Preservation of chemical residue-melt equilibria in natural anatexite: the effects of deformation and rapid cooling

A combined petrologic, textural and chemical approach is used to interpret the relationship between chemical exchange and deformation during partial melting of a granodioritic gneiss in the contact aureole of the Bergell Pluton (Central Alps). In contrast to most regional metamorphic anatexites, chemical equilibrium between residue and segregated melt was attained and preserved by several elements, as shown by their present distribution. Equilibrium involved both the major and the trace elements hosted in the rock-forming minerals and the light rare earth elements (LREE), hosted primarily in allanite. Equilibrium with respect to LREEs was achieved because allanite had a reactive behaviour during water-present melting, in contrast to the refractive behaviour of xenotime, which mostly controls the distribution of the HREE's. The attainment and preservation of equilibrium between leucosome and residue requires peculiar boundary conditions. We propose that the achievement of equilibrium between melt and residue was promoted by deformation, operating via a mechanism of melt present granular flow (i.e. dissolution-accommodated grain-boundary sliding active during partial melting). Microstructural observations indicate that melt-present granular flow was the dominating deformation mechanism in these anatexites. The preservation of residue-melt equilibrium is inferred to result from rapid cooling under contact metamorphic conditions and from the lack of deformation below the solidus.     

Paleoenvironmental reconstruction of Holocene coastal depositsfrom the Southeastern Buenos Aires Province, Argentina

An estuarine sequence outcropping at La Ballenera Creek (BuenosAires Province), dated between 6,800 and 4,100 ¹⁴C years BP, wasinvestigated for diatoms and molluscs. The sea level history along the BuenosAires coastline has been reconstructed from discrete beach ridge sequencesalong low-lying plains. The La Ballenera profile is located on a cliffcoast where a sequence recorded environmental changes. Fifty-eightdiatom species were grouped based on their salinity and life formcharacteristics. Cluster analysis allowed the division of the sequence intothree diatom zones. Mollusc tolerances were also used to discern theenvironmental changes induced by sea-level fluctuations. The base of thesequence recorded the initiation of the marine influence about6,790–6,200 years ago. Diatom assemblages consist ofbrackish-freshwater tychoplankton accompanied by brackish benthicdiatoms. Among the molluscs, the freshwater-brackish species Heleobiaparchappii dominates. Between 6,200 and ca. 4,800 ¹⁴C years BP, anestuarine lagoon environment is indicated by benthic and epiphyticmarine-brackish diatoms, as well as by the estuarine snail Heleobiaaustralis. After 4,800 ¹⁴C years BP, the diatom assemblages and therelative abundance of freshwater molluscs indicate a marshy environment withlower salinity content. The La Ballenera records the salinity changes thataffect an estuary that infilled during the 2,700 years after the maximum sealevel reached in mid-latitudes of South America.     

Integrated correlation of the Vendian to Cambrian Arroyo del Soldado and Corumbá Groups (Uruguay and Brazil): palaeogeographic, palaeoclimatic and palaeobiologic implications

The Corumbá Group of SW Brazil and the Arroyo del Soldado Group (ASG) of Uruguay are correlated on the basis of litho-, bio- and chemostratigraphy. Both units represent marine sedimentation with alternating siliciclastics and carbonates developed on a stable continental shelf. In the Corumbá basin, sedimentation began in the Varangerian, represented by the glaciomarine Puga Formation. A series of sea-level fluctuations coupled with climatic changes are recorded up section. While uppermost deposits of the ASG are of lowermost Cambrian age, sedimentation ceased in the latest Vendian in the Corumbá basin. An assemblage of six species of organic-walled microfossils dominated by Bavlinella faveolata and Soldadophycus bossii, three species of vendotaenids and two species of skeletal fossils (Cloudina and Titanotheca) is described from the Corumbá Group. The vendotaenid Eoholynia corumbensis sp. nov is described from siltstones of the Guaicurus Formation. An important diversity of skeletal fossils in the Corumbá, Arroyo del Soldado and Nama groups points to favourable Vendian palaeoclimatic conditions in SW-Gondwana. Preliminary carbon isotopic data show a series of alternating positive and negative excursions, corroborating the upper Vendian age indicated by fossils for both units. Previously reported strontium isotopic data are also consistent with this age. It is postulated that the Corumbá and ASGs were deposited onto the same shelf, which opened to the east. The Rio de la Plata Superterrane (Craton) extends farther to the north than previously expected, or it was already amalgamated with the Amazonian Craton by Vendian times. Collision of the platform with the Paraná Block caused closure of the basin during the Cambrian-Early Ordovician. Finally, models of Neoproterozoic glaciations based on enhanced bioproductivity driven by high nutrient availability are discussed.     

