Method of Data Reduction and Uncertainty Estimation for Platinum-Group Element Data Using Inductively Coupled Plasma-Mass Spectrometry

A data reduction method is described for determining platinum-group element (PGE) abundances by inductively coupled plasma-mass spectrometry (ICP-MS) using external calibration or the method of standard addition. Gravimetric measurement of volumes, the analysis of reference materials and the use of procedural blanks were all used to minimise systematic errors. Internal standards were used to correct for instrument drift. A linear least squares regression model was used to calculate concentrations from drift-corrected counts per second (cps). Furthermore, mathematical manipulations also contribute to the uncertainty estimates of a procedure. Typical uncertainty estimate calculations for ICP-MS data manipulations involve: (1) Carrying standard deviations from the raw cps through the data reduction or (2) calculating a standard deviation from multiple final concentration calculations. It is demonstrated that method 2 may underestimate the uncertainty estimate of the calculated data. Methods 1 and 2 do not typically include an uncertainty estimate component from a regression model. As such models contribute to the uncertainty estimates affecting the calculated data, an uncertainty estimate component from the regression must be included in any final error calculations. Confidence intervals are used to account for uncertainty estimates from the regression model. These confidence intervals are simpler to calculate than uncertainty estimates from method 1, for example. The data reduction and uncertainty estimation method described here addresses problems of reporting PGE data from an article in the literature and addresses both precision and accuracy. The method can be applied to any analytical technique where drift corrections or regression models are used.     

HCl emissions at Soufrière Hills Volcano,Montserrat, West Indies,during a second phase of dome building: November 1999 to October 2000

HCl:SO₂ mass ratios measured by open path Fourier transform spectroscopy (OP-FTIR) in the volcanic plume at Soufrière Hills Volcano, Montserrat, are presented for the second phase of dome building between November 1999 and November 2000. HCl:SO₂ mass ratios of greater than 1 and HCl emission rates of greater than 400 t day^–1 characterise periods of dome building for this volcano. The data suggest that chlorine partitions into a fluid phase as the magma decompresses and exsolves water during ascent. This is substantiated by a correlation between chlorine and water content in the melt (derived from the geochemical analysis of plagioclase melt inclusion and matrix glasses from phase I and II of dome growth). The matrix glass from the November 1999 and March 2000 domes indicate an open system degassing regime with a fluid-melt partition coefficient for chlorine of the order of 250–300. September 1997 glasses have higher chlorine contents and may indicate a switch to closed system degassing prior to explosive activity in September and October 1997. The OP-FTIR HCl time series suggests that HCl emission rate is strongly related to changes in eruption rate and we infer an emission rate of over 13.5 kt day^–1 HCl during a period of high extrusion rate in September 2000. A calculation of the HCl emission rate expected for varying extrusion rates from the open-system degassing model suggests a HCl emission rate of the order of 1–4 kt day^–1 is indicative of an extrusion rate of between 2 and 8 m³ s^–1. Monitoring of HCl at Soufrière Hills Volcano provide a proxy for extrusion rate, with changes in ratio between HCl and SO₂ occurring rapidly in the plume. Order of magnitude changes occur in HCl emission rates over the time-scale of hours to days, making these changes easy to detect during the day-to-day monitoring of the volcano. Mean water emission rates are calculated to range from 9–24 kt day^–1 during dome building activity, calculated from the predicted mass ratio of H₂O:HCl in the fluid at the surface and FTIR-derived HCl emission rates.     

Implications of the relationship between catchment vegetation type and the variability of annual runoff

The impact of changing catchment vegetation type on mean annual runoff has been known for some time, however, the impact on the variability of annual runoff has been established only recently. Differences in annual actual evapotranspiration between vegetation types and the potential effect of changing vegetation type on mean annual runoff and the variability of annual runoff are briefly reviewed. The magnitude of any change in the variability of annual runoff owing to a change in catchment vegetation type is related to the pre‐ and post‐change vegetation types and the seasonality of precipitation, assuming that the variability of annual precipitation remains constant throughout. Significant implications of the relationship between vegetation type and the variability of annual runoff are presented and discussed for water resource management, stream ecology and fluvial geomorphology. Copyright © 2002 John Wiley & Sons, Ltd.     

Microtextural analysis of a glacially ‘deformed’ bedrock: implications for inheritance of preferred clast orientations in diamictons

Although analysis of clast macrofabrics has been used to differentiate between different types of glacial diamictons and to determine palaeo‐ice flow directions, no account appears to have been made of preferred clast orientations inherited from the parental source material. Clast macrofabrics in tills are typically interpreted as having developed in response to an imposed subglacial deformation and as such provide a link between the sedimentary record and glacier dynamics. They rely on the assumption that any preferred clast orientation is a result of deformation/flow. The results of the micromorphological study of the Langholm Till exposed at North Corbelly near Dumfries (southwestern Scotland) clearly demonstrate that bedrock structure can influence clast orientation (macrofabric) within diamictons. In the lower part of the till, the orientation of elongate clasts preserves the geometry of the tectonic cleavage present within the underlying bedrock. The intensity of this steeply inclined, ‘inherited’ clast fabric decreases upward through the till, to be replaced by a more complex pattern of successive generations of clast microfabrics developed in response to deformation/flow. These results indicate potential limitations of applying clast macrofabric or microfabric analysis in isolation to establish till genesis or palaeo ice‐flow directions. Consequently, due account should be made of other glacial palaeo‐environmental and ice flow indicators, as well as rockhead depth and morphology in relation to the selection of fabric measurements sites. © British Geological Survey/Natural Environment Research Council copyright 2007. Reproduced with the permission of BGS/NERC. Published by John Wiley & Sons, Ltd.     

