Sample treatment with focused ultrasound and bath sonication as a powerful tool for the evaluation of cadmium pollution in estuarine waters

A new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration. Cadmium was first pre-concentrated using a classical approach (APDC as the complexing agent and MIBK as the organic phase) and then back-extracted into HNO₃ with the aid of focused ultrasound, which reduced the acid concentration by more than one order of magnitude (from 4 to 0.1 mol L^− 3). This sample treatment was accomplished in less than 5 min, using low sample volume (20 mL), and low-volume, low-concentration reagents. The pre-concentration factor used in this work was 25, but different sample/organic volume ratios may be used in order to increase that value. The limit of detection and the limit of quantification in Tagus water samples were 0.03 nmol L^− 1 and 0.1 nmol L^− 3, respectively. Recoveries from spiked Tagus water were higher than 90%. The procedure was validated using the reference estuarine water NRC-SLEW-3. In the solubilization of Cd particulate, bath ultrasonication was used in conjunction with HNO₃ + HCl, followed by H₂O₂, which took about 2 instead of the usual 12 h (cooling included) when high-pressure microwave digestion is used.     

Suspended sediment concentration in a buoyant plume: Fraser River,Canada

A study of suspended sediment concentration in the buoyant plume of the Fraser River, Canada, showed that unstratified flow conditions at the river mouth caused resuspension of sandy bed material and high concentrations of coarse sediment. When flow at the mouth was stratified, sediment was fine-grained and concentrations were low. Application of a multivariate model revealed that suspended sediment concentration along the plume axis was controlled primarily by distance seaward of the river mouth, secondly by tidal height, and least by sediment concentration in the river.     

Suspended barite as a tracer of biological activity in the Southern Ocean

During two cruises in the Southern Ocean (INDIGO 3, Indian sector and EPOS 2, Scotia-Weddell Confluence) suspended matter samples were collected for analysis of several biogenic elements including Ba, Si and particulate organic carbon (POC).The good agreement between particulate barium in subsurface water with oxygen minimum concentrations as well as with nitrate depletions suggests that it reflects the intensity of new production over the past season. As a consequence of new production in the Southern Ocean being performed mainly by diatoms, the occurrences of barite and diatoms are related in the water column. In areas characterized by diatom-poor phytoplankton, barite does occur, but in lower concentrations.     

Marine mammals from northeast Atlantic: relationship between their trophic status as determined by delta13C and delta15N measurements and their trace metal concentrations

The relationship between trophic position through delta13C and delta15N and trace metal concentrations (Zn, Cd, Cu and Hg) was investigated in the tissues of six marine mammal species from the Northeast Atlantic: striped dolphin Stenella coeruleoalba, common dolphin, Delphinus delphis, Atlantic white-sided dolphin Lagenorhynchus acutus, harbour porpoise Phocoena phocoena, white beaked-dolphin Lagenorhynchus albirostris, grey seal Halichoerus grypus stranded on French Channel and Irish coasts. White-beaked dolphins, harbour porpoises, white-sided dolphins, common and striped dolphins display the same relative and decreasing trophic position, as measured by delta15N values, along both the Irish and French channel coasts, reflecting conservative trophic habits between these two places. Hepatic and renal Cd concentrations were significantly correlated to muscle delta13C and delta15N values while Hg, Zn and Cu did not. These results suggest that Cd accumulation is partly linked to the diet while other factors such as age or body condition might explain Hg, Zn or Cu variability in marine mammals. Combined stable isotope and trace metal analyses appear to be useful tools for the study of marine mammal ecology.     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

Stratigraphy and inversion tectonics in the St. Georges Channel area off SW Wales,U.K.

Transgressive Upper Cretaceous Chalk terminates (between SW Wales and SE Ireland) at approximately latitude 52°N as thinly bedded marginal facies; while the Tertiary sequences, previously considered to extend uninterrupted into both the South Celtic Sea area and the Nymphe Bank basin are preserved as isolated subcrops separated by Jurassic. The distinct subsidence history of St. Georges Channel basin, as compared to the Nymphe Bank basin which both belong to the North Celtic Sea graben, is attributed to inversion activity with the final phase occurring during the Paleogene.     

Motions in the field of two rotating magnetic dipoles. III: Zero-velocity curves and surfaces

The zero-velocity curves and surfaces created by two parallel or antiparallel magnetic dipoles moving on concentric circles are computed. It is found that for all combinations of values of the mass parameter µ and the ratio of the magnitudes of the magnetic moments of the two dipoles, there exist closed regions inside of which charged particles are permanently trapped.     

The University of Durham Southern Hemisphere VHE gamma ray telescope

The design of very high energy (VHE) gamma ray telescopes is discussed and it is shown that a triple-mirror telescope operating in threefold fast coincidence provides an effective instrument. The design, construction and operation of a large VHE gamma ray telescope with an energy threshold of 300 GeV (at the zenith) and incorporating several novel features is described. The use of a coincidence guard ring technique is shown to result in the rejection of about 50% of the off-source (proton) events which form a high background and limit the sensitivity of such telescopes.     

Studies on post-flare loop prominence of 1981 April 27

By use of the H observations of the Astrophysical Observatory in Catania, Italy and the Purple Mountain Observatory in Nanking, China as well as hard X-ray and gamma-ray burst data from the Solar Maximum Mission (SMM) Gamma-Ray Spectrometer (GRS), a major eruptive loop prominence was studied during the limb solar flare event of 1981 April 27.Our preliminary analysis shows that there seems to exist a second abrupt energy release for this event, almost 20 min after the end of the impulsive phase of the flare. This energy release is probably associated with the rapidity in upward motion or activation of the loop prominence.A possible candidate for such a process could be the reconnection of the old magnetic field with a newly emerging magnetic field.A theoretical gross estimate for the energy release and particle acceleration has also been made in this work. It appears that the proposed model for charged particle acceleration is very efficient.     

The U.S. National 8 m telescope project

The National Optical Astronomy Observatories (NOAO) are planning to buld two 8 m telescopes, one for Mauna Kea, Hawaii, the other for a site in Chile. Optical configurations, primary mirror systems, and the telescope mounting are discussed. A new optical testing method is outlined. The system imaging goal is 0.25 FWHM. Construction could begin in the early 1990's.Paper presented at the Symposium on the JNLT and Related Engineering Developments, Tokyo, November 29–December 2, 1988.Operated by the Association of Universities for Research in Astronomy Inc., under contract with the National Science Foundation.