TEQC multipath metrics in MATLAB

Knowledge of the local direction of multipath at a particular site is important for a number of reasons. For example, such information can be used to study site selections or during monument design for GPS installations. We present a MATLAB program for creating colorized polar maps of high-frequency multipath using TEQC report files of single-epoch data. The maps, although not necessarily indicating the actual local direction of multipath on the ground, give the orientation with respect to the geometry of the satellites in the sky. This information can aid the interpretation of ground multipath geometry at the site. We give an example of short-span data with ∼0.05 Hz multipath (i.e. repeat period ≈ 20 s) although the program can be modified for long-term measurements as well.     

Stratigraphy and depositional environments of the Mamfe Formation and its implication on the tectonosedimentary evolution of the Ikom-Mamfe Embayment, West Africa

A 42 m thick outcropping portion of the Mamfe Formation is subdivided into Manyu (31 m thick) and Kesham (11m thick) Members on the basis of textural, mineralogical and structural differences. The Manyu Member (Albian) consists of folded and indurated, medium to coarse grained arkosic sandstones and thickly laminated organic-rich shales deposited in a lacustrine environment. The Kesham Member (Cenomanian) consists of subarkoses intercalated with massive green shale and mudstone deposited in a fluvial environment. The change in depositional environment was tectonically controlled. The mid Cretaceous paleogeography of the embayment was governed by the NE-SW trending “Ikom ridge” which prevented marine incursion from adjacent the Benue Sea. Evaporites found within the basin were precipitated from ocean water that was periodically spilled by strong tides and storms across the ridge into the embayment. The filling-up of the embayment to base level in the Cenomanian resulted in a shift in the depositional center downstream to adjoining lower Benue Trough. Similarity in heavy mineral composition and maturity of the Cenomanian sandstones with recent clastics in the embayment indicates their derivation from the same source terrain and relatively stable tectonic and climatic conditions at the source area since the Cenomanian time.     

Scaling of adsorption reactions: U(VI) experiments and modeling

Iron-coated sands were prepared via two common protocols, a precipitation method, where Fe was precipitated directly onto the sand in a single step, and an adsorption method, where pure goethite was prepared in the first step and then adsorbed onto the sand in a second step. The coated sands from both the systems were characterized using scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, and selective Fe extraction. Although neither of the methods produced a completely crystalline Fe coating, the precipitation method produced sands with larger portions of amorphous Fe than the adsorption method, with the fraction of amorphous Fe decreasing with increasing Fe content. Uranium(VI) adsorption isotherms and pH adsorption edges were measured on three coated sands with Fe contents ranging from 0.04% to 0.3%. Experimentally, the adsorption of U(VI) onto the three sands was more comparable when normalized to surface area than when normalized to Fe content. A surface complexation model, although originally developed for U(VI) adsorption onto amorphous Fe oxide, captured the differences in adsorption when adjusted for the surface area of the coated sand. The findings indicate that surface area is a better scaling parameter than Fe content in predicting U(VI) adsorption to Fe-dominated media. These findings are significant because many common surface complexation models are parameterized on the basis of Fe content rather than specific surface area. Although the interactions of U(VI) and Fe-coated sands were used as representative adsorbate and adsorbent, the general principles may be applicable to other adsorbate–adsorbent systems as well.     

Impact of seasonal variations in hydrological stresses and spatial variations in geologic conditions on a TCE plume at an industrial complex in Wonju,Korea

