Hydrogen emissions from Erebus volcano, Antarctica

The continuous measurement of molecular hydrogen (H₂) emissions from passively degassing volcanoes has recently been made possible using a new generation of low-cost electrochemical sensors. We have used such sensors to measure H₂, along with SO₂, H₂O and CO₂, in the gas and aerosol plume emitted from the phonolite lava lake at Erebus volcano, Antarctica. The measurements were made at the crater rim between December 2010 and January 2011. Combined with measurements of the long-term SO₂ emission rate for Erebus, they indicate a characteristic H₂ flux of 0.03?kg s^–1 (2.8?Mg? day^–1). The observed H₂ content in the plume is consistent with previous estimates of redox conditions in the lava lake inferred from mineral compositions and the observed CO₂/CO ratio in the gas plume (～0.9 log units below the quartz–fayalite–magnetite buffer). These measurements suggest that H₂ does not combust at the surface of the lake, and that H₂ is kinetically inert in the gas/aerosol plume, retaining the signature of the high-temperature chemical equilibrium reached in the lava lake. We also observe a cyclical variation in the H₂/SO₂ ratio with a period of ～10?min. These cycles correspond to oscillatory patterns of surface motion of the lava lake that have been interpreted as signs of a pulsatory magma supply at the top of the magmatic conduit.     

Darkness on the Edge of Town: Mapping Urban and Peri-Urban Australia Using Nighttime Satellite Imagery

This article explores the use of nighttime satellite imagery for mapping urban and peri-urban areas of Australia. A population-weighted measure of urban sprawl is used to characterize relative levels of sprawl for Australia's urban areas. In addition, the expansive areas of low light surrounding most major metropolitan areas are used to map the urban–bush interface of exurban land use. Our findings suggest that 82 percent of the Australian population lives in urban areas, 15 percent live in peri-urban or exurban areas, and 3 percent live in rural areas. This represents a significantly more concentrated human settlement pattern than presently exists in the United States.     

Is irrigated agriculture in the Murray Darling Basin well prepared to deal with reductions in water availability?

The “Big Dry”, a prolonged dry period in Australia from 1997 to 2009, dried out much of the Murray-Darling Basin (MDB) and resulted in large agricultural losses and degraded river ecosystems. Climate projections are that dry conditions in the MDB are likely to be more regular and severe than ever before, and recent policy initiatives are likely to reduce consumptive water use and redirect water to ecosystem management. This paper aims to develop an understanding of the interactions between water policy and irrigation practices by deriving lessons from drought management in irrigated agriculture of the MDB during the Big Dry, and furthermore, to draw out lessons to enhance the preparedness of irrigated agriculture for a future drier climate and reduced water availability. Reviews of irrigation farmers’ practices, attitudes and capacity to manage during prolonged droughts in the MDB, and the evolution of agricultural water policy in Australia since 1990 were made. It is clear that farmers could be better prepared to deal with a drier climate if their water management practices, e.g. irrigation methods and soil moisture measuring tools are improved, if the impediments to the uncertainty of water allocation and low water availability could be overcome, and if well-targeted research and extension could assist farmers to use water more wisely. It is also clear that Australian water policy could be better prepared in terms of assisting irrigated agriculture to deal with a drier climate. Key areas are reduction of barriers and distortions to water trading, optimizing the environmental water allocation, and seeking mutual benefits between environmental water allocation and irrigated agriculture, improvement of the cost-effectiveness of investments in water supply infrastructure, facilitating carryover and capacity sharing at larger scales, and provision of accurate, accessible and useful water information at different scales. An approach to irrigation practice and water policy is proposed based on past experience and potential opportunities. The approach is a set of linked strategies for more robust agricultural production and a more sustainable environment under a drier climate and reduced water availability.     

Choppy waters ahead in “a sea of peace cooperation and friendship”?: Slow progress towards the application of maritime joint development to the East China Sea

China and Japan’s June 2008 agreement in principle on maritime cooperation in the East China Sea raised hopes of a significant breakthrough in the parties' complex and long-standing disputes in the area. Subsequent progress towards the realisation of a legally binding, formal treaty on, for example, offshore petroleum joint development has been slow to materialise. In fact, the area under dispute appears to have become more rather than less extensive. This paper examines competing maritime and sovereignty claims in the East China Sea together with progress towards maritime cooperation in the context of overlapping jurisdictional claims. The paper identifies some of the key challenges that need to be overcome in realizing a functioning joint resource management regime in the East China Sea.     

