Tar ball frequency data and analytical results from a long-term beach monitoring program

Following the spill of fuel oils from the New Carissa in February 1999, approximately 300 km of beaches on the Pacific coast of North America were surveyed. A long-term observation program focused on the documentation of stranded tar balls in the vicinity of the spill site. Systematic beach surveys which were conducted over the period March 1999 to April 2001 and semi-logarithmic scale, time-series plots proved the most useful format for identifying trends. Beach monitoring continued through to August 2001. by which time 212 tar balls had been analyzed by GC/MS for their chemical characteristics. The samples of tar balls collected between February 1999 and August 2001 were qualitatively compared with New Carissa source oils (NCSO) and 101 (48%) were not consistent with NSCO. The presence of tar balls that are not related to an incident can confound attempts to define cleanup or endpoint criteria and to assess possible injury to natural resources.     

Pollen representation,source area,and basin size: Toward a unified theory of pollen analysis

The concepts of pollen source area and of production and dispersal biases in pollen representation are quantified by means of a simple theoretical model. Source areas and relative pollen representation are shown to depend on basin size according to functions that describe the amount of pollen remaining airborne at increasing distances from single pollen sources. The form of these functions is determined by physical processes. Standard formulas for elevated sources do not apply, but the integrated form of Sutton's equation for particle dispersal from a ground-level source gives useful approximations applicable to pollen transport over a forest canopy. Simulations using this equation yielded source areas that increased realistically with basin size, showed substantial differences between source areas for pollen grains with different deposition velocities, and predicted that lighter pollen grains should become better represented with increasing basin size. All of these predictions are qualitatively consistent with present knowledge of the characteristics of pollen assemblages in different depositional environments. The model further allows parameters that can be estimated by statistical calibration methods to be predicted from underlying physical quantities. This extension suggests procedures for testing the theory with quantitative data on surface pollen and forest composition. Preliminary results showed reasonable agreement between estimated and predicted values of dispersal indices for the most abundant taxa in pollen spectra from the northern midwestern United States.     

基于分布式大流域径流模型的中国西北黑河流域水文模拟

水资源短缺是中国西北干旱地区长期的问题,区域人口增加、城市化扩张,加之气候变化的影响进一步加剧了西北地区水资源短缺,也使生活用水、灌溉用水、工业用水和维持生态系统稳定的用水危险加剧.采用分布式大流域径流模型(DLBRM)模拟黑河流域水文(中国第二大内陆河,流域面积128 000 km2)来理解区域的冰川和积雪融化水、地下水、地表水、蒸散发等方面的分布,评估气候变化对水文的影响和冰川退缩对中游和下游来水量的影响.模拟结果表明,黑河流域的大部分产流那源于黑河上游地区的祁连山.模拟1990-2000年黑河河流日流量变化结果认为,黑河中游正义峡给下游的供水为10×108m3,其中地表径流占51%,层间流占49%.中游地区沙土具有较高的蒸腾发能力,近一半的地表水被蒸发掉.模拟实践证明,分布式大流域径流模型可以结合气候变化、水资源管理方面的成果,改进流域水文模拟的精度.     

Experimental hydrogen isotope studies III: Diffusion of hydrogen in hydrous minerals,and stable isotope exchange in metamorphic rocks

Diffusion parameters for hydrogen diffusion in epidote-group minerals and micas have been measured under hydrothermal conditions, or calculated from existing experimental data, for bulk hydrogen isotope exchange experiments between hydrous minerals and water. Activation energies in the range 14 to 31 kcals/g-atom H are comparable to those derived by application of kinetic theory to experimental hydrogen isotope exchange data, and to those for oxygen diffusion in minerals under hydrothermal conditions. Diffusion of hydrogen in epidote is about four orders of magnitude faster than in muscovite, and about two orders of magnitude faster than in zoisite. Hydrogen diffusion in micas is about five orders of magnitude faster than oxygen diffusion, and hydrogen transport occurs dominantly parallel to the layers rather than parallel to the c-axis as for oxygen.Rapid hydrogen transport in minerals may proceed by hydrolysis of Si-O and Al-O bonds, followed by exchange of hydrolyzed oxygens with slower-diffusing (OH) or H₂O. Water appears to be essential for stable isotope exchange between minerals in slowly cooling metamorphic rocks.Stable isotope data for regional metamorphic mineral assemblages suggests that water is usually present in small amounts during cooling of prograde regional metamorphic systems, and estimated closure temperatures for cessation of stable isotope exchange are often more comparable to those calculated from diffusion data than to likely temperatures of metamorphism.Alpine deformation of the Hercynian Monte Rose Granite (Frey et al. 1976) permitted access of water and initiated stable isotope exchange amongst coexisting minerals. The diffusional behaviour of species in relict Hercynian muscovites is consistent with available experimental diffusion data.     