Calibration of cross-line components for sea-bed 4C acquisition systems

Faithful recording of the elastic wavefield at the sea‐bed is required for quantitative applications of 4C seismic. The accuracy of the recorded vectorial wavefield depends on factors that vary from deployment to deployment. This paper focuses on one such factor: the interaction of the acquisition system with the sea‐bed, which is referred to here as coupling. We show, using multi‐azimuth data recorded with a cable‐based sea‐bed acquisition system, whose sensor housing is cylindrically shaped and with the in‐line geophone fixed to the cable, that coupling depends on the propagation direction and wave type (P‐ or S‐waves) of the incident wavefield. We show that coupling is more critical for S‐waves than for P‐waves. Detection of inconsistent coupling using both P‐ and S‐waves is therefore mandatory. A data‐driven processing method to compensate for the frequency‐dependent coupling response of the cross‐line geophone is derived. Its application to field data verifies the effectiveness of the method.     

Corrections of Systematic Errors and Data Homogenisation in the Daily Temperature Padova Series (1725–1998)

The correction, validation and homogenisation of the long temperature series of Padova (1725–1998) are discussed. After a careful historical investigation made in order to discover the metadata concerning the series, i.e., instrument features, calibrating methodologies, operational procedures (i.e., exposure, timing and number of daily observations), instrument maintenance, relocations and instrument replacements, the series has been corrected for all the systematic errors derived from any change in the instruments or the operative methodology. Above all, correction focused on instrumental drift, scale expansion, building influence, relationship between indoor-outdoor measurements, minima and maxima evaluation from observations performed at different times, homogenisation for difference of level and change of site. Statistical tests applied to the data and the comparison with other known series has clarified some uncertainties about exposure and operational procedures that the historical analysis of metadata was unable to solve. Moreover, gaps have been filled after the comparison of the series with others of neighbouring sites. The critical work of debugging, correcting, validating and homogenising the series is essential for a correct interpretation of data, as in some cases the errors that have been corrected have been found to be greater than the climate signal. Especially in the early period, the algebraic sum of the corrections of the mean daily temperature exceeds 8 ° C, where monthly corrections can reach 6 ° C. After correction, validation and homogenisation, the linear trend of the Padova series is positive, +0.31 ° C/100 yr over the period1774–today. Looking at post-industrial warming, the temperature rise is+0.44 ° C in the last 130 years, which means +0.34 ° C/100 yr, not farfrom the above bulk average.     

The action of neutral oleic acid in the flotation of hematite

Acidification of solutions of oleate salts forms emulsions of oleic acid. It was found that these emulsions produce a different adsorption behaviour on different size fractions of the same mineral. At low oleate concentrations, for the finer fractions, adsorption at acid pH was higher than chemisorption at pH = 7.5; adsorption was lower for the coarser, flotation-size fractions. Therefore, the conclusions obtained in acid solutions for the adsorption of oleate on fine minerals cannot be applied to flotation-size minerals.At low oleate concentrations there is a good correlation between oleate adsorption and hematite flotation. This does not hold for oleate concentrations > 5· 10^?5M, where there is poor flotability in the acid region, although the adsorption of oleic acid is very high. This is attributed to the disordered character of the layer of cooperatively adsorbed oleic acid.     

Pre-alpine and alpine evolution of the South-alpine basement of the Orobic Alps

New K-Ar age determinations on the gneisses and schists of the south-Alpine basement of the Orobic Alps and their separated minerals have been carried out to supplement and support the previous study ofBocchio et al. (1981).The cooling ages of biotites and muscovites range from 218 to 331 my and from 170 to 330 my respectively, according to a bimodal distribution with modes at 222 and 298 my for biotite, 182 and 322 my for muscovite. The whole rock ages spread from 43 to 402 my with no significant cluster. Only a few samples give statistically significant internal isochrones, and these suggest two periods of equilibration, at 226–245 and 312–368 my.These age determinations support the conclusion drawn from regional petrologic studies (Bocchio et al., 1980;Crespi et al., 1980), that the south-Alpine basement underwent two main phases of metamorphism, now preferentially preserved in different areas: an old, Hercynian phase under a regime of intermediate pressure (staur-ky type), and a young, post-Hercynian phase under a regime of low pressure (staur-sill type) reactivated by the cover of the thick sedimentary pile on top of the basement. Furthermore, radiometric ages also point out the widespread but irregularly distributed occurence of an alpine overprint under the conditions of a very low metamorphic regime, that is documented by the growth of post-kinematic stilpnomelane in rocks of suitable bulk composition (Crespi et al., 1981, 1982), as well as by fine-grained phengite.

