Experimental hydrogen isotope studies III: Diffusion of hydrogen in hydrous minerals,and stable isotope exchange in metamorphic rocks

Diffusion parameters for hydrogen diffusion in epidote-group minerals and micas have been measured under hydrothermal conditions, or calculated from existing experimental data, for bulk hydrogen isotope exchange experiments between hydrous minerals and water. Activation energies in the range 14 to 31 kcals/g-atom H are comparable to those derived by application of kinetic theory to experimental hydrogen isotope exchange data, and to those for oxygen diffusion in minerals under hydrothermal conditions. Diffusion of hydrogen in epidote is about four orders of magnitude faster than in muscovite, and about two orders of magnitude faster than in zoisite. Hydrogen diffusion in micas is about five orders of magnitude faster than oxygen diffusion, and hydrogen transport occurs dominantly parallel to the layers rather than parallel to the c-axis as for oxygen.Rapid hydrogen transport in minerals may proceed by hydrolysis of Si-O and Al-O bonds, followed by exchange of hydrolyzed oxygens with slower-diffusing (OH) or H₂O. Water appears to be essential for stable isotope exchange between minerals in slowly cooling metamorphic rocks.Stable isotope data for regional metamorphic mineral assemblages suggests that water is usually present in small amounts during cooling of prograde regional metamorphic systems, and estimated closure temperatures for cessation of stable isotope exchange are often more comparable to those calculated from diffusion data than to likely temperatures of metamorphism.Alpine deformation of the Hercynian Monte Rose Granite (Frey et al. 1976) permitted access of water and initiated stable isotope exchange amongst coexisting minerals. The diffusional behaviour of species in relict Hercynian muscovites is consistent with available experimental diffusion data.     

Past explosion and future threat: Exacerbation of red water disease (Schistosomiasis haematobium) in the Upper Region of Ghana

An historical reconstruction is offered which suggests that the hyperendemicity of red water or Schistosomiasis haematobium in Ghana's Upper Region may have been, in part, an inadvertent by-product of agricultural development, through the construction of a large number of agricultural dams in an endemic area some 20 years ago. No disease prevention measures were undertaken in conjunction with the building of the dams, and S. haematobium prevalence may have been tripled in consequence. Certainly river blindness and probably other water-related diseases were also affected. Cyclical labor migration disseminates schistosomiasis southwards from the hyperendemic zone to those transmission sites where suitable snail hosts are to be found. History may be about to repeat itself in 1981 – 1985 in that a new wave of construction of dams will commence in the region; again without the concurrent introduction of any measures for disease control. Integrated planning is needed to prevent disease exacerbation by agriculture.     

Gas adsorption on crushed quartz and basalt

The new surfaces generated by crushing rocks and minerals adsorb gases. Different gases are adsorbed to different extents so that both the total amount and composition of the released gases are changed. This affects the interpretation of the composition of the gases obtained by vacuum crushing lunar basalts, meteorites and minerals with fluid inclusions.     

Salinity stress in harpacticoid copepods

Three species of intertidal harpacticoid copepods,Tigriopus japonicus, Tachidius brevicornis andTisbe sp., were tested for their response to salinities ranging from 0‰ to 210‰. At 90‰Tigriopus became dormant, but could be reanimated if placed in 30‰ seawater within 18 hours.Tachidius became dormant at 60‰ but could also be revived if placed in 30‰ seawater.Tisbe died shortly after an exposure to seawater of 45‰. Death was brought about inTigriopus andTachidius by salinities of 150‰. Naupliar, copepodite, and adult stages ofTigriopus withstood the salinities equally well, while egg sacs could tolerate five times the length of exposure of these stages. The respiratory rate ofTigriopus was 3.76 (±1.32) μl 0₂ hr^?1 for active adults and 0.03 (±0.01) nl 0₂ hr^?1 mg dry wt^?1 for adults in the dormant state. The duration of dormancy, with successful revival, appears to be limited to the time before the loss of the vital water content of the tissues due to the high osmotic pressure. The ability to enter dormancy in times of stress may have high survival value to some intertidal copepods.     

Bedrock freeze-thaw weathering regime in an alpine environment,colorado front range

Reduced major axis analysis is used to describe monthly temperature averages for daily maxima, minima, means and ranges at a sequence of bedrock microenvironments in the alpine zone of the Colorado Front Range. Seven thermistors buried at 1 cm in bedrock provide comparative data on easterly, southerly and westerly aspects, and also upon the impact of snow accumulation (?0.5m to ≥4.0m deep) against an east-facing rock wall. Intersite temperatures commonly differ by less than 5°C and, rarely, by more than 10°C. The freezing intensity of freeze-thaw cycles occurring within the confines of a seasonal snow patch rarely dropped to ?5°C, while at snowfree, vertical faces freezing dropped to ?5°C quite commonly. Comparison with laboratory established criteria for effective freeze-thaw weathering (abundant moisture and freezing to at least ?5°C) suggests that moisture rich microsites lack adequate freezing intensity, while adequately frozen sites lack moisture. Available data suggest that the overlap between freeze-thaw and hydration weathering requires careful re-evaluation.     

