Multi‐scale analysis of a migrating submarine channel system in a tectonically‐confined basin: The Miocene Gorgoglione Flysch Formation,southern Italy

The Miocene Gorgoglione Flysch Formation records the stratigraphic product of protracted sediment transfer and deposition through a long‐lived submarine channel system developed in a narrow and elongate thrust‐top basin of the Southern Apennines (Italy). Channel‐fill deposits are exposed in an outcrop belt approximately 500 m thick and 15 km long, oriented oblique to the palaeoflow, which was roughly south‐eastward. These exceptional exposures of channel‐fill strata allow the stacking architectures and the evolution of the channel system to be analyzed at multiple scales, enabling the effects of syn‐sedimentary thrust tectonics and basin confinement on the depositional system development to be deciphered. Two end‐member types of elementary channel architecture have been identified: high‐aspect‐ratio, weakly‐confined channels, and low‐aspect‐ratio, incisional channels. Their systematic stacking results in a complex pattern of seismic‐scale depositional architectures that determines the stratigraphic framework of the deep‐water system. From the base of the succession, two prominent channel complex sets have been recognized, namely CS1 and CS2, consisting of amalgamated incisional channel elements and weakly‐confined channel elements. These channelized units are overlain by isolated incisional channels, erosional into mud‐prone slope deposits. The juxtaposition of different channel architectures is interpreted to have been governed by regional thrust‐tectonics, in combination with a high subsidence rate that promoted significant aggradation. In this scenario, the alternating ‘in sequence’ and ‘out of sequence’ tectonic pulses of the basin‐bounding thrusts controlled the activation of coarse‐clastic inputs in the basin and the resulting stacking architectures of channelized units. The tectonically‐driven confinement of the depositional system limited the lateral offset in channel stacking, preventing large‐scale avulsions. This study represents an excellent opportunity to analyze the stratigraphic evolution of a submarine channel system in tectonically‐active settings from an outcrop perspective. It should find wide applicability in analogous depositional systems, whose stratigraphic architecture has been influenced by tectonically‐controlled lateral confinement and associated lateral tilting.     

Three‐fold nature of coastal progradation during the Holocene eustatic highstand,Po Plain,Italy – close correspondence of stratal character with distribution patterns

Although general trends in transgressive to highstand sedimentary evolution of river‐mouth coastlines are well‐known, the details of the turnaround from retrogradational (typically estuarine) to aggradational–progradational (typically coastal/deltaic) stacking patterns are not fully resolved. This paper examines the middle to late Holocene eustatic highstand succession of the Po Delta: its stratigraphic architecture records a complex pattern of delta outbuilding and coastal progradation that followed eustatic stabilization, since around 7·7 cal kyr bp . Sedimentological, palaeoecological (benthic foraminifera, ostracods and molluscs) and compositional criteria were used to characterize depositional conditions and sediment‐dispersal pathways within a radiocarbon‐dated chronological framework. A three‐stage progradation history was reconstructed. First, as soon as eustasy stabilized (7·7 to 7·0 cal kyr bp ), rapid bay‐head delta progradation (ca 5 m year^?1), fed mostly by the Po River, took place in a mixed, freshwater and brackish estuarine environment. Second, a dominantly aggradational parasequence set of beach‐barrier deposits in the lower highstand systems tract (7·0 to 2·0 cal kyr bp ) records the development of a shallow, wave‐dominated coastal system fed alongshore, with elongated, modestly crescent beaches (ca 2·5 m year^?1). Third, in the last 2000 years, the development of faster accreting and more rapidly prograding (up to ca 15 m year^?1) Po delta lobes occurred into 30 m deep waters (upper highstand systems tract). This study documents the close correspondence of sediment character with stratal distribution patterns within the highstand systems tract. Remarkable changes in sediment characteristics, palaeoenvironments and direction of sediment transport occur across a surface named the ‘A–P surface’. This surface demarcates a major shift from dominantly aggradational (lower highstand systems tract) to fully progradational (upper highstand systems tract) parasequence stacking. In the Po system, this surface also reflects evolution from a wave‐dominated to river‐dominated deltaic system. Identifying the A–P surface through detailed palaeoecological and compositional data can help guide interpretation of highstand systems tracts in the rock record, especially where facies assemblages and their characteristic geometries are difficult to discern from physical sedimentary structures alone.     

