ca. 60°C and pH varying between 5.4 and 6.2. It is of sodium chloride type, resulting from ca. 50% seawater mixing with an acid brackish, at ≈100°C, denoting the presence of significant CO₂(g) and the progress of water–rock interactions in open system conditions. The thermal Na–Cl water is strongly enriched with Sr and Mn and, comparatively, has low concentrations in Al, Fe and As. These elements are removed from the solution as critical conditions for the formation of several neo-formed mineral phases are gradually attained. Thermodynamic equilibrium calculations are consistent with this interpretation, showing that the thermal fluid can precipitate Fe³⁺-(hydr-)oxides, kaolinite and non-crystalline silica. Wells logging show fracture planes and pores fully/partly filled up with polyphase botryoidal aggregates mostly composed of goethite + ferrihydrite and displaying variable adsorbed contents of Si, P and As. These neo-formed phases result from the pristine fluid oxidation due to seawater mixing; its precipitation is easily affected by pH and redox variations of the brackish, due to volcanic gases pressure alterations, and fluid pressure or flow-velocity oscillation in the fractured aquifer.     

Shear banding in geomaterials under extensional plane strain conditions: Physical and analytical model

The shear band (SB) spacing phenomenon in geomaterials is addressed in this paper under plane strain extensional conditions. On the basis of sand box observations, a method is proposed for the prediction of the spacing between shear bands based on the so-called “bookshelf” deformation mechanism. The proposed method is based on the assumption that the material is softening inside the shear bands whereas outside the SB it undergoes elastic unloading. The underlying assumption for the prediction of SB spacing is that the material reaches the lowest possible energy rate. An analytical expression for the determination of the shear band spacing is presented taking into account the plane strain extensional deformation of the specimen. The friction due to the normal off-plane shear acting on the boundaries is then taken into account.     

Improving strategies with constraints regarding non-Gaussian statistics in a three-dimensional variational assimilation method

We assess validity of a Gaussian error assumption, the basic assumption in data assimilation theory, and propose two kinds of constraints regarding non-Gaussian statistics. In the mixed water region (MWR) off the east coast of Japan exhibiting complicated frontal structures, a probability density function (PDF) of subsurface temperature shows double peaks corresponding to the Kuroshio and Oyashio waters. The complicated frontal structures characterized by the temperature PDF sometimes cause large innovations, bringing about a non-Gaussianity of errors. It is also revealed that assimilated results with a standard three-dimensional variational (3DVAR) scheme have some issues in MWR, arising from the non-Gaussianity of errors. The Oyashio water sometimes becomes unrealistically cold. The double peaks seen in the observed temperature PDF are too smoothed. To improve the assimilated field in MWR, we introduce two kinds of constraints, J _c1 and J _c2, which model the observed temperature PDF. The constraint J _c1 prevents the unrealistically cold Oyashio water, and J _c2 intends to reproduce the double peaks. The assimilated fields are significantly improved by using these constraints. The constraint J _c1 effectively reduces the unrealistically cold Oyashio water. The double peaks in the observed temperature PDF are successfully reproduced by J _c2. In addition, not only subsurface temperature but also whole level temperature and salinity (T–S) fields are improved by adopting J _c1 and J _c2 to a multivariate 3DVAR scheme with vertical coupled T–S empirical orthogonal function modes.     

The Indian Ocean’s asymmetric effect on the coupling of the Northwest Pacific SST and anticyclone anomalies during its spring–summer transition after El Niño

By comparing different climatologies in El Niño decaying summer with regard to the presence of Indian Ocean Basin (IOB) warming, we studied the effect of IOB warming on the Northwest Pacific sea surface temperature (SST) anomalies and the coupling process with the surface wind. Zonal asymmetric coupling feedback in the west and east of the Northwest Pacific were caused by the asymmetric spring–summer transition of the background tropical atmospheric circulation. Although the westward wind anomaly caused by the remote effect of IOB warming is found in the whole Northwest Pacific, reversal of the mean background surface winds in the western part leads to negative wind-evaporation SST (WES), whereas sustained trade winds lead to positive WES in the eastern part. The east–west SST gradient resulting from this zonal asymmetric evolution of SST sets off more positive feedback that strengthens the local anticyclone easterly anomalies.     

Algorithm for estimating sea surface temperatures based on Aqua/MODIS global ocean data. 2. Automated quality check process for eliminating cloud contamination

This study developed a post-processing quality check (QC) process to eliminate cloud contamination in infrared sea surface temperature (SST) without manual handling. Cloudiness of a pixel was evaluated quantitatively, in which the graduated verifications and a comprehensive decision from a combination of several tests were conducted. Additionally, the quality of SST data at the pixel was measured by acceptable limits from reference SST, which were obtained from historical data. The QC processed data showed good accuracy below 0.8°C, even in the near-cloud area. Before the QC, their accuracies including near-cloud areas were as poor as 2–5°C.     

On the observed relationship between the Pacific Decadal Oscillation and the Atlantic Multi-decadal Oscillation

We studied the relationship between the dominant patterns of sea surface temperature (SST) variability in the North Pacific and the North Atlantic. The patterns are known as the Pacific Decadal Oscillation (PDO) and the Atlantic Multi-decadal Oscillation (AMO). In the analysis we used two different observational data sets for SST. Due to the high degree of serial correlation in the PDO and AMO time series, various tests were carried out to assess the significance of the correlations. The results demonstrated that the correlations are significant when the PDO leads the AMO by 1 year and when the AMO leads the PDO by 11–12 years. The possible physical processes involved are discussed, along with their potential implication for decadal prediction.     

Morphological and genetic comparison of two strains of a Prorocentrum species isolated from Zhejiang coastal water of China and Masan Bay of Korea

In this paper, we examined the detailed morphology of two strains of Prorocentrum isolated from the coastal waters of Zhejiang (Wenling area), China, and Masan Bay of Korea. A taxonomic comparison was made among strains on the basis of morphological and molecular data. The cellular dimensions of the Chinese Wenling strain (LAMB090508) and Korean strain (PDKS0206) were similar and the cells of both strains were of asymmetric and elongated shape. The posterior end of most cells was rounded. Megacytic zones of aged cells were broader with dense tiny knobs. The roundish nucleus was located in the posterior part of the cell. A few irregular shaped chloroplasts were distributed within the cell. The nucleotide similarity of the two strains, determined from the 5.8S rDNA-ITS sequences, was 99.83%. The comparative results of morphology and molecular analysis suggest that both strains isolated from China and Korea were the identical species, Prorocentrum donghaiense Lu.