Elevation adjustments of paired natural levees during flooding of the Saskatchewan River

Natural levees control the exchange of water between an alluvial channel and its floodplain, but little is known about the spatial distribution and evolution of levee heights. The summer 2005 flood of the Saskatchewan River (Cumberland Marshes, east‐central Saskatchewan) inundated large areas of floodplain for up to seven weeks, forming prominent new deposits on natural levees along main‐stem channels. Measurements of flood‐deposit thickness and crest heights of 61 levee pairs show that the thickest deposits occur on the lower pre‐flood levee in 80% of the sites, though no clear relationship exists between deposit thickness and magnitude of height difference. Only 16% of the pairs displayed thicker deposits on the higher levee, half of which occurred at sites where relatively clear floodbasin waters re‐entered turbid channels during general flooding. Difference in crest elevation (ΔE) between paired levees is approximately log‐normally distributed, both before and after the flood, though with different mean values. Supplemental observations from tank experiments indicate that during near‐bankfull flows, temporally and spatially variable deposition and erosion occur on levees due to backwater effects associated with nearby channel bars and irregular rises of the channel bed forced by channel extension. During floods, preferential deposition in lows tends to even out crest heights. Copyright © 2009 John Wiley & Sons, Ltd.     

Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.     

Characterisation of Memory Effects and Development of an Effective Wash Protocol for the Measurement of Petrogenetically Critical Trace Elements in Geological Samples by ICP-MS

High sensitivity and low detection limits would seem to make inductively coupled plasma-mass spectrometry (ICP-MS) an ideal analytical tool for determining low (sub-μg g^-1) concentrations of the rare earth elements (REE), Y, Zr, Nb, Hf, Ta, Sn, W, Mo, Th, and U in most mafic materials (e.g. Hall and Plant 1992). However, the generally "sticky" nature exhibited by most of the high field strength elements (HFSEs: Zr, Nb, Hf, Ta, Th and U) as well as Sn, W and Mo can result in spurious results due to memory effects transmitted between unknowns and calibration samples. This, in turn, can seriously compromise the sensitivity, accuracy, and precision of ICP-MS analyses for these elements in geological materials. Data resulting from analyses with poor accuracy and precision can lead to erroneous interpretation and misleading petrogenetic modelling. To resolve this problem, we propose an effective wash protocol for these critical trace elements.     

Method of Data Reduction and Uncertainty Estimation for Platinum-Group Element Data Using Inductively Coupled Plasma-Mass Spectrometry

A data reduction method is described for determining platinum-group element (PGE) abundances by inductively coupled plasma-mass spectrometry (ICP-MS) using external calibration or the method of standard addition. Gravimetric measurement of volumes, the analysis of reference materials and the use of procedural blanks were all used to minimise systematic errors. Internal standards were used to correct for instrument drift. A linear least squares regression model was used to calculate concentrations from drift-corrected counts per second (cps). Furthermore, mathematical manipulations also contribute to the uncertainty estimates of a procedure. Typical uncertainty estimate calculations for ICP-MS data manipulations involve: (1) Carrying standard deviations from the raw cps through the data reduction or (2) calculating a standard deviation from multiple final concentration calculations. It is demonstrated that method 2 may underestimate the uncertainty estimate of the calculated data. Methods 1 and 2 do not typically include an uncertainty estimate component from a regression model. As such models contribute to the uncertainty estimates affecting the calculated data, an uncertainty estimate component from the regression must be included in any final error calculations. Confidence intervals are used to account for uncertainty estimates from the regression model. These confidence intervals are simpler to calculate than uncertainty estimates from method 1, for example. The data reduction and uncertainty estimation method described here addresses problems of reporting PGE data from an article in the literature and addresses both precision and accuracy. The method can be applied to any analytical technique where drift corrections or regression models are used.     

Climate Change Impacts for the Conterminous USA: An Integrated Assessment Summary

This special issue of Climatic Change describes an effort to improve methodology for integrated assessment of impacts and consequences of climatic change. Highlights of the seven foregoing Parts (papers) that constitute this special issue are summarized here. The methodology developed involves construction of scenarios of climate change that are used to drive individual sectoral models for simulating impacts on crop production, irrigation demand, water supply and change in productivity and geography of unmanaged ecosystems. Economic impacts of the changes predicted by integrating the results of the several sectoral simulation models are calculated through an agricultural land-use model. While these analyses were conducted for the conterminous United States alone, their global implications are also considered in this summary as is the need for further improvements in integrated assessment methodology.     

BiSON performance

Since 1981 we have been operating the Birmingham Solar-Oscillations Network (BiSON), a global network of resonant-scattering spectrometers, observing the low-l solar p modes. Here we discuss historical developments, culminating in the establishment of a 6-station network in 1992 September, and the subsequent performance of that network. The data record of each station from 1992 to 1994 has been analysed in terms of weather and equipment breakdowns. Our early experience suggests that the best long-term coverage possible with a 6-station network is limited in practice to about 80%, which falls short of previous predictions.