钛胶海水提铀动力学研究Ⅱ——吸附机理的推断

海水提铀机理的研究,已逐渐受到重视,然而,至今研究还不是很深入,观点也各有差别.例如,Keen等[1]认为钛胶从海水中吸附铀是阳离子交换过程,即海水中的铀是UO₂2+离子的形式与钛胶进行交换;尾方升等[2]则倾向于阴离子吸着,即铀是以UO₂(CO₃)₃4-的形式被吸附.我们曾于1973年在海洋局系统的一次会议上提出阳离子给合交换的看法,并在后来的两次专业会议上予以补充发展.张正斌[3]认为是阳离子交换或一价阳离子失水络合.最近崔清晨[4]提出可能是UO₂(OH)₃-的络合吸附.根据几年来的工作,我们仍认为,钛胶从海水中的吸铀机理可能是一种阳离子形式的络合交换过程.     

海水中微量元素无机离子交换动力学研究——液膜递进模型理论 Ⅰ.天然海水条件下

最近十几年来,海水物理化学中关于海水的化学热力学研究已较广泛地开展,并已有一些重要的研究结果报导。但是,关于海水中化学动力学的研究,至今却基本上仍属空白。然而这正是海洋中许多化学过程(特别像海水化学资源开发、海洋污染和防治等实践性比较强的领域中)要解决的关键问题。本文是我们从事这一方面研究工作的第一篇报导,讨论的内容是海洋中最重要的过程之一——无机离子交换过程。     

Study on the characteristics of the marine boundary layer in the Equatorial Pacific

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Caught in the act: the 20 December 2001 gravity flow event in Monterey Canyon

A sediment gravity flow descended through the axis of Monterey Canyon on 20 December 2001 at 13:35 Pacific standard time. The timing of this event is documented by a current-meter package which recorded an 11.9-dbar pressure increase in less than 10 min and was found 550 m down-canyon from its deployment site, buried completely within a >70-cm-thick gravity flow deposit. This event is believed to have started in less than 290 m of water because an instrument at this location was also lost at the same time. A 178-cm core collected after the event from the axis of the canyon at 1,297-m water depth contained fresh, greenish, chlorophyll-rich organic material at 32-cm sub-bottom depth, suggesting the event extended to this water depth. The only trigger identified for this mass movement event appears to be moderate sea and surf conditions. Thus, gravity flow events of this magnitude do not require an exceptional triggering event.     

Treatment of Hydrodynamic Loading for Random Sea State

- In order to employ cost effective frequency domain analysis for off-shore structures treatment of hydrodynamic loading is essential. Drag and inertia dominated, resonating and antiresonating cases under random sea states are analyzed to highlight the implications and relative merits of four salient linearization techniques.     

Freshening of the Intermediate Waters in the Northern South China Sea over the PastSix Decades

The properties of salinity in the South China Sea (SCS), a significant marginal sea connecting the Pacific andIndian Oceans, are greatly influenced by the transport of fresh water flux between the two oceans. However, the long-termchanges in the intermediate water in the SCS have not been thoroughly studied due to limited data, particularly in relationto its thermodynamic variations. This study utilized reanalysis data products to identify a 60-year trend of freshening in theintermediate waters of the northern South China Sea (NSCS), accompanied by an expansion of low-salinity water. Thestudy also constructed salinity budget terms, including advection and entrainment processes, and conducted an analysis ofthe salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of theintermediate water in the NSCS. The analysis revealed that the freshening in the northwest Pacific Ocean and theintensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes inthe NSCS. Additionally, a weakened trend in the intensity of vertical entrainment also contributes to the freshening in theNSCS. This study offers new insights into the understanding of regional deep sea changes in response to variations in boththermodynamics and oceanic dynamic processes.     

频率域电磁法中视电阻率全区定义

视电阻率定义在电法勘探中得到广泛的应用。目前在频率域电磁法中常常采用远区视电阻率定义。由于在频率域中收发距并非足够大,以致在低频段远区定义视电阻率往往不能反映地下电阻率值。我们定义全区电阻率及引入校正系数K,经二层三层模型及野外实测资料的计算,证明了方法的有效性。