Simulation of the nucleation and growth of binary solid solutions in aqueous solutions

We present a model which, for the first time, accounts for nucleation, growth and/or resorption of particles of variable composition in aqueous solutions (AS). Devised for describing the precipitation of binary solid solutions, it yields the time evolution of all ion activities in the AS, together with the particle population characteristics: number, size and composition profile of particles as a function of time and of their time of nucleation. We apply this numerical approach to the prototypical case of (Ba,Sr)CO₃ solid solution precipitation. We demonstrate the great sensitivity of the composition profiles and particle sizes to the initial conditions under which the AS is prepared, and thus illustrate the possibility of engineering the particle characteristics into a chosen state. Finally, by comparing the precipitation of two solid solutions (Ba,Sr)CO₃ and (Ba,Sr)SO₄, we evidence the sensitivity of the particle composition profiles to the ratio of the end-member solubility products, which leads to the formation of core-shell particles in the case of (Ba,Sr)SO₄.     

Definition of areas of probable risk to human health posed by As and Pb in soils and ground-level dusts of the surrounding area of an abandoned As-sulfide mine in the north of Portugal: part 1

The aim of this study is to assess the potential health risk posed by As and Pb in the soils of the Pintor mine area. The site was never remediated but a residential area is being constructed in the mine land, next to the smelters, a fact that raised some concern about the probable risk posed by potentially harmful elements in the soil to the health of the residents. 132 samples were collected and analyzed by ICP-MS to determine total metal concentrations. The soluble fraction of As in the soil was obtained using 1 M NH₄ Acetate, pH 4.5. To assess the probable risk, total concentrations are compared with the soil guideline value established for the UK. Exposure through soil ingestion is probable in and around the residential area that has higher As and Pb concentrations, and therefore is classified as area with a potential health risk.     

Depuration dynamics of oysters (Crassostrea gigas) artificially contaminated by Salmonella enterica serovar Typhimurium

The State of Santa Catarina produces the greatest quantity of edible mollusks in Brazil. To guarantee sanitary qualify, mollusk cultures should be monitored for contamination by pathogenic microorganisms. A self-purification or "depuration" system that eliminates Salmonella enterica serovar Typhimurium contamination from oysters has been developed and evaluated. The depuration process occurred within a closed system, in which 1000 L of water was recirculated for 24 h. The water was sterilized with ultraviolet (UV) light, chlorine, or both together. Oysters (Crassostrea gigas) artificially contaminated with S. typhimurium were harvested every 6 h. Samples of oyster tissue were excised and both the presence and numbers of bacteria were determined. Combined UV light and chlorine treatments resulted in total elimination of bacteria within 12 h. Polymerase chain reaction detected bacteria in water exposed to the three treatments. This pioneering study is the first of its kind in Brazil and represents a major contribution to commercial mollusk culture in this country.     

Personennachrichten

Ohne Zusammenfassung     

Zur Morphologie,Systematik und Entwicklungsgeschichte der Vereinskurve

Ohne Zusammenfassung     

Wave-induced setup of the mean surface over a sloping beach

A new theoretical approach for the wave-induced setup over a sloping beach is presented that takes into consideration the explicit variations of the surface waves due to bottom slope and viscosity. In this way, the wave forcing of the mean Lagrangian volume fluxes is calculated without assuming that the local depth is constant. The analysis is valid in the region outside the surf zone and is based on the shallow-water assumption. A novel approach for separating the viscous damping of the waves from the frictional damping of the mean flow is introduced, where the mean Eulerian velocity is applied in the bottom stress for the mean fluxes. In the case where the onshore Lagrangian mean transport is zero, a new formula is derived for the Eulerian mean free surface slope, in which the effects of bottom slope, viscous wave damping and frictional bottom drag on the mean flow are clearly identified. The analysis suggests that viscous damping of the waves and frictional dissipation of the Eulerian near-bed return flow could lead to setup outside the surf zone.     