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Zusammenfassung Neue Kali-Argon-Datierungen von Gneisen und Schiefern und ihrer abgetrennten Minerale des südalpinen Grundgebirges wurden in Ergänzung der Studie vonBocchio et al., 1981 durchgeführt. Die Abkühlungsalter der Biotite und Muskovite reichen von 218 bis 331 ma und von 170 bis 330 ma entsprechend einer bimodalen Entwicklung mit Modalwerten bei 222 und 298 ma für Biotit und 182 und 322 ma für Muskovit. Die Gesamtgesteinsalter reichen von 43–402 ma ohne signifikante Häufung. Nur wenige Proben geben eine statistisch signifikante Isochrone, woraus sich zwei Gleichgewichtsperioden zwischen 226–245 ma und 312–368 ma ablesen lassen.Diese Altersbestimmungen unterstützen die Schlußfolgerungen, die aus regional-petrologischen Studien (Bocchio et al., 1980;Crespi et al., 1980) gezogen wurden und die Aussagen, daß das südalpine Grundgebirge zwei Hauptphasen der Metamorphose mitgemacht hat, die heute in verschiedenen Gebieten erhalten sind: eine ältere herzynische Phase unter mittleren Druckbedingungen (Staur-Ky) und eine jüngere postherzynische Phase unter niedrigem Druck (Staur-Sil), die unter der Überdeckung einer mächtigen Sedimentserie über dem Grundgebirge reaktiviert wurde. Darüber hinaus deuten die radiometrischen Alter auf einen weit verteilten, aber unregelmäßig auftretenden alpinen Einfluß hin, der unter den Bedingungen einer sehr niedrigen Metamorphose aufgeprägt wurde. Dies wird dokumentiert durch das Wachstum postkinematischer Stilpnomelane in Gesteinen mit einer entsprechenden Zusammensetzung (Crespi et al., 1981, 1982) sowie von feinkörnigen Phenigiten.

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Résumé De nouvelles déterminations d'âge par la méthode K-Ar ont été effectuées sur les gneiss et les schistes du socle sudalpin des Alpes Orobiques, ainsi que sur certains de leurs minéraux, en complément aux travaux antérieurs deBocchio et al. (1981).L'âge du refroidissement des biotites s'étend de 210 à 331 Ma et celui des muscovites de 170 à 330 Ma, selon une distribution bimodale: modes à 222 à 298 Ma pour la biotite et à 183 et 322 Ma pour la muscovite. Les âges mesurés sur roche totale vont de 43 à 402 Ma sans concentration significative autour d'une valeur. Un petit nombre d'échantillons seulement fournissent des isochrones statistiquement significatives; elles suggèrent deux périodes de mise en équilibre, à 226–245 Ma et à 312–368 Ma.Ces déterminations d'âge appuient les conclusions d'études pétrologiques régionales antérieures (Bocchio et al. 1980;Crespi et al. 1980), à savoir que le socle sud-alpin a subi deux phases principales de métamorphisme, conservées aujourd'hui dans de régions différentes: une phase ancienne, hercynienne, de pression intermédiaire (type staurotide-disthène) et une phase jeune, post-hercynienne, de basse pression (type staurotide-sillimanite) réactivée sous la couverture sédimentaire épaisse reposant sur le socle. De plus, les âges radiométriques mettent en évidence une reprise alpine, d'extension régionale mais irrégulièrement distribuée, dans les conditions d'un métamorphisme de très faible degré. Cette reprise s'exprime par la croissance de stilpnomélane post-cinématique dans les roches de composition appropriée (Crespi et al. 1981, 1982) ainsi que par le développement de phengite finement grenue.

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. (1981), K/Ar-. 218 331 170 330 , 222 298 182 322 . 43–402 - . , 226–245 312–368 . . (1980) . (1980) , - : , , (Staur-Ky) , , (StaurSil) , . , , . ( ., 1981, 1982), .

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Paper presented at the Second E.U.G. Meeting at Strasbourg, April 23–26, 1983     

Size distribution models of fog and cloud droplets and their volume extinction coefficients at visible and infrared wavelengths

Based on the average variability of the skewness with respect to the droplet mode radius, a wide set of mean size-distribution models is presented in terms of the modified gamma function for fog and stratified cloud droplets. These models appear appropriate for giving reliable size-distribution curves relative to the various formation stages of the droplet population both in fogs and in stratus and stratocumulus clouds.The corresponding volume extinction coefficient has been computed at various wavelengths from 0.4 to 17 m using Van de Hulst's (1957) approximation multiplied by Deirmendjian's (1960) correction factors. This set of theoretical extinction data has been compared with experimental extinction measurements performed in atmospheres characterized by a marked thermal inversion for describing the evolutionary features of the water droplet size distribution within the whole ground layer.     

Simulation of South American wintertime climate with a nesting system

A numerical nesting system is developed to simulate wintertime climate of the eastern South Pacific-South America-western South Atlantic region, and preliminary results are presented. The nesting system consists of a large-scale global atmospheric general circulation model (GCM) and a regional climate model (RCM). The latter is driven at its boundaries by the GCM. The particularity of this nesting system is that the GCM itself has a variable horizontal resolution (stretched grid). Our main purpose is to assess the plausibility of such a technique to improve climate representation over South America. In order to evaluate how this nesting system represents the main features of the regional circulation, several mean fields have been analyzed. The global model, despite its relatively low resolution, could simulate reasonably well the more significant large-scale circulation patterns. The use of the regional model often results in improvements, but not universally. Many of the systematic errors of the global model are also present in the regional model, although the biases tend to be rectified. Our preliminary results suggest that nesting technique is a computationally low-cost alternative for simulating regional climate features. However, additional simulations, parametrizations tuning and further diagnosis are clearly needed to represent local patterns more precisely. Received: 18 February 1999 / Accepted: 31 May 2000