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851.
W.?SiebelEmail author A.?K.?Schmitt E.?Kiemele M.?Dani?ík F.?Aydin 《Contributions to Mineralogy and Petrology》2011,162(6):1233-1247
The Acigöl rhyolite field erupted the most recent high-silica rhyolites within the Cappadocian Volcanic Province of central Anatolia, Turkey. It comprises two sequences of domes and pyroclastic rocks with eruption ages of ~150–200 ka (eastern group) and ~20–25 ka (western group). Compositionally, the eastern rhyolite group lavas are less evolved (SiO2 = 74–76 wt%), whereas the western group has higher silica abundance (SiO2 = ~77 wt%) with extremely depleted feldspar-compatible trace elements. Within each group, compositional variability is small and 143Nd/144Nd (0.51257–0.51265) and Pb isotope compositions (206Pb/204Pb = 18.87–18.88, 207Pb/204Pb = 15.65–15.67 and 208Pb/204Pb = 38.94–38.98) are homogeneous. The western group rhyolites have δ18O(zircon) overlapping mantle values (5.7 ± 0.2‰), whereas eastern group rhyolites are enriched in δ18O by ~0.5‰, consistent with a tendency to lower εNd values. By contrast, western group rhyolites have markedly more radiogenic 87Sr/86Sr ratios (0.7065–0.7091) compared to those of the eastern group (0.7059–0.7065). The presence of angular granitic xenoliths and a correlation between hydration (based on loss on ignition data) and 87Sr/86Sr in the western lavas, however, indicates that Sr was added during the eruption or post-eruption alteration. Isotope constraints preclude the possibility that the rhyolite magmas formed by partial melting of any known regional crystalline basement rocks. Basalts and andesites erupted in the periphery of the Acigöl field are characterised by 87Sr/86Sr ratios between 0.7040 and 0.7053, 143Nd/144Nd = 0.51259–0.51300, 206Pb/204Pb = 18.85–18.87, 207Pb/204Pb = 15.646–15.655, 208Pb/204Pb = 38.90–38.97. The isotopic and trace element data favour an origin of the rhyolites by mixing of basaltic/andesitic magmas with minor amounts of crustal melts and followed by extensive fractional crystallization. 相似文献
852.
Idael Francisco Blanco-Quintero C. Lázaro A. García-Casco J. A. Proenza Y. Rojas-Agramonte 《Contributions to Mineralogy and Petrology》2011,162(2):395-413
Whole-rock compositions of muscovite-bearing amphibolite, trondhjemite, pegmatite and quartz-muscovite rocks from Sierra del
Convento and La Corea mélanges (eastern Cuba), as well as mineralogy, record complex circulation of Ba-rich fluids and melts
in the subduction environment. Partial melting of fluid-fluxed, MORB-derived amphibolite produced trondhjemite magmas that
crystallized at depth, in some cases evolving into pegmatites. Qtz-Ms rocks probably crystallized from primary fluids derived
from subducted sediments. All these rocks have elevated concentrations of large-ion lithophile elements, especially Ba (up
to 11,810 ppm), presumably released from slab sediments by fluids and/or melts. Fluid–rock interaction produced crystallization
of phengite in parental amphibolites. The phengite crystallized in all types of rocks is rich in Ba, with concentric zoning,
characterized by Ba-rich cores and Ba-poor rims, indicating a compatible behaviour of Ba in the studied systems. Zoning in
phengite is governed primarily by the celadonite (tschermak) exchange vector ((Mg,Fe)Si-(Al)-2), with more moderate contributions of the celsian (BaAl-(KSi)-1) and paragonite (NaK-1) exchange vectors. Late remobilization of Ba at relatively low temperature formed retrograde celsian. The compatible behaviour
of Ba in the studied rocks strengthens the importance of the stability of phengite for the transfer of LIL elements from the
subduction to the volcanic arc environments. 相似文献
853.
Paul D. Taylor Consuelo Sendino 《Proceedings of the Geologists' Association. Geologists' Association》2011,122(3):492-500
When first described in 1922, Dinocochlea ingens, an Early Cretaceous (Valanginian) fossil from the Wadhurst Clay Formation (Wealden) of Hastings in Sussex, England, was regarded as the steinkern of a huge gastropod over 2 m in length and claimed to be the largest gastropod ever to have lived. Most subsequent researchers have doubted the identity of D. ingens as a gastropod, usually believing it to be a pseudofossil, but no convincing explanation has been proposed for its origin. Restudy of the type material leads to the new hypothesis that Dinocochlea originated as a horizontal, corkscrew-shaped burrow resembling Helicodromites that acted as a nucleus for concretion growth. Sectioned specimens of Dinocochlea are filled with concentrically banded sediment interpreted to be growth rings of a concretion. Modification of a computer simulation designed to illustrate gastropod shell growth shows how the development of a concretion around a corkscrew-shaped burrow could lead to the morphology seen in Dinocochlea. The most likely tracemaker for Dinocochlea was a capitellid polychaete (‘threadworm’) with a body just a few mm in diameter. 相似文献
854.
