Chemical Characterisation of Natural Ilmenite: A Possible New Reference Material

Seven ilmenite (FeTiO₃) megacrysts derived from alnöite pipes (Island of Malaita, Solomon Islands) were characterised for their major and trace element compositions in relation to their potential use as secondary reference materials for in situ microanalysis. Abundances of thirteen trace elements obtained by laser ablation ICP‐MS analyses (using the NIST SRM 610 glass reference material) were compared with those determined by solution‐mode ICP‐MS measurements, and these indicated good agreement for most elements. The accuracy of the LA‐ICP‐MS protocol employed here was also assessed by repeated analysis of MPI‐DING international glass reference materials ML3B‐G and KL2‐G. Several of the Malaitan ilmenite megacrysts exhibited discrepancies between laser ablation and solution‐mode ICP‐MS analyses, primarily attributed to the presence of a titano‐magnetite exsolution phase (at the grain boundaries), which were incorporated solely in the solution‐mode runs. Element abundances obtained by LA‐ICP‐MS for three of the ilmenite megacrysts (CRN63E, CRN63H and CRN63K) investigated here had RSD (2s) values of < 20% and therefore can be considered as working values for reference purposes during routine LA‐ICP‐MS analyses of ilmenite.     

Current state of knowledge regarding the world’s wetlands and their future under global climate change: a synthesis

Wetlands cover at least 6 % of the Earth’s surface. They play a key role in hydrological and biogeochemical cycles, harbour a large part of the world’s biodiversity, and provide multiple services to humankind. However, pressure in the form of land reclamation, intense resource exploitation, changes in hydrology, and pollution threaten wetlands on all continents. Depending on the region, 30–90 % of the world’s wetlands have already been destroyed or strongly modified in many countries with no sign of abatement. Climate change scenarios predict additional stresses on wetlands, mainly because of changes in hydrology, temperature increases, and a rise in sea level. Yet, intact wetlands play a key role as buffers in the hydrological cycle and as sinks for organic carbon, counteracting the effects of the increase in atmospheric CO₂. Eight chapters comprising this volume of Aquatic Sciences analyze the current ecological situation and the use of the wetlands in major regions of the world in the context of global climate change. This final chapter provides a synthesis of the findings and recommendations for the sustainable use and protection of these important ecosystems.     

Internal structure of a trough blowout, determined from migrated ground-penetrating radar profiles

Ground‐penetrating radar (GPR) was used to investigate the relationship between the geomorphological development of a large aeolian trough blowout and the stratigraphy and internal sedimentary structure of its associated deposits. Although analogous, many of the data‐processing techniques routinely applied in seismic reflection are very rarely applied in GPR studies. In this study, a simple migration program was used that significantly enhanced the quality of GPR images from a large trough blowout at Raven Meols on the Sefton coast, northwest England. These improvements aided subsequent data interpretation, which was achieved through application of the principles of radar stratigraphy. GPR shows the pre‐blowout dunes to have a complex internal structure that suggests they were formed in the presence of at least a partial vegetation cover. Subsequent to stabilization of these dunes a thin soil developed. This dune soil forms an important radar sequence boundary and delineates a complex topography beneath the depositional lobe of the blowout. The internal structure of the depositional lobe of the blowout does not conform to a model of simple radial foreset deposition, as derived from contemporary process studies reported in the literature. Instead, the pattern of deposition has been extensively modified by the antecedent dune topography and by varying spatial and temporal exposure to important sand‐transporting winds that is partly controlled by interactions between the regional wind pattern and local dune morphology. Trough blowout deposits in coastal aeolian sedimentary sequences are likely to be recognized by the presence of laterally continuous packets of relatively high‐angle cross‐strata, which often display a spatially‐variable radial dip pattern that is only very poorly or partially developed. In addition, a soil, or other surface representing a significant hiatus in dune deposition, is likely to underlie the blowout deposits, the topography of which will show a clear relationship to the dip and orientation of the overlying cross‐strata.     

