Geochemistry of groundwater in front of a warm‐based glacier in Southeast Greenland

Groundwater in front of warm‐based glaciers is likely to become a more integrated part of the future proglacial hydrological system at high latitudes due to global warming. Here, we present the first monitoring results of shallow groundwater chemistry and geochemical fingerprinting of glacier meltwater in front of a warm‐based glacier in Southeast Greenland (Mittivakkat Gletscher, 65° 41′ N, 37° 48′ W). The groundwater temperature, electrical conductivity and pressure head were monitored from August 2009 to August 2011, and water samples were collected in 2009 and analyzed for major ions and water isotopes (δD, δ¹⁸O). The 2 yrs of monitoring revealed that major outbursts of glacier water during the ablation season flushed the proglacial aquifer and determined the groundwater quality for the next 2–8 weeks until stable chemical conditions were reached again. Water isotope composition shows that isotopic fractionation occurs in both groundwater and glacier meltwater, but fractionation due to evaporation from near‐surface soil moisture prior to infiltration has the most significant effect. This study shows that groundwater in Low Arctic Greenland is likely to possess a combined geochemical and isotopic composition, which is distinguishable from other water sources in the proglacial environment. However, the shallow groundwater composition at a given time is highly dependent on major outbursts of glacier water in the previous months.     

Distribution and relative density of cetaceans in the Hauraki Gulf,New Zealand

Understanding species distributions, and how they change in space and time, is vital when prioritising conservation or management initiatives. We assessed the distribution and density patterns of common dolphins (Delphinus sp.), bottlenose dolphins (Tursiops truncatus) and Bryde’s whales (Balaenoptera edeni) in the Hauraki Gulf, New Zealand. Dedicated boat-based surveys were conducted in the inner Hauraki Gulf (IHG) and off Great Barrier Island (GBI) during 2010–2012. Generalised linear models were used to investigate temporal changes in relative densities and kernel density estimation was implemented to examine spatial trends. Common dolphins were widely distributed during all seasons, with higher densities observed during winter and spring in the IHG but during autumn off GBI. There was inter-annual variation in Bryde’s whale distribution, with high densities recorded off GBI in 2011. Bottlenose dolphins were infrequently sighted in the IHG but regularly encountered off GBI, with the highest densities during spring and summer.     

Private rights,public benefits: Industry-driven seabed protection

New Zealand has a large exclusive economic zone (EEZ) that contains a variety of marine habitats and commercially-important species. The commercial fishing industry operating within New Zealand's EEZ is of significant value to the economy and fisheries resources are managed through the extensive use of Individual Transferable Quotas (ITQs). One of the benefits of ITQs has been to better align some of the private incentives of quota owners with the public interest. These incentives contributed to an initiative proposed by the fishing industry to close large areas of New Zealand's EEZ to protect the seabed from trawling. These closed areas are termed benthic protection areas (BPAs) and protect the benthic biodiversity of about 1.1 million square kilometres of seabed—approximately 30% of New Zealand's EEZ. A significant proportion of New Zealand's known seamounts and active hydrothermal vents are protected by these closed areas. We describe and discuss the criteria used to select BPAs and some of the criticism of this marine protection initiative. We argue that the assignment of strong property rights in fishing resources was an important precondition to an industry initiative that has a significant public benefit. Where private and public interests are well aligned, government can adopt an enabling and facilitation role, ceding direct control of processes in order to get the results the align with the public interest.     

Results of recent Pacific-Arctic ice-ocean modeling studies at the Naval Postgraduate School

Summary of results from a high - resolution pan - Arctic ice - ocean model are presented for the northern North Pacific, Bering, Chukchi, and Beaufort seas. The main focus is on the mean circulation, communication from the Gulf of Alaska across the Bering Sea into the western Arctic Ocean and on mesoscale eddy activity within several important ecosystems. Model results from 1979 -2004 are compared to observations whenever possible. The high spatial model resolution at 1/12o （or -9 - km） in the horizontal and 45 levels in the vertical direction allows for representation of eddies with diameters as small as 36 km. However, we believe that upcoming new model integrations at even higher resolution will allow us to resolve even smaller eddies. This is especially important at the highest latitudes where the Rossby radius of deformation is as small as 10 km or less.     

Ecological Modernization or Aristocratic Conservation? Exploring the Impact of Affluence on Carbon Emissions at the Local Level

Social scientists have debated how affluence impacts carbon emissions at the national level. We conduct an exploratory study at the subnational level to expose another dimension of the affluence–emissions debate. Based on the notion of aristocratic conservation, we hypothesize that affluence is positively related to carbon emissions from consumption activities but negatively related to emissions from production activities. We test these hypotheses using county-level data in the United States for the year 2002. A spatial regression analysis demonstrates that median household income is positively associated with consumption-based emissions; nevertheless, we find evidence of an environmental inequality Kuznets curve in the relationship between median household income and production-based emissions. This finding suggests that the wealthiest counties are able to displace certain types of emissions, specifically those related to energy and industrial production. We discuss the theoretical and political implications of these results.     

