Geomagnetic activity dependence of O in transit from the ionosphere

Energetic O⁺ ions have important dynamic effects on the ring current. Insights into the effects of O⁺ on ring current dynamics have come primarily from models, not observations. Here, we discuss observations of O⁺ populations escaping from the ionosphere and their access to the plasma sheet and ring current. We review data establishing that a significant flux of O⁺ escapes the ionosphere during geomagnetically quiet intervals. We then estimate the relative magnitude of the O⁺ population in transit between the ionosphere and ring current during quiet intervals before geomagnetic storms. Our analysis suggests that dynamic reconfigurations of the magnetosphere during geomagnetic storms significantly alter the O⁺ transport paths from the ionosphere to the ring current. During these reconfigurations some of the pre-existing, quiet time, in-transit O⁺ populations are captured on magnetic field lines leading to the ring current. The prompt appearance of this O⁺ population in the ring current could modify the evolution of the ring current in the storm growth phase. Our analysis suggests that the consequences of an activity-dependent O⁺ transport path to the ring current should be systematically investigated.     

Mechanical behaviour of Lixhe chalk partly saturated by oil and water: experiment and modelling

Two or more different fluids generally saturate chalk in oil reservoir, and therefore its behaviour can be very complicated. In this paper, a constitutive law is proposed for modelling the mechanical behaviour of a chalk saturated by two non‐miscible fluids, water and oil. The effects of the capillary pressure or suction are taken into account. They are considered as an independent variable, as in the Barcelona's basic model developed for unsaturated soils. On the other hand, internal friction and pore collapse are modelled as independent mechanisms. The determination of the parameters is based on triaxial and oedometer tests. Finally, in order to validate the model, predictions are compared with experimental results of water‐flooding test. Copyright © 2002 John Wiley & Sons, Ltd.     

The nature of olefins and carboxyl groups in an Australian brown coal resin

The chemical structure of the resin from an Australian soft brown coal (Yallourn) has been investigated by cross-polarization nuclear magnetic resonance spectroscopy with magic angle spinning (¹³C CP MAS NMR). Some additional solution ¹H and ¹³C data were also obtained. Solid-state experiments were performed with and without a delay period before data acquisition. The resulting free induction decays were Fourier transformed with respect to acquisition time and delay period to produce two-dimensional solid-state spectra. Assignments made from the spectra clearly demonstrate that the gross chemical structure of the Yallourn resin is best described as a polymerized diterpenoid with one axial carboxylic group and two double bonds. One double bond is trisubstituted, the other is monosubstituted. After consideration of various mechanisms for polymerization of diterpenoid units during biogenesis and coalification, it was concluded that polymerization occurs at the C₁₅ carbon atoms in the diterpenoids without cyclization of the methylene units at C₈.     

GEOMORPHOLOGICAL PHOTOGRAMMETRY

The broad requirements of the geomorphologist for original mapping are reviewed. The extent to which aerial photogrammetry can meet these requirements is exemplified through typical approaches and mapping products in fluvial, coastal and glacial specialisms.     

High-resolution cyclostratigraphic analysis from magnetic susceptibility in a Lower Kimmeridgian (Upper Jurassic) marl–limestone succession (La Méouge,Vocontian Basin,France)

High-resolution magnetic susceptibility (MS) analysis was carried out on a Lower Kimmeridgian alternating marl–limestone succession of pelagic origin that crops out at La Méouge (Vocontian Basin, southeastern France). The aim of the study was to characterize the strong, dm-scale sedimentary cyclicity of the succession at a very high resolution, and to analyze the cycles for evidence of astronomical forcing. From marl to limestone, MS varies progressively and closely tracks the highest frequency cyclicity corresponding to the basic marl–limestone couplets. Long-term wavelength cycling modulates the high-frequency cyclicity (couplets), and appears to be controlled by clay content. Spectral analysis of the MS record reveals the presence of the complete suite of orbital frequencies in the precession, obliquity, and eccentricity (95–128 ka and 405 ka) bands with very high amplitude of the precession index cycles originating from dm-scale couplets. 405 ka-eccentricity cycles are very pronounced in the MS maxima of the marl members of the couplets, suggesting eccentricity-driven detrital input to the basin. 405 ka-orbital tuning of the MS maxima further sharpens all of the orbital frequencies present in the succession. These results are similar to those of previous studies at La Méouge that used carbonate content observed in field. Our results are also in accordance with cyclostratigraphic studies in Spain and Canada that report dominant precession index forcing. By contrast, in the Kimmeridge Clay (Dorset, UK), obliquity forcing dominates cyclic sedimentation, with weaker influence from the precession index. Ammonite zone duration estimates are made by counting the interpreted precession cycles, and provide an ultra-high resolution assessment of geologic time. In sum, this study demonstrates the power of the MS as a proxy in characterizing the high-resolution cyclostratigraphy of Mesozoic sections, particularly in alternating marl–limestone successions, and for high-resolution correlation and astronomical calibration of the geologic time scale.     

Study of the soil–atmosphere moisture exchanges through convective drying tests in non‐isothermal conditions

This paper deals with the moisture exchanges occurring between soils and the surrounding atmosphere. Convective drying tests are performed on Awans silts at different drying temperatures and air relative humidities in order to reproduce the natural drying conditions. The experiments improve the understanding of the vapour transfers kinetics between the soil samples and the atmosphere. The experimental results are analysed assuming that the transfers take place in a boundary layer existing at the surface of the porous medium. The influence of the thermal conditions on the evaporation is also taken into account. In our model, coupled vapour and energy exchanges are controlled by mass and heat transfer coefficients characterizing the boundary layer. These coefficients are determined from the drying experiments. The modelling of the drying tests in non‐isothermal conditions is performed in order to validate the formulation of the vapour and heat exchanges. The numerical results present a good agreement with the kinetic of the materials desaturation determined during the tests. The analysis of the moisture transport mechanisms into the sample and at the boundary shows that at the beginning of the test, the drying is first achieved by the transport of moisture in its liquid form and its evaporation at the sample outer boundary in contact with the atmosphere. In a second step, vapour diffusion becomes predominant into the sample and it corresponds to the most important decrease of relative humidity. Copyright © 2009 John Wiley & Sons, Ltd.