Soil Paleocatenas,Prehistoric Land Use,and Coastal Landscape Dynamics at Druridge Bay,Northeast England

Coastal erosion of sand dune systems along Druridge Bay, northeast England, has progressively exposed parts of the subdune mid‐Holocene landscape, including paleocatenas, indicating former soil hydrosequences with localized wetland habitats, and archaeological evidence of human activities and land use from the Late Mesolithic to the Romano‐British period. Archaeological investigations and pedostratigraphic studies of paleosols provide a unique spatial–chronological framework to interpret soil and land use change over several millennia in the context of a changing coastal environment. Evidence includes dating of archaeological remains, the stratigraphy, morphology and micromorphology of buried soils and sediments, and the palynology and radiocarbon dating of subdune peats. Early Bronze Age burial sites were preferentially located on well‐drained hillocks also used for grazing. Adjacent wetland depressions provided areas of marshy grassland and swamp over deep fen peat soils that started to develop c. 5435 cal. yr B.P. in response to a rising groundwater table stimulated partly by slow sea‐level rise. The backslopes of the paleocatena were occupied by imperfectly to poorly drained soils that supported open oak‐hazel woodland with evidence for progressive clearance and use for agriculture. Windblown sand started to accumulate on the study site sometime between 3930 and 3670 cal. yr B.P., well before the Little Ice Age date for dune formation suggested by previous researchers.     

Determination of reactive phosphorus with and without modification for arsenic interference in New Zealand fresh waters (note)

Two methods for determining reactive phosphorus were compared, using a variety of New Zealand fresh waters, some containing arsenic. The method which eliminated arsenic interference was found to be better, but suffered the disadvantage that high reagent turbidity required the use of solvent extraction when reactive phosphorus concentrations were low.     

Preliminary considerations on the potential influence of submarine fans on marine delimitation

The complex issues associated with marine delineation for the outer limit of continental shelf and the boundary delimitation have provoked considerable attention among researchers in a variety of academic circles, particularly in the juristic filed and the geo-science field. In the present contribution, we start from an overview of submarine fans, as one of common types of sediment-deposit bodies in the ocean, and ex- plore the related geological features which may be of relevance to the marine delimitation in accordance with the 1982 United Nations Convention on the Law of the Sea. We carry out a comparative assessment of certain significant geological features of submarine fans, using the Bengal fan as an example, which is the biggest submarine fan in the world and represents an important factor in the maritime boundary dispute between the neighboring states currently. The relationship between the special geological bodies and the international principle in the 1982 United Nations Convention can be established by combining geological and juristic analyses. This preliminary observation on the effect of submarine bodies both on the marine entitlement and boundary delimitation indicates that it is important for the international society to appro- priately deal with this problem so that the marine right of any state can be protected.     

The Eldgjá eruption: timing,long-range impacts and influence on the Christianisation of Iceland

The Eldgjá lava flood is considered Iceland’s largest volcanic eruption of the Common Era. While it is well established that it occurred after the Settlement of Iceland (circa 874 CE), the date of this great event has remained uncertain. This has hampered investigation of the eruption’s impacts, if any, on climate and society. Here, we use high-temporal resolution glaciochemical records from Greenland to show that the eruption began in spring 939 CE and continued, at least episodically, until at least autumn 940 CE. Contemporary chronicles identify the spread of a remarkable haze in 939 CE, and tree ring-based reconstructions reveal pronounced northern hemisphere summer cooling in 940 CE, consistent with the eruption’s high yield of sulphur to the atmosphere. Consecutive severe winters and privations may also be associated with climatic effects of the volcanic aerosol veil. Iceland’s formal conversion to Christianity dates to 999/1000 CE, within two generations or so of the Eldgjá eruption. The end of the pagan pantheon is foretold in Iceland’s renowned medieval poem, V?luspá (‘the prophecy of the seeress’). Several lines of the poem describe dramatic eruptive activity and attendant meteorological effects in an allusion to the fiery terminus of the pagan gods. We suggest that they draw on first-hand experiences of the Eldgjá eruption and that this retrospection of harrowing volcanic events in the poem was intentional, with the purpose of stimulating Iceland’s Christianisation over the latter half of the tenth century.