The modern geoid and ancient plate boundaries

The non-hydrostatic geoid is dominated by three large anomalies: an area of high gravity potential in the equatorial Pacific; another stretching from Greenland through Africa to the southwest Indian Ocean; and a semi-continuous low region passing from Hudson's Bay through Siberia to India and on to Antarctica. None of these three high-amplitude (greater than 60 m) and long-wavelength anomalies corresponds to present-day plate boundaries. However, if the modern geoid is plotted over the positions of continents and plate boundaries at 125 Ma B.P. (reconstructed relative to hotspots) a strong correlation emerges. The modern geoidal low corresponds in position to the areas of subduction surrounding the Pacific 125 Ma ago. The geoidal high now centered on Africa is entirely contained within ancient Pangaea, and the equatorial Pacific high overlies the location of the spreading centers preserved in the magnetic anomalies of the central Pacific. The most plausible cause of the large geoidal undulations is lower mantle convection only weakly coupled to plate motions. The correspondence between modern geoid and ancient plate boundaries implies either that the coupling was much more intimate in the past, or that there is a lag of at least 100 Ma in response of the lower mantle to upper mantle conditions.     

北京大学陆面过程模式PKULM(Peking University Land Model)介绍及检验

陆面过程模式是气候模式和天气模式的核心组成部分之一.在土壤-植被-大气耦合模式(Soil-Plant-Atmosphere Model, SPAM)的基础上,发展了新一代北京大学陆面过程模式PKULM(Peking University Land Model).本文首先介绍了PKULM的辐射传输、湍流输送、光合作用、土壤水热输送等过程的参数化方案;采用隐式迭代计算框架,发展并应用了一个快速的线性方程组求解算法,提高了模式计算稳定性;提出并使用了二分搜索算法计算气孔阻抗,避免了CLM(Community Land Model)等使用的迭代方法在干旱区不稳定的情况,提高了模式的适用性;采用水势为基础的土壤水分扩散方程,使模式能够模拟土壤饱和区的水分输送过程,为进一步与水文过程模式耦合奠定了基础;还发展了一个地表积水与径流过程的机理模型,提高了模式对地表水分平衡过程的模拟能力;最后,使用"中国西北干旱区陆-气相互作用观测试验"平凉站的资料对模式进行了检验并与NOAH(National Center for Environmental Prediction, Oregon State University, Air Force, and Hydrology Lab model)陆面过程模式的模拟结果进行了比较,结果表明PKULM能够较好地模拟西北半干旱区农田下垫面地气交换过程.     

Enzymatic microbial Mn(II) oxidation and Mn biooxide production in the Guaymas Basin deep-sea hydrothermal plume

Microorganisms play important roles in mediating biogeochemical reactions in deep-sea hydrothermal plumes, but little is known regarding the mechanisms that underpin these transformations. At Guaymas Basin (GB) in the Gulf of California, hydrothermal vents inject fluids laden with dissolved Mn(II) (dMn) into the deep waters of the basin where it is oxidized and precipitated as particulate Mn(III/IV) oxides, forming turbid hydrothermal “clouds”. Previous studies have predicted extremely short residence times for dMn at GB and suggested they are the result of microbially-mediated Mn(II) oxidation and precipitation. Here we present biogeochemical results that support a central role for microorganisms in driving Mn(II) oxidation in the GB hydrothermal plume, with enzymes being the primary catalytic agent. dMn removal rates at GB are remarkably fast for a deep-sea hydrothermal plume (up to 2 nM/h). These rapid rates were only observed within the plume, not in background deep-sea water above the GB plume or at GB plume depths (∼1750-2000 m) in the neighboring Carmen Basin, where there is no known venting. dMn removal is dramatically inhibited under anoxic conditions and by the presence of the biological poison, sodium azide. A conspicuous temperature optimum of dMn removal rates (∼40 °C) and a saturation-like (i.e. Michaelis-Menten) response to O₂ concentration were observed, indicating an enzymatic mechanism. dMn removal was resistant to heat treatment used to select for spore-forming organisms, but very sensitive to low concentrations of added Cu, a cofactor required by the putative Mn(II)-oxidizing enzyme. Extended X-ray absorption fine structure spectroscopy (EXAFS) and synchrotron radiation-based X-ray diffraction (SR-XRD) revealed the Mn oxides to have a hexagonal birnessite or δ-MnO₂-like mineral structure, indicating that these freshly formed deep-sea Mn oxides are strikingly similar to primary biogenic Mn oxides produced by laboratory cultures of bacteria. Overall, these results reveal a vigorous Mn biogeochemical cycle in the GB hydrothermal plume, where a distinct microbial community enzymatically catalyzes rapid Mn(II) oxidation and the production of Mn biooxides.     

Impact of Terrain Heterogeneity on Coherent Structure Properties: Numerical Approach

A three-dimensional large-eddy simulation (LES) model, which includes the effects of plant–atmosphere interactions, is used to study the effects of surface inhomogeneities on near-surface coherent structures over an open field and behind a forest canopy. These simulated conditions are representative of two wind sectors of the Site Instrumental de Recherche par Télédétection Atmosphérique (SIRTA) experimental site at the Institut Pierre Simon Laplace, Palaiseau, France. Coherent structure properties deduced from wavelet transforms of the simulated near-surface vertical velocity time series are not modified by upstream terrain heterogeneities, in agreement with site measurements. This feature is related to the nature of structures detected from the vertical velocity time series. The turbulence close to the surface seems composed of both local coherent structures and large coherent structures reflecting outer-layer properties, which depend on the overall surface heterogeneity or upstream heterogeneity. It is argued that the streamwise velocity is representative of these large outer-layer structures that impinge onto the ground through a top-down mechanism as identified through the space–time correlation of the wind velocity components. In contrast, the vertical velocity is more representative of small structures resulting from the impingement of the large outer-layer structures. These small structures represent locally-generated, active turbulence, which adjusts rapidly to local surface conditions, and consequently they are only weakly dependent on upstream heterogeneities.