Spatial and temporal variations in a trichloroethylene (TCE) plume at an industrial complex in Wonju, Korea, were examined based on hydrogeological data and seven rounds of groundwater quality data collected over a year. The site has considerable vertical heterogeneities; the top layer of soil is covered by impermeable paving material at several locations, followed by a series of reclaimed or residual soil layers, and with weathered rocks to the crystalline biotite granite at the bottom. Areal heterogeneity in the surface conditions plays an important role in controlling groundwater recharge. The heterogeneity structure is influenced by complex surface conditions paved with asphalt and concrete. Owing to the presence of limited recharge area and concentrated summer precipitation events, the effects of seasonal variations on groundwater hydraulics tend to diminish with distance from the recharge area. This result was established by analysing the influence of the contrasting surface recharge conditions between the near‐source zone and the far zone, and the seasonally concentrated precipitation on the transport patterns of a TCE plume. In addition, variations in the plume's downstream contaminant flux levels were also analysed along a transect line near the source zone. The results show that the general tendency of the TCE plume contaminant concentration and mass discharges were reproducible if we account for seasonal recharge variations and the associated changes in the groundwater level. During recharge events, the TCE concentration variations appear to be influenced by leaching of the residual dense non‐aqueous‐phase liquid (DNAPL) TCE trapped in the unsaturated zone. This result shows that seasonal variations in contaminant plume near the source zone is inevitable at this site, and that these variations indicate the presence of residual DNAPL at or above the water table, at least in some isolated locations. Copyright © 2011 John Wiley & Sons, Ltd.     

http://www.sciencedirect.com/science/article/pii/S1674987113000327

The Panzhihua intrusion in southwest China is part of the Emeishan large igneous province and host of a large Fe-Ti-V ore deposit.In previous interpretations it was considered to be a layered,differentiated sill with the ore deposits at its base.New structural and petrological data suggest instead that the intrusion has an open S-shape,with two near-concordant segments joined by a discordant dyke-like segment. During emplacement of the main intrusion,multiple generations of mafic dykes invaded carbonate wall rocks,producing a large contact aureole.In the central segment,magmatic layering is oriented oblique to the walls of the intrusion.This layering cannot have formed by crystal settling or in-situ growth on the floor of the intrusion;instead we propose that it resulted from inward solidification of multiple,individually operating,convection cells.Ore formation was triggered by interaction of magma with carbonate wall rocks.     

Beitrag zur feinstmahlung von industriemineralen

Industrial minerals of a high degree of fineness such as kaolinite, calcite and barite are used to an increasing extent in the chemical industries as filling material in the manu-facturing of paper, paints and plastics or as ingredients of ceramic products. Grains smaller than 5 μm can be produced by dry grinding in a jet mill or by wet grinding in drum mills. To avoid impurities due to wear, these mills are lined with rubber or plastic and ceramic balls are used as grinding bodies.Our investigations in a jet mill show that the fineness of the ground product depends on the feed rate and on the air volume. The grain sizes received in the drum mill are influenced by feed rate, pulp density, speed of rotation and by the grinding bodies (density, size).REM-photographs of mill discharge in the grain-size ranges 10-5 μm and below 5 μm indicate that in both the grains mainly show crystal planes as boundaries. After dry grinding the grains show smooth and clean faces; thus is traced back to the impact effect of the air streams. In wet grinding the fine grains are very prone to form agglomerates.     

Untersuchungen zur kreislaufmahlung in einer aufbereitung für komplexe sulfidische erze

Circuit grinding was investigated in the Rammelsberg ore dressing plant. From short-interval sampling it was possible to make a statement about the non-stationary and stationary state of grinding. The objective of these investigations was to establish the distribution curves of the quantitative flow, of the grain sizes and of the mineralogical components in the individual streams of the circuit grinding.     

Climate and irrigation scenario analyses using three-dimensional numerical modelling: a case study of the Nasia sub-basin in the White Volta Basin,Ghana

