A Paddock to reef monitoring and modelling framework for the Great Barrier Reef: Paddock and catchment component

Targets for improvements in water quality entering the Great Barrier Reef (GBR) have been set through the Reef Water Quality Protection Plan (Reef Plan). To measure and report on progress towards the targets set a program has been established that combines monitoring and modelling at paddock through to catchment and reef scales; the Paddock to Reef Integrated Monitoring, Modelling and Reporting Program (Paddock to Reef Program). This program aims to provide evidence of links between land management activities, water quality and reef health. Five lines of evidence are used: the effectiveness of management practices to improve water quality; the prevalence of management practice adoption and change in catchment indicators; long-term monitoring of catchment water quality; paddock & catchment modelling to provide a relative assessment of progress towards meeting targets; and finally marine monitoring of GBR water quality and reef ecosystem health. This paper outlines the first four lines of evidence.     

Photochemical degradation of phenanthrene as a function of natural water variables modeling freshwater to marine environments

Photolysis rates of phenanthrene as a function of ionic strength (salinity), oxygen levels and humic acid concentrations were measured in aqueous solution over the range of conditions found in fresh to marine waters. Photolysis followed first order kinetics, with an estimated photodegradation half-life in sunlight in pure water of 10.3±0.7h, in the mid-range of published results. Photolysis rate constants decreased by a factor of 5 in solutions with humic acid concentrations from 0 to 10 mg C L(-1). This decrease could be modeled entirely based on competitive light absorption effects due to the added humics. No significant ionic strength or oxygen effects were observed, consistent with a direct photolysis mechanism. In the absence of significant solution medium effects, the photodegradation lifetime of phenanthrene will depend only on solar fluxes (i.e. temporal and seasonal changes in sunlight) and not vary with a freshwater to marine environment.     

Applicability of Individual Transferable Quotas (ITQs) in Japanese fisheries: A comparison of rights-based fisheries management in Iceland, Japan, and United States

ITQs have not yet been introduced by the Government of Japan. In coastal areas, fishery cooperative associations have traditionally played an important role in managing fisheries through self-imposed rules and peer-monitoring systems. Recently, however, the economic competitiveness of Japanese fisheries in the international market is being questioned. In this paper, a detailed examination of the pros and cons of the current system in Japan is compared to the current fishery management measures of Iceland and the United States, where attaining economically or biologically efficient outcomes may be prioritized in making fisheries management decisions. For many coastal fisheries in Japan, maintaining a management scheme in which stakeholders play an active role in determining fisheries measures seems more relevant if their priority is to maintain the stability of coastal communities and equity of stakeholders. Intensive dialog among stakeholders would be necessary to identify shared objectives of their fishery operations and to make decisions to establish specific steps toward the goal of increasing economic efficiency, environmental sustainability, or stability of communities and equity of stakeholders.     

Divergent Perspectives on Water Security: Bridging the Policy Debate

Environmental policy discussion is replete with references to water security, food security, ecosystem health, community resilience, sustainable development, and sustainable urbanism. These terms are, by their very nature, ambiguous and difficult to define; they allow room, however, for a variety of actors to conceptualize water, food, ecological, economic, and urban problems in ways that allow them to move forward on contentious issues. This article focuses on the idea of water security and asks how it is conceptualized and used for regional policy debate in western Canada. We asked fifty-eight water stakeholders from the Saskatchewan River Basin to define water security, identify major barriers to security, and prioritize water problems. Responses showed there are myriad ways to think about water security, ranging from narrow conceptualizations, such as reliability, quality, and quantity, to broader sustainability perspectives about the nature of resource development and its social and economic consequences. The human dimensions of water security (governance, land use, and competing demands) were assigned higher priority than its biophysical aspects (flooding, droughts, and climate change). Framing water security to emphasize the human capacity to manage uncertain and rapid biophysical and societal change offers the opportunity to unite actors who otherwise would be separated by core environmental values, definitions of water security, provincial context (Alberta vs. Saskatchewan), and occupation.     