From the Oort cloud to observable short-period comets – I. The initial stage of cometary capture

We investigate the first stage of the dynamical evolution of Oort cloud comets entering the planetary region for the first time. To this purpose, we integrate numerically the motions of a large number of fictitious comets pertaining to two samples, both with perihelion distances up to 5.7 au and random inclinations; the first sample is composed of comets whose orbits have at least one node close to 5.2 au, while the second is not subject to this constraint. We examine the orbits when the comets come to aphelion after their first perihelion passage within the planetary region, and find that there is a clear statistical dependence of the energy perturbations on the Tisserand parameter. There appear to be two main processes, of comparable importance, governing the shortening of semimajor axes to values of less than 1000 au, i.e. planetary close encounters, especially with Jupiter, and indirect perturbations due to the shifting of the motion from barycentric to heliocentric and back; the former process mostly affects comets crossing the ecliptic at about 5.2 au, or on low-inclination orbits, while the latter mostly affects comets of small perihelion distance. This last result may help to understand the relative paucity of Halley-type comets with perihelion distances larger than about 1.5 au.     

Comparison of surface wind stress characteristics over the Tropical Atlantic (10°N–40°S) in fields derived from the UWM/COADS, NCEP/NCAR and QuikSCAT datasets

A comparison of monthly wind stress derived from winds of NCEP/NCAR (National Centers for Environmental Prediction/National Center for Atmospheric Research) reanalysis and UWM/COADS (The University of Wisconsin-Milwaukee/Comprehensive Ocean-Atmosphere Data Set) dataset (1950–1993), and of NCEP/NCAR reanalysis and satellite-based QuikSCAT dataset (2000–2006), is made over the South Atlantic (10°N–40°S). On a mean seasonal scale, the comparison shows that these three wind stress datasets have qualitatively similar patterns. Quantitatively, in general, from about the equator to 20°S in the mid-Atlantic the wind stress values are stronger in NCEP/NCAR data than those in UWM/COADS data. On the other hand, in the Intertropical Convergence Zone (ITCZ) area the wind stress values in NCEP/NCAR data are slightly weaker than those in UWM/COADS data. In the South Atlantic, between 20° S–40°S, the QuikSCAT dataset presents complex circulation structures which are not present in NCEP/NCAR and UWM/COADS data. The wind stress is used in a numerical ocean model to simulate ocean currents, which are compared to a drifting-buoy observed climatology. The modeled South Equatorial Current agrees better with observations between March–May and June–August. Between December–February, the South Equatorial Current from UWM/COADS and QuikSCAT experiments is stronger and more developed than that from NCEP/NCAR experiment. The Brazil Current, in turn, is better represented in the QuikSCAT experiment. Comparison of the annual migration of ITCZ at 20° and 30°W in UWM/COADS and NCEP/NCAR data sources show that the southernmost position of ITCZ at 30°W in February, March and April coincides with the rainy season in NE Brazil, while the northernmost position of ITCZ at 20°W in August coincides with the maximum rainfall of Northwest Africa.     

Rockfalls detached from a lateral moraine during spring season. 2010 and 2011 events observed at the Rebaixader debris-flow monitoring site (Central Pyrenees, Spain)

Instability processes at glacial deposits represent an important hazard in mountainous areas. During the spring seasons of 2010 and 2011, two falls of large boulders (18 and 55? m³) initiated in a lateral moraine in the Rebaixader catchment (Central Pyrenees, Spain). Detailed information was gathered due to the debris-flow monitoring system installed along the torrent. Meteorological data showed that the two rockfalls were triggered without important rainfall amounts. Field surveys, ground vibration acquired at geophones and the movie recorded with a video camera provided unique information on the rockfall occurrence and dynamics. In addition, the information gave an excellent opportunity to show the importance of monitored data for the calibration of model parameters for runout simulations. The analysis focussed on the 2011 event and showed that the boulder passed rolling and bouncing through the monitored torrent reach. The velocity estimates in this reach range from 3 to 9 ?m/s. The 2011 rockfall was also back-analysed by a two-dimensional physically based model, which was fitted by the monitored and field data. The results of the simulation coincided well with recorded measurements, although the output could be improved by the application of a three-dimensional model.