Bayesian modelling the retreat of the Irish Sea Ice Stream

We present an 8000‐year history spanning 650 km of ice margin retreat for the largest marine‐terminating ice stream draining the former British–Irish Ice Sheet. Bayesian modelling of the geochronological data shows the ISIS expanded 34.0–25.3 ka, accelerating into the Celtic Sea to reach maximum limits 25.3–24.5 ka before a collapse with rapid marginal retreat to the northern Irish Sea Basin (ISB). This retreat was rapid and driven by climatic warming, sea‐level rise, mega‐tidal amplitudes and reactivation of meridional circulation in the North Atlantic. The retreat, though rapid, is uneven, with the stepped retreat pattern possibly a function of the passage of the ice stream between normal and adverse ice bed gradients and changing ice stream geometry. Initially, wide calving margins and adverse slopes encouraged rapid retreat (～550 m a^?1) that slowed (～100 m a^?1) at the topographic constriction and bathymetric high between southern Ireland and Wales before rates increased (～200 m a^?1) across adverse bed slopes and wider and deeper basin configuration in the northern ISB. These data point to the importance of the ice bed slope and lateral extent in predicting the longer‐term (>1000 a) patterns and rates of ice‐marginal retreat during phases of rapid collapse, which has implications for the modelling of projected rapid retreat of present‐day ice streams. Copyright © 2013 John Wiley & Sons, Ltd.     

Probabilistic domain decomposition for the solution of the two-dimensional magnetotelluric problem

Probabilistic domain decomposition is proposed as a novel method for solving the two-dimensional Maxwell’s equations as used in the magnetotelluric method. The domain is split into non-overlapping sub-domains and the solution on the sub-domain boundaries is obtained by evaluating the stochastic form of the exact solution of Maxwell’s equations by a Monte-Carlo approach. These sub-domains can be naturally chosen by splitting the sub-surface domain into regions of constant (or at least continuous) conductivity. The solution over each sub-domain is obtained by solving Maxwell’s equations in the strong form. The sub-domain solver used for this purpose is a meshless method resting on radial basis function-based finite differences. The method is demonstrated by solving a number of classical magnetotelluric problems, including the quarter-space problem, the block-in-half-space problem and the triangle-in-half-space problem.     

Periglacial trimlines,former nunataks and the altitude of the last ice sheet in Wester Ross,northwest Scotland

High-level weathering limits separating ice-scoured topography from frost-weathered detritus were identified on 28 mountains in Wester Ross at altitudes of 700–960 m, and a further 22 peaks support evidence of ice scouring to summit level. Weathering limits are defined most clearly on sandstone and gneiss, which have resisted frost shattering during the Late Devensian Lateglacial, but can also be distinguished on schists and quartzite. Schmidt hammer measurements and analyses of clay mineral assemblages indicate significantly more advanced rock and soil weathering above the weathering limits. The persistence of gibbsite above weathering limits indicates that they represent the upper limit of Late Devensian glacial erosion. The regular decline of weathering-limit altitudes along former flowlines eliminates the possibility that the weathering limits represent former thermal boundaries between protective cold-based and erosive warm-based ice. The weathering limits are therefore interpreted as periglacial trimlines that define the maximum surface altitude of the last ice sheet. Calculated basal shear stresses of 50–95 kPa are consistent with this interpretation. Reconstruction of ice-sheet configuration indicates that the former ice-shed lay above 900 m along the present watershed, and that the ice surface descended northwestwards, with broad depressions along major troughs and localised domes around independent centres of ice dispersal. Extrapolation of the ice surface gradient and altitude suggests that the ice sheet did not overrun the Outer Hebrides, but was confluent with the independent Outer Hebrides ice-cap in the North Minch basin. Erratics located up to 140 m above the reconstructed ice surface are inferred to have been emplaced by a pre-Late Devensian ice sheet (or ice sheets) of unknown age. © 1997 John Wiley & Sons, Ltd.