In quest of Paleocene global-scale transgressions and regressions: constraints from a synthesis of regional trends

Chronostratigraphically-justified records of regional transgressions and regressions are important for understanding the nature of the Paleocene shoreline shifts on a global scale. Review of previously synthesized data from 7 tectonically “stable” regions, namely the eastern Russian Platform, Northwestern Europe, Northwestern Africa, Northeastern Africa, the Arabian Platform, the northern Gulf of Mexico, and Southern Australia, allows a comparison of transgressions and regressions interpreted in these regions. No common patterns are found in the early Danian and late Selandian, which reflects small or zero eustatic fluctuations that are overwhelmed locally on coastlines by regional tectonic motions and local changes in dynamic support of surface topography by mantle flow. Sea level was stabilized during these stages by a warm climate and a lack of planetary-scale tectonic changes. We have detected a middle–late Danian regression that occurred in 5 of 7 study regions, and can be explained by glacial advance at ～62–63 Ma or by concurrent subduction of the Izanagi–Pacific ridge beneath eastern Asia. An early–middle Selandian transgression also occurred in 5 regions, probably, as a result of a hyperthermal at ～61 Ma that coincided with emplacement of large igneous provinces in the oceanic domain. Both events are characterized by significant diachroneity, which can also be explained by the influence of regional tectonic subsidence or uplift. Results of the present study permit us to propose a tentative framework for a new Paleocene eustatic curve that is constrained globally using available records of transgressions and regressions.     

African Refugee Communities in Southeast Queensland: forces of concentration and dispersion

Black African refugee communities are a relatively recent addition to the Australia landscape. Between 2001 and 2007, over 5000 refugees from various African nations resettled in Queensland. There are very few data about African refugee settlement geography in Australia and no previous study delineating African refugee settlement within the State of Queensland. This research addresses the knowledge gap by examining the geographic distribution and secondary migration patterns of eight African refugee communities in Southeast Queensland. The research adopted a multi-method approach, mapping quantitative data from an existing secondary database and comparing these to qualitative primary data to determine geographical distribution. Additional qualitative data were used to establish secondary migration patterns of the case study communities. Results show noticeable discrepancies between existing secondary datasets and primary data collected from the communities. These inconsistencies are significant because settlement service providers who use the secondary data to budget, plan and deliver essential settlement services might be underestimating the size of the African communities and missing some settlement locations altogether. The results also reveal a tension between the main socio-cultural forces of concentration and housing forces of dispersion that are driving secondary migration in the communities. A policy recommendation to mitigate the potentially negative effects of residential dispersion on settlement outcomes includes the strategic location of service hubs in key suburbs, such as Moorooka, to which the communities are already drawn.     

Air-based measurements of permeability in pebbly sands

We considered small-scale measurement of permeability in pebbly sands having coarser grains supported in a finer grained matrix (fine packing). Our central question was whether air-based measurements are representative if made with a permeameter tip seal pressed in the sand matrix. We created pebbly sands and variably sorted sands, with systematic variation in aspects of their fine packing. We made permeability measurements by inserting the tip seal of an air permeameter in the matrix of these samples and compared them to the permeability of the composite sample determined by both water-based methods and theory. The air-permeameter measurements made in this way represent the permeability of the composite mixtures of coarser and finer grains and allow for the discernment of permeability between samples with different matrix compositions, ranging from fine to coarse sand. Furthermore, the collective results show that permeability differences in the pebbly sands and variably sorted sands with fine packing, however measured, are primarily due to differences in matrix permeability and not due to differences in the size or the percentage of the coarser grains.     

Determination of Trace Elements in Twenty Six Chinese Geochemistry Reference Materials by Inductively Coupled Plasma-Mass Spectrometry

We report new data for thirty seven elements determined in twenty six Chinese geochemistry reference materials using inductively coupled plasma-mass spectrometry and a reliable and simple dissolution technique. One hundred milligrams of sample were digested with 1 ml of HF and 0.5 ml of HNO₃ in PTFE-lined stainless steel bombs heated to 200 °C for 12 hours. Insoluble residues were dissolved using 6 ml of 40% v/v HNO₃ heated to 140 C for 3 hours. Analytical calibration was accomplished using aqueous standard solutions. Rhodium was used as an internal standard to correct for matrix effects and instrument drift. Precisions were typically better than 5% RSD. Most of the data presented here agree well with the published certified values. For the elements Zr, Hf and most other trace elements, the measured values were less than 10% in error when compared to certified values.     