Experimental hydrogen isotope studies,II. Fractionations in the systems epidote-NaCl-H2O,epidote-CaCl2-H2O and epidote-seawater,and the hydrogen isotope composition of natural epidotes

The hydrogen isotope fractionation factors between epidote and aqueous 1 M and 4 M NaCl, 1 M CaCl₂ solutions, and between epidote and seawater, have been measured over the temperature range 250–550°C over which the degree of dissociation of dissolved species varies significantly. Measured fractionations at 350°C are decreased by up to 12‰, 9‰ and 7‰ relative to pure water in seawater, 1 M CaCl₂ and 1 M NaCl respectively, while above 500°C fractionations are not measurably dependent on fluid composition. Water—solution fractionation factors are derived which are generally applicable to the correction of mineral—water hydrogen isotope fractionations for the composition of the fluid phase.The hydrogen isotope compositions of natural epidotes are interpreted in the light of experimental fractionation data for situations where temperature, δD (fluid), and, in some cases, fluid chemistry, are independently known. Epidotes from active geothermal systems have hydrogen isotope quench temperatures consistent with or close to measured well temperatures unless the measured temperature has declined substantially since epidote formation or there is uncertainty in the D/H ratio of the water associated with the epidote because of isotopic heterogeneity in the well waters. Hydrothermal and metamorphic epidotes show closure temperatures of 175–225°C and 200–250°C. There is no evidence that retrograde metamorphic fluids, if present, are isotopically different from prograde fluids.The water-solution fractionations indicate strong solute-solvent interactions between 250 and 450°C and imply that both dissociated and associated species contribute to the fractionation effects through modification of the orientations and structure of the water molecules. Solute-solvent interactions become negligible at temperatures around 550°C.     

Depositional environments of some Pleistocene coastal terrace deposits,southwestern Oregon—case history of a progradational beach and dune sequence

Pleistocene coastal terrace deposits exposed in sea cliffs near Gold Beach, Oregon can be divided into four stratigraphic units: a basal gravelly unit and three overlying sandy units, each with mud beds, a paleosol, or the modern soil in its uppermost part. The gravelly unit consists of gravel and sand in its lower part, sand, in part pebbly or cobbly, in its middle part, and mud and sand in its upper part. Black sand and transported pieces of wood are common in the middle part of the unit, and wood is common in the mud. This unit is interpreted as a progradational deposit including environments ranging from lower forebeach at the base to backbeach flats and streams at the top.The main sandy parts of the sandy units are made up of a crossbedded sand facies, the dominant structure in which is medium-scale crossbedding, and an irregularly bedded sand facies, which is locally pebbly and is dominated by scour-and-fill structures. Deciding between shallow marine and eolian interpretations of the sandy units proved exceptionally difficult until modern analogues were found in the fine details of the internal structures. Largely on the basis of such structural details, the crossbedded sand facies is interpreted as the product of small eolian dunes, and the irregularly bedded sand facies is interpreted as deposits of interdune ephemeral streams, ephemeral ponds, and wet to dry subaerial flats. The mud beds and paleosols at the tops of the sandy units represent times of temporary stabilization of the dune field.     

Crustal development in the Kaapvaal craton, II. The Proterozoic

The relationship in time and space of the elements comprising the greenstone—granitie terrane in the eastern Transvaal and Swaziland is discussed. On the evidence derived from structural analysis, metamorphic style, geochemistry, and geophysics it is concluded that sialic crust (now represented by the Ancient Gneiss Complex in Swaziland) pre-dates the Swaziland Sequence. It is postulated that the sialic crust formed as a result of partial and total melting of hydrous basaltic lithosphere under tectonically metastable conditions. Limited sedimentation and volcanism in small basins on this early crust took place during periods of quiescence, following which deformation resulted in the tectonic interslicing of the early sialic crust and the sedimentary—volcanic sequences that were metamorphosed at high temperatures and low pressure (Abukuma-type), and included limited partial melting. The protocontinental crust so formed was distended along linear zones overlying sites of mantle upwelling. Rifting resulted from the distension and was accompanied by intense volcanism typical of greenstone belts. Following mantle withdrawal sagging was initiated in the linear zone leading to sedimentation that was initially of turbidite type. As greater stability was achieved, the style of sedimentation changed and cratonic-type, Moodies Group sediments were deposited. The cyclic nature of the volcanism and sedimentation is considered to be a response to, and a reflection of, the degree of distension and of the vertical adjustments along the bounding faults. Diapiric rise of tonalitic magma produced as a result of partial melting of the early sialic crust mixing with mantle material caused the deformation of the original linear geometry. Continued depression of the amphibolite facies of the sialic crust into the zone of partial melting gave rise to potassic granitic magma that spread at higher crustal levels at interfaces of low free energy to form hood-like sheets of granite flanking the original linear rift. It is concluded that the eastern Transvaal and Swaziland area attained a crustal thickness of ± 25 km prior to 3.0 b.y.