The Production of Investment Returns in Spatially Extensive Financial Markets

Investment returns are produced by combining financial assets with human capital, the decision-making protocols of investment houses, and the electronic infrastructure that supports the flow of information about investment. At the center of the production process stand senior managers; their power and authority in the production process is fundamental to the performance of investment organizations. This article provides a model of the production of investment returns in financial centers and spatially extensive financial markets. We begin with Coase's theory of the firm but go beyond models of the firm that represent commodity-producing industries. Having substantiated the model of investment management, it is applied to institutions that seek investment returns in geographically extensive financial markets. Operating in financial markets at a distance from home jurisdictions is an increasingly important aspect of investment management. Given recent turmoil in global financial markets, financial houses have sought higher rates of return from markets in which they have little direct experience. At issue is how different types of financial organizations (large and small, growing and declining) produce investment returns in this new environment.     

Soil quality and human migration in Kenya and Uganda

Soil degradation is widely considered to be a key factor undermining agricultural livelihoods in the developing world and contributing to rural out-migration. To date, however, few quantitative studies have examined the effects of soil characteristics on human migration or other social outcomes for potentially vulnerable households. This study takes advantage of a unique longitudinal survey dataset from Kenya and Uganda containing information on household-level soil properties to investigate the effects of soil quality on population mobility. Random effects multinomial logit models are used to test for effects of soil quality on both temporary and permanent migration while accounting for a variety of potential confounders. The analysis reveals that soil quality significantly reduces migration in Kenya, particularly for temporary labor migration, but marginally increases migration in Uganda. These findings are consistent with several previous studies in showing that adverse environmental conditions tend to increase migration but not universally, contrary to common assumptions about environmentally-induced migration.     

Relationship among titanium,rare earth elements,U–Pb ages and deformation microstructures in zircon: Implications for Ti-in-zircon thermometry

A zircon grain in an orthopyroxene–garnet–phlogopite–zircon–rutile-bearing xenolith from Udachnaya, Siberia, preserves a pattern of crystallographic misorientation and subgrain microstructure associated with crystal–plastic deformation. The zircon grain records significant variations in titanium (Ti) from 2.6 to 30 ppm that corresponds to a difference in calculated Ti-in-zircon temperatures of over several hundred degrees Celsius. The highest Ti concentration is measured at subgrain centres (30 ppm), and Ti is variably depleted at low-angle boundaries (down to 2.6 ppm). Variations in cathodoluminescence coincide with the deformation microstructure and indicate localised, differential enrichment of rare earth elements (REE) at low-angle boundaries. Variable enrichment of U and Th and systematic increase of Th/U from 1.61 to 3.52 occurs at low-angle boundaries. Individual SHRIMP-derived U–Pb ages from more deformed zones (mean age of 1799 ± 40, n = 22) are systematically younger than subgrain cores (mean age of 1851 ± 65 Ma, n = 7), and indicate that open system behaviour of Ti–Th–U occurred shortly after zircon growth, prior to the accumulation of significant radiogenic Pb. Modelling of trace-element diffusion distances for geologically reasonable thermal histories indicates that the observed variations are ~ 5 orders of magnitude greater than can be accounted for by volume diffusion. The data are best explained by enhanced diffusion of U, Th and Ti along deformation-related fast-diffusion pathways, such as dislocations and low-angle (< 5°) boundaries. These results indicate chemical exchange between zircon and the surrounding matrix and show that Ti-in-zircon thermometry and U–Pb geochronology from deformed zircon may not yield information relating to the conditions and timing of primary crystallisation.     