The leaching behaviour of electrostatic precipitator dust from the Mufulira Cu smelter (Copperbelt, Zambia) was studied using a 48-h pH-static leaching experiment (CEN/TS 14997). The release of metals (Cd, Co, Cu, Ni, Pb and Zn) and changes in mineralogical composition using X-ray diffraction and PHREEQC-2 modelling were investigated in the pH range of 3–7. The highest concentrations of metals were released at pH 3–4.5, which encompasses the natural pH of the dust suspension (~4.3). About 40% of the total Cu was leached at pH 3, yielding 107 g/kg. Chalcanthite (CuSO4·5H2O), magnetite (Fe3O4) and delafossite (CuFeO2) represented the principal phases of the studied dust. In contact with water, chalcanthite was dissolved and hydrated Cu sulphates precipitated at pH 4–7. Gypsum (CaSO4·2H2O) and secondary Fe or Al phases were observed in the leached residues. Serious environmental impact due to leaching may occur in dust-contaminated soil systems in the vicinity of the smelting plants. 相似文献
855.
The Teplá–Barrandian unit (TBU) of the Bohemian Massif exposes a section across the once extensive Avalonian–Cadomian belt, which bordered the northern active margin of Gondwana during late Neoproterozoic. This paper synthesizes the state-of-the-art knowledge on the Cadomian basement of the TBU to redefine its principal component units, to revise an outdated stratigraphic scheme, and to interpret this scheme in terms of a recent plate-tectonic model for the Cadomian orogeny in the Bohemian Massif. The main emphasis of this paper is on an area between two newly defined fronts of the Variscan pervasive deformation to the NW and SE of the Barrandian Lower Paleozoic overlap successions. This area has escaped the pervasive Variscan (late Devonian to early Carboniferous) ductile reworking and a section through the Cadomian orogen is here superbly preserved.The NW segment of the TBU consists of three juxtaposed allochthonous belts of unknown stratigraphic relation (the Kralovice–Rakovník, Radnice–Kralupy, and Zbiroh–?árka belts), differing in lithology, complex internal strain patterns, and containing sedimentary and tectonic mélanges with blocks of diverse ocean floor (meta-)basalts. We summarize these three belts under a new term the Blovice complex, which we believe represents a part of an accretionary wedge of the Cadomian orogen.The SE segment of the TBU exposes the narrow Pi?ín belt, which is probably a continuation of the Blovice complex from beneath the Barrandian Lower Paleozoic, and a volcanic arc sequence (the Davle Group). Their stratigraphic relation is unknown. Flysch units (the ?těchovice Group and Svrchnice Formation) overlay the arc volcanics, and both units contain material derived from volcanic arc. The former was also sourced from the NW segment, whereas the latter contains an increased amount of passive margin continental material. In contrast to the Blovice complex, the flysch experienced only weak Cadomian deformation.The new lithotectonic zonation fits the following tectonic scenario for the Cadomian evolution of the TBU well. The S- to SE-directed Cadomian subduction beneath the TBU led to the involvement of turbidites, chaotic deposits, and 605 ± 39 Ma ocean floor in the accretionary wedge represented by the Blovice complex. The accretionary wedge formation mostly overlapped temporally with the growth of the volcanic arc (the Davle Group) at ~ 620–560 Ma. Upon cessation of the arc igneous activity, the rear of the wedge and some elevated portions of the arc were eroded to supply the deep-water flysch sequences of the ?těchovice Group, whereas the comparable Svrchnice Formation (~ 560 to < 544 Ma) was deposited in a southeasterly remnant basin close to the continental margin. The Cadomian orogeny in the TBU was terminated at ~ 550–540 Ma by slab breakoff, by final attachment of the most outboard ~ 540 Ma oceanic crust, and by intrusion of ~ 544–524 Ma boninite dikes marking the transition from the destructive to transform margin during the early/middle Cambrian. 相似文献
856.