Numerical support of laboratory experiments: Attenuation and velocity estimations

We show that numerical support of laboratory experiments can significantly increase the understanding and simplify the interpretation of the obtained laboratory results. First we perform simulations of the Seismic Wave Attenuation Module to measure seismic attenuation of reservoir rocks. Our findings confirm the accuracy of this system. However, precision can be further improved by optimizing the sensor positions. Second, we model wave propagation for an ultrasonic pulse transmission experiment used to determine pressure- and temperature-dependent seismic velocities in the rock. Multiple waves are identified in our computer experiment, including bar waves. The metal jacket that houses the sample assembly needs to be taken into account for a proper estimation of the ultrasonic velocities. This influence is frequency-dependent.     

Long-time variation of soil CO2 fluxes at the summit crater of Vulcano (Italy)

Here, we report the first continuous data of geochemical parameters acquired directly from the active summit crater of Vulcano. This approach provides a means to better investigate deep geochemical processes associated with the degassing system of Vulcano Island. In particular, we report on soil CO₂ fluxes from the upper part of Vulcano, a closed-conduit volcano, from September 2007 to October 2010. Large variations in the soil CO₂ and plume SO₂ fluxes (order of magnitude), coinciding with other discontinuous geochemical parameters (CO₂ concentrations in fumarole gas) and physical parameters (increase of shallow seismic activity and fumarole temperatures) have been recorded. The results from this work suggest new prospects for strengthening geochemical monitoring of volcanic activity and for improving the constraints in the construction of a “geochemical model”, this being a necessary condition to better understand the functioning of volcanic systems.     

Methane levels in shallow subtropical lake sediments: Dependence on the trophic status of the lake and allochthonous input

The vertical sediment profiles (10 cm) of the margins of three shallow subtropical lakes (Rio Grande, Brazil) with different trophic states and surrounding areas were evaluated to identify the effects of the allochthonous input on the methane concentration in the sediment. Sediment cores were collected to quantify the organic matter content (OM) and total carbon (TC), total nitrogen (TN), total phosphorous (TP) and methane (CH₄) concentrations.The three lakes were distinguished according to the trophic status and classified as oligotrophic, dystrophic and eutrophic. The natural characteristics of the dystrophic and eutrophic lakes have been changed due to the allochthonous input of leaves and twigs (Eucalyptus sp.) and the excreta of birds, respectively. In the eutrophic lake, the allochthonous input contributed to high autochthonous production. The highest values of OM, TC, TN and TP were found in the superficial sediments of the dystrophic and eutrophic lakes. The accumulation of allochthonous organic matter in the littoral zone promoted changes in the vertical sediment profiles and contributed to increases in the CH₄ concentrations in the sediment.     

A macro‐model with nonlinear springs for seismic analysis of URM buildings

Seismic assessment of existing unreinforced masonry buildings represents a current challenge in structural engineering. Many historical masonry buildings in earthquake regions were not designed to withstand seismic loading; thus, these structures often do not meet the basic safety requirements recommended by current seismic codes and need to be strengthened considering the results from realistic structural analysis. This paper presents an efficient modelling strategy for representing the nonlinear response of unreinforced masonry components under in‐plane cyclic loading, which can be used for practical and accurate seismic assessment of masonry buildings. According to the proposed strategy, generic masonry perforated walls are modelled using an equivalent frame approach, where each masonry component is described utilising multi‐spring nonlinear elements connected by rigid links. When modelling piers and spandrels, nonlinear springs are placed at the two ends of the masonry element for describing the flexural behaviour and in the middle for representing the response in shear. Specific hysteretic rules allowing for degradation of stiffness and strength are then used for modelling the member response under cyclic loading. The accuracy and the significant potential of the proposed modelling approach are shown in several numerical examples, including comparisons against experimental results and the nonlinear dynamic analysis of a building structure. Copyright © 2016 John Wiley & Sons, Ltd.     