Use of daily precipitation uncertainties in streamflow simulation and forecast

Among other sources of uncertainties in hydrologic modeling, input uncertainty due to a sparse station network was tested. The authors tested impact of uncertainty in daily precipitation on streamflow forecasts. In order to test the impact, a distributed hydrologic model (PRMS, Precipitation Runoff Modeling System) was used in two hydrologically different basins (Animas basin at Durango, Colorado and Alapaha basin at Statenville, Georgia) to generate ensemble streamflows. The uncertainty in model inputs was characterized using ensembles of daily precipitation, which were designed to preserve spatial and temporal correlations in the precipitation observations. Generated ensemble flows in the two test basins clearly showed fundamental differences in the impact of input uncertainty. The flow ensemble showed wider range in Alapaha basin than the Animas basin. The wider range of streamflow ensembles in Alapaha basin was caused by both greater spatial variance in precipitation and shorter time lags between rainfall and runoff in this rainfall dominated basin. This ensemble streamflow generation framework was also applied to demonstrate example forecasts that could improve traditional ESP (Ensemble Streamflow Prediction) method.     

Bioattenuation in groundwater impacted by landfill leachate traced with δ13C

The impact on groundwater imparted by the infiltration of high dissolved organic carbon (DOC) leachate from capped, unlined landfills can be attenuated by biogeochemical reactions beyond the waste source, although such reactive loss in the aquifer is difficult to distinguish from conservative advective dispersion. Compound-specific measurement of δ(13)C in carbon species, including CH(4), dissolved inorganic carbon (DIC), and the major DOC compounds (acetate, humic acid, and fulvic acid) provides a constraint in this assessment that can assist in exercises of modeling and prediction of leachate transport. The Trail Road municipal landfill near Ottawa, Ontario, Canada, hosts an unlined sector which produces a highly enriched leachate (DOC >4500 mg/L) that provides a good site to examine reactive attenuation within the receptor aquifer. Acetate, a sentinel component of leachate DOC (~1000 mg C/L), is absent in impacted groundwater. Mass balance calculations together with reaction modeling suggest continued acetate fermentation with calcite control on DIC and δ(13)C(DIC) evolution. In groundwater within 50 m of the landfill, methane concentrations are elevated (~10 mg/L), consistent with acetate fermentation, whereas δ(13)C(CH4) measurements in deeper groundwater range down to -51‰ compared with -60‰ in the landfill demonstrating oxidative loss. DOC in the deep aquifer is remarkably depleted to values less than -40‰ suggesting methanotrophic bacteria selectively consume isotopically light CH(4) to fix carbon. Continued reaction of leachate DOC in groundwater is demonstrated by evolution away from conservative mixing lines on diagrams of δ(13)C vs. concentrations of DIC and DOC.     

Origin of magmatic sulfides in a Proterozoic island arc—an example from the Portneuf–Mauricie Domain,Grenville Province,Canada

The Portneuf–Mauricie Domain (PMD), located in the south-central part of the Grenville province, contains Mesoproterozoic Ni–Cu ± platinum-group element (PGE) prospects hosted in a variety of plutonic intrusions (layered, with simple structures, or zoned) and emplaced in a mature island arc setting. A two-stage model is envisaged to explain the formation of magmatic sulfides. An early loss of a small amount of sulfides in the conduits of primitive, hydrous mantle-derived melts under high fO₂, resulted in depletion of the magmas in chalcophile and precious metals (Cu/Pd ratios vary from initial mantle values up to 1.6 × 10⁶). Then, nearer the mineralized zones, the magmas interacted with sulfide-bearing country rocks, resulting in felsification of the magmas, assimilation of crustal sulfur (δ ³⁴S values up to +5.5‰), and the formation of an immiscible sulfide liquid. Liquid-sulfide formation was followed by variable interactions between the silicate and sulfide magmas, which were responsible for the enrichment of sulfides in Ni, Cu, and, locally, PGE. Indeed, low R factors are found for prospects hosted in intrusions with a simple internal structure and in layered intrusions whereas high R factors are found for prospects hosted in zoned intrusions. Finally, sulfide melt may have been partly incorporated into later pulses of magma and injected into shallow magma chambers to form the PMD prospects. The PMD prospects share common characteristics with other well-known deposits (Aguablanca, Vammala, Stormyrplunen, and deposits in Alaskan/Ural-type intrusions), attesting to the Ni, Cu, and PGE potential of deposits associated with subduction-zone settings.