Spatial and temporal analysis of global seismological data 1964–2005 reveals a distinct teleseismic earthquake activity producing
a columnar-like formation in the continental wedge between the Krakatau volcano at the surface and the subducting slab of
the Indo-Australian plate. These earthquakes occur continuously in time, are in the body-wave (m
b) magnitude range 4.5–5.3 and in the depth range 1–100 km. The Krakatau earthquake cluster is vertical and elongated in the
azimuth N30°E, suggesting existence of a deep-rooted fault zone cutting the Sunda Strait in the SSW-NNE direction. Possible
continuation of the fault zone in the SW direction was activated by an intensive 2002/2003 aftershock sequence, elongated
in the azimuth of N55°E. Beneath the Krakatau earthquake cluster, an aseismic gap exists in the Wadati-Benioff zone of the
subducting plate at the depths 100–120 km. We interpret this aseismic gap as a consequence of partial melting inhibiting stress
concentration necessary to generate stronger earthquakes, whereas the numerous earthquakes observed in the overlying lithospheric
wedge beneath the volcano probably reflect magma ascent in the recent plumbing system of the Krakatau volcano. Focal depth
of the deepest events (~100 km) of the Krakatau cluster constrains the location of the primary magma generation to greater
depths. The ascending magmatic fluids stress fault segments within the Sunda Strait fault zone and change their friction parameters
inducing the observed tectonic earthquakes beneath Krakatau. 相似文献
857.
858.
S. A. Medina-Moreno Ph.D. D. Jiménez-Islas Ph.D. J. N. Gracida-Rodríguez Ph.D. M. Gutiérrez-Rojas I. J. Díaz-Ramírez Ph.D. 《International Journal of Environmental Science and Technology》2011,8(3):471-482
A mathematical model to predict the rhamnolipids production by Pseudomonas aeruginosa from oleic acid in a two phase liquid-liquid batch reaction system, was developed in this study. The model was based on two theoretical assumptions: 1) the convective oleic acid mass transfer is coupled to a bioreaction in the aqueous liquid bulk, and 2) the volume of the immiscible oleic acid drops and the saturation concentration at the interface are a function of rhamnolipids production. The model was able to accurately predict the experimental growth of the Pseudomonas aeruginosa strain, and the rhamnolipids production data with oleic acid as carbon source. This mathematical approach indicated a high correspondence between the saturation dimensionless profiles of oleic acid at the interface and the experimental profiles of surface tension difference. This modeling approach may constitute a useful tool in the design and scaling-up of bioreactors applied to the production of biosurfactants with immiscible carbon sources. 相似文献
859.
Comparison of quantitative petrographic, stable isotope and cathodoluminescence data for fingerprinting Czech marbles 总被引:1,自引:1,他引:0
Various marbles from both historic quarries and historical artefacts of the Czech Republic were examined in order to make determinations of their provenance. The methodology used was based upon a combination of petrographic image analysis (PIA) of thin sections, stable isotope geochemistry of carbonates, and cathodoluminescence. Multivariate statistical methods (i.e. cluster analysis and discriminant analysis) confirmed the geoscientific relevance of the marble’s different characteristics with a high degree of consistency as well as the enhanced significance of stable C and O isotopes in correlation with the petrographic data. The qualitative cathodoluminescence data provided a useful additional tool to help recognise the fingerprinting of marbles with similar petrographic and/or geochemical characteristics. 相似文献
860.
M. I. Carretero M. Pozo F. Ruiz J. Rodríguez Vidal L. M. Cáceres M. Abad J. M. Muñoz F. Gómez J. M. Campos M. L. González-Regalado M. Olías 《Environmental Earth Sciences》2011,64(5):1215-1223
The multidisciplinary analysis of core sediments from Doñana National Park, south Spain, permits to delimitate both the paleoenvironmental changes and the geochemical evolution of this area during the Holocene. In a first phase (10–6.5 kyr cal), this area was occupied by freshwater/brackish marshes with periodical alternation of dry periods and humid intervals. In a second phase, these marshes were inundated during the Flandrian transgression (~6.5 kyr cal), with the deposition of bioclastic sands. The third phase (6.5–3.6 kyr cal) is characterized by the transition to an old lagoon, with unpolluted, bottom sediments. The geochemical concentrations of these clayey sediments can be used as a geochemical background for present-day and future environmental evaluations of this area. In the following 600 years approximately, two tsunamis caused the partial infilling of this area with bioclastic, marine sediments. In the interval comprised between these two tsunamis, this lagoon was polluted with heavy metals derived from historical mining activities. This environmental contamination represents one of the oldest evidences of mining pollution in the world (>3 kyr cal BP). 相似文献