Magma storage and ascent at Lipari Island (Aeolian archipelago, Southern Italy) at 223–81 ka: the role of crustal processes and tectonic influence

Fluid inclusion studies together with volcanological and petrochemical data allow reconstruction of the magma feeding system of basaltic-andesitic to andesitic activity during the oldest and intermediate stages of development of Lipari Island (223–81 ka). A major magma storage zone is active during the overall investigated time span at depths of 22 km, close to the crust-mantle Moho transition, at which mantle-derived mafic magmas tend to accumulate due to neutral buoyancy conditions. Beneath central-type volcanoes (M. Mazzacaruso, M. S.Angelo, M. Chirica-Costa d’Agosto), a shallower magma reservoir is located within the upper crust at 5.5–3.5 km, associated with a major lithological discontinuity. For fissural-type volcanoes (Timpone Ospedale, Monterosa, M. Chirica), tectonic structures are suggested to influence further magma ascent and storage at mid-crustal depths (∼14 km), with no ponding at shallower levels. Partial crustal melting processes at the roofs of the deep magma reservoirs (∼17 km) are invoked to explain the origin of cordierite-bearing lavas beneath M. S.Angelo and M. Chirica-Costa d’Agosto volcanoes, which were active during the intermediate stages of development of Lipari (105–81 ka). The generation of felsic anatectic melts in the lower crust could have created density and rheologic barriers to impede the passage of mafic melts and promote their ponding, with influence on the subsequent evolution of Lipari volcano.     

Accuracy assessment of the GPS-based slant total electron content

The main scope of this research is to assess the ultimate accuracy that can be achieved for the slant total electron content (sTEC) estimated from dual-frequency global positioning system (GPS) observations which depends, primarily, on the calibration of the inter-frequency biases (IFB). Two different calibration approaches are analyzed: the so-called satellite-by-satellite one, which involves levelling the carrier-phase to the code-delay GPS observations and then the IFB estimation; and the so-called arc-by-arc one, which avoids the use of code-delay observations but requires the estimation of arc-dependent biases. Two strategies are used for the analysis: the first one compares calibrated sTEC from two co-located GPS receivers that serve to assess the levelling errors; and the second one, assesses the model error using synthetic data free of calibration error, produced with a specially developed technique. The results show that the arc-by-arc calibration technique performs better than the satellite-by-satellite one for mid-latitudes, while the opposite happens for low-latitudes.     

Tracing clinothem geometry and sediment pathways in the prograding Holocene Po Delta system through integrated core stratigraphy

Though clinothem geometry represents a key control on fluid flow in reservoir modelling, tracing clinothem boundaries accurately is commonly limited by the lack of sufficiently precise outcrop or subsurface data. This study shows that in basin systems with strongly heterogeneous compositional signatures, the combination of bulk-sediment geochemistry and benthic foraminiferal distribution can help identify clinothem architecture and generate realistic models of 3D deltaic upbuilding and evolution. Middle-late Holocene deposits in the Po Delta area form an aggradational to progradational parasequence set that reveals the complex interaction of W–E Po Delta progradation, S-directed longshore currents (from Alpine rivers) and Apennines rivers supply. Unique catchment lithologies (ophiolite rocks and dolostones) were used to delineate basin-wide geochemical markers of sediment provenance (Cr and Mg) and to assess distinctive detrital signatures. The geochemical characterization of cored intervals across different components of the sediment routing system enabled a direct linkage between clinothem growth, transport pathways and provenance mixing to be established. On the other hand, abrupt microfaunal variations at clinothem boundaries were observed to reflect the palaeoenvironmental response to sharp changes in sediment flux and fluvial influence. This study documents the ability of an integrated geochemical and palaeoecological approach to delineate three distinct sources (Po, Alps and Apennines) that contributed to coastal progradation and to outline the otherwise lithologically cryptic geometries of clinothems that using conventional sedimentological methods it would be virtually impossible to restore.     

A new simple approach to evaluate pedogenic clay transformation in a Vertic Calcisol

The aim of this study is to characterize the pedogenic clay minerals by using simple approach: mixing mineralogical and geochemical findings.The fine clay fractions (< 0.1 μm) of a Vertic Cambisol profile were studied by means of X-ray diffraction (XRD), infrared spectroscopy (FTIR) and cation exchange capacity (CEC).Qualitative and quantitative mineralogical compositions of the clay mixture were determined.Moreover, chemical equilibria and thermodynamic stabilities of minerals (calcite, gypsum, kaolinite, smectites and illites) were studied using results of ionic activities obtained from total concentration of various aqueous species in water extracts from soil-saturated pastes.XRD analysis shows a good homogeneity in the mineralogical composition of the soil material, with depth of soil profiles. The identified clay minerals are mainly illite–smectite mixed layers (I/S) and kaolinite. The chemical analysis of saturated paste extracts with clay minerals shows a slight undersaturation of the illitic phase while smectites and also calcite and gypsum reach the thermodynamic equilibrium along the soil profile.