Analysis of the surface temperature and wind forecast errors of the NCAR-AirDat operational CONUS 4-km WRF forecasting system

Investigating the characteristics of model-forecast errors using various statistical and object-oriented methods is necessary for providing useful guidance to end-users and model developers as well. To this end, the random and systematic errors (i.e., biases) of the 2-m temperature and 10-m wind predictions of the NCAR-AirDat weather research and forecasting (WRF)-based real-time four-dimensional data assimilation (RTFDDA) and forecasting system are analyzed. This system has been running operationally over a contiguous United States (CONUS) domain at a 4-km grid spacing with four forecast cycles daily from June 2009 to September 2010. In the result an exceptionally useful forecast dataset was generated and used for studying the error properties of the model forecasts, in terms of both a longer time period and a broader coverage of geographic regions than previously studied. Spatiotemporal characteristics of the errors are investigated based on the 24-h forecasts between June 2009 and April 2010, and the 72-h forecasts between May and September 2010. It was found that the biases of both wind and temperature forecasts vary greatly seasonally and diurnally, with dependency on the forecast length, station elevation, geographical location, and meteorological conditions. The temperature showed systematic cold biases during the daytime at all station elevations and warm biases during the nighttime above 1,000 m above sea level (ASL), while below 600 m ASL cold biases occurred during the nighttime. The forecasts of surface wind speed exhibited strong positive biases during the nighttime, while the negative biases were observed in the spring and summer afternoons. The surface wind speed was mostly over-predicted except for the stations located between 1,000 and 2,100 m ASL, for which negative biases were identified for most forecast cycles. The highest wind-speed errors were found over the high terrain and near sea-level stations. The wind-direction errors were relatively large at the high-terrain elevation in the Rocky and Appalachian mountain ranges and the western coastal areas and the error structure exhibited notable diurnal variability.     

The Cretaceous-Tertiary fireball layer,ejecta layer and coal seam: Platinum-group element content and mineralogy of size fractions

Abstract— Grain size separates of the Cretaceous-Tertiary (K-T) fireball layer at marine sites and the entire K-T boundary interval at nonmarine sites (fireball layer, ejecta layer, coal seam) were analysed for platinum-group elements (PGE: Ru, Ir, Ft, Pd, Rh) and Au using inductively coupled plasma mass-spectrometry. X-ray diffractometry and scanning electron microscopy were performed on each fraction to establish the mineralogy. It was determined that the most abundant minerals in the finest fraction were a smectite-group mineral at marine K-T sites and illite-smectite mixed layer clay at nonmarine K-T sites. Positive correlation of PGE content and mineralogy indicates that the PGE are presently associated with these clay minerals which were likely formed by alteration of a condensed mafic phase (e.g., olivine or pyroxene). The correlation of clay mineral abundance with PGE content is imperfect because not all of the clay minerals in the fireball layer are derived by alteration of the original condensed ejecta. In addition, undetected PGE host(s), present in trace amounts, are likely also present.     

Assessment of the historical trace metal contamination of sediments in the Elizabeth River, Virginia

Two sediment cores (Southern Branch, PC-1, and Western Branch, WB-2) were taken from the highly industrialized Elizabeth River, Virginia. The concentrations of trace metals cadmium, cobalt, chromium, copper, nickel, lead and zinc, major elements iron, manganese and aluminum, organic carbon content and the specific surface area of the sediments were determined in each of the cores. Down-core variations in metals varied significantly in each core with maximum contamination events occurring at different times in different portions of the river. In PC-1, maximum metal concentrations were seen after the appearance of (137)Cs. In contrast, the highest levels in WB-2 occurred well before the appearance of (137)Cs. Although stricter environmental regulations have caused a decrease in metal concentrations since the 1980s, the concentrations in the surface sediments of many trace metals were elevated to levels 2-5 times higher than the levels at the bottom of the cores in both the Southern and Western Branches of the river.