A groundwater resource characterisation and assessment model was developed for Nasia river sub-basin in the White Volta Basin, Ghana. The model is useful to policymakers for planning and sustainable management of groundwater resources in the basin for domestic and irrigation purposes. A conceptual model was constructed that characterized boundary conditions and hydrostratigraphy, and estimated recharge rates and hydraulic and storage parameters. From current understanding of the hydrogeological dynamics, three hydrostratigraphic layers were delineated. The conceptual model was converted to a three-dimensional steady-state groundwater flow model using MODFLOW. Recharge rates estimated from the base model indicate a minimum of 1.1% and maximum of 6.2% of the total rainfall. The hydraulic conductivity ranged between 0.20 and 15 m/day. Four possible scenarios were simulated: (1) increased population, (2) climate variations (reduced recharge), (3) increased abstraction for irrigation, and (4) worst-case scenario which is a combination of the first three scenarios. Results from scenarios 1 and 2 indicated that, under such conditions, the groundwater resources could be sustained and no significant effect on any of the water budget indicators was observed. For scenario 3, there was significant drop in hydraulic head in the central portions of the study area. The scenario 4 simulation indicated that there was significant reduction in groundwater levels and groundwater discharge into streams under these stressors. Such reduction can affect stream levels in the basin and, subsequently, the ecosystem. These findings are valid within the limits of uncertainty in the hydrogeological data that were used in this study.

     

Retrieval of chlorophyll and nitrogen in Norway spruce (Picea abies L. Karst.) using imaging spectroscopy

The research evaluated the information content of spectral reflectance (laboratory and airborne data) for the estimation of needle chlorophyll (C_AB) and nitrogen (C_N) concentration in Norway spruce (Picea abies L. Karst.) needles. To identify reliable predictive models different types of spectral transformations were systematically compared regarding the accuracy of prediction. The results of the cross-validated analysis showed that C_AB can be well estimated from laboratory and canopy reflectance data. The best predictive model to estimate C_AB was achieved from laboratory spectra using continuum-removal transformed data (R²cv = 0.83 and a relative RMSEcv of 8.1%, n = 78) and from hyperspectral HyMap data using band-depth normalised spectra (R²cv = 0.90, relative RMSEcv = 2.8%, n = 13). Concerning the nitrogen concentration, we observed somewhat weaker relations, with however still acceptable accuracies (at canopy level: R²cv = 0.57, relative RMSEcv = 4.6%). The wavebands selected in the regression models to estimate C_AB were typically located in the red edge region and near the green reflectance peak. For C_N, additional wavebands related to a known protein absorption feature at 2350 nm were selected. The portion of selected wavebands attributable to known absorption features strongly depends on the type of spectral transformation applied. A method called “water removal” (WR) produced for canopy spectra the largest percentage of wavebands directly or indirectly related to known absorption features. The derived chlorophyll and nitrogen maps may support the detection and the monitoring of environmental stressors and are also important inputs to many bio-geochemical process models.     

Satellite-based analysis of the role of land use/land cover and vegetation density on surface temperature regime of Delhi,India

The knowledge of the surface temperature is important to a range of issues and themes in earth sciences central to urban climatology, global environmental change and human-environment interactions. The study analyses land surface temperature (LST) estimation using temporal ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) datasets (day time and night time) over National Capital Territory Delhi using the surface emissivity information at pixel level. The spatial variations of LST over different land use/land cover (LU/LC) at day time and night time were analysed and relationship between the spatial distribution of LU/LC and vegetation density with LST was developed. Minimum noise fraction (MNF) was used for LU/LC classification which gave better accuracy than classification with original bands. The satellite derived emissivity values were found to be in good agreement with literature and field measured values. It was observed that fallow land, waste land/bare soil, commercial/industrial and high dense built-up area have high surface temperature values during day time, compared to those over water bodies, agricultural cropland, and dense vegetation. During night time high surface temperature values are found over high dense built-up, water bodies, commercial/industrial and low dense built-up than over fallow land, dense vegetation and agricultural cropland. It was found that there is a strong negative correlation between surface temperature and NDVI over dense vegetation, sparse vegetation and low dense built-up area while with fraction vegetation cover, it indicates a moderate negative correlation. The results suggest that the methodology is feasible to estimate NDVI, surface emissivity and surface temperature with reasonable accuracy over heterogeneous urban area. The analysis also indicates that the relationship between the spatial distribution of LU/LC and vegetation density is closely related to the development of urban heat islands (UHI).