Is irrigated agriculture in the Murray Darling Basin well prepared to deal with reductions in water availability?

The “Big Dry”, a prolonged dry period in Australia from 1997 to 2009, dried out much of the Murray-Darling Basin (MDB) and resulted in large agricultural losses and degraded river ecosystems. Climate projections are that dry conditions in the MDB are likely to be more regular and severe than ever before, and recent policy initiatives are likely to reduce consumptive water use and redirect water to ecosystem management. This paper aims to develop an understanding of the interactions between water policy and irrigation practices by deriving lessons from drought management in irrigated agriculture of the MDB during the Big Dry, and furthermore, to draw out lessons to enhance the preparedness of irrigated agriculture for a future drier climate and reduced water availability. Reviews of irrigation farmers’ practices, attitudes and capacity to manage during prolonged droughts in the MDB, and the evolution of agricultural water policy in Australia since 1990 were made. It is clear that farmers could be better prepared to deal with a drier climate if their water management practices, e.g. irrigation methods and soil moisture measuring tools are improved, if the impediments to the uncertainty of water allocation and low water availability could be overcome, and if well-targeted research and extension could assist farmers to use water more wisely. It is also clear that Australian water policy could be better prepared in terms of assisting irrigated agriculture to deal with a drier climate. Key areas are reduction of barriers and distortions to water trading, optimizing the environmental water allocation, and seeking mutual benefits between environmental water allocation and irrigated agriculture, improvement of the cost-effectiveness of investments in water supply infrastructure, facilitating carryover and capacity sharing at larger scales, and provision of accurate, accessible and useful water information at different scales. An approach to irrigation practice and water policy is proposed based on past experience and potential opportunities. The approach is a set of linked strategies for more robust agricultural production and a more sustainable environment under a drier climate and reduced water availability.     

Choppy waters ahead in “a sea of peace cooperation and friendship”?: Slow progress towards the application of maritime joint development to the East China Sea

China and Japan’s June 2008 agreement in principle on maritime cooperation in the East China Sea raised hopes of a significant breakthrough in the parties' complex and long-standing disputes in the area. Subsequent progress towards the realisation of a legally binding, formal treaty on, for example, offshore petroleum joint development has been slow to materialise. In fact, the area under dispute appears to have become more rather than less extensive. This paper examines competing maritime and sovereignty claims in the East China Sea together with progress towards maritime cooperation in the context of overlapping jurisdictional claims. The paper identifies some of the key challenges that need to be overcome in realizing a functioning joint resource management regime in the East China Sea.     

Volcanoes of the Tibesti massif (Chad,northern Africa)

The Tibesti massif, one of the most prominent features of the Sahara desert, covers an area of some 100,000 km². Though largely absent from scientific inquiry for several decades, it is one of the world’s major volcanic provinces, and a key example of continental hot spot volcanism. The intense activity of the TVP began as early as the Oligocene, though the major products that mark its surface date from Lower Miocene to Quaternary (Furon (Geology of Africa. Oliver & Boyd, Edinburgh (trans 1963, orig French 1960), pp 1–377, 1963)); Gourgaud and Vincent (J Volcanol Geotherm Res 129:261–290, 2004). We present here a new and consistent analysis of each of the main components of the Tibesti Volcanic Province (TVP), based on examination of multispectral imagery and digital elevation data acquired from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER). Our synthesis of these individual surveys shows that the TVP is made up of several shield volcanoes (up to 80 km diameter) with large-scale calderas, extensive lava plateaux and flow fields, widespread tephra deposits, and a highly varied structural relief. We compare morphometric characteristics of the major TVP structures with other hot spot volcanoes (the Hawaiian Islands, the Galápagos Islands, the Canary and Cape Verdes archipelagos, Jebel Marra (western Sudan), and Martian volcanoes), and consider the implications of differing tectonic setting (continental versus oceanic), the thickness and velocity of the lithosphere, the relative sizes of main volcanic features (e.g. summit calderas, steep slopes at summit regions), and the extent and diversity of volcanic features. These comparisons reveal morphologic similarities between volcanism in the Tibesti, the Galápagos, and Western Sudan but also some distinct features of the TVP. Additionally, we find that a relatively haphazard spatial development of the TVP has occurred, with volcanism initially appearing in the Central TVP and subsequently migrating to both the Eastern and Western TVP regions. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.