Mineralogy and geochemistry of the sodium metasomatism-related uranium occurrence of Aricheng South, Guyana

The Aricheng South uranium occurrence is associated with Na metasomatism that affected the granitoids of the Kurupung Batholith in western Guyana. The mineral paragenesis indicates that late-magmatic albitization was followed by chlorite alteration of biotite. A minor amount of uraninite occurs in fractures in the newly formed albite crystals, often in company of calcite. The main mineralization stage occurred later than albitization and chloritization and is represented by brannerite disseminated in a groundmass of fine-grained hydrothermal zircon. Whole rock geochemistry supports the temporal dissociation of albitization from the main ore stage. Brannerite, zircon, and uraninite are often partially altered to secondary brannerite, zircon, and coffinite, respectively. Stable oxygen (chlorite, calcite) and hydrogen (chlorite) isotope compositions suggest that a highly evolved meteoric fluid, or at least one corresponding to a very high rock/fluid ratio (δ¹⁸O of approx. 3.4% to 4‰ and δD of approx. −80‰) may have caused the pre-ore alteration assemblage. The fluids in equilibrium with main ore stage zircon have δ¹⁸O of approx. 6.8‰ and appear to be of magmatic origin. The Aricheng occurrence geochemically, mineralogically, thermally, and paragenetically resembles the Valhalla U deposit in northern Australia despite differences between the deposits’ host lithologies, whereas the Lagoa Real and Espinharas U deposits in Brazil have host rock lithology that resembles that of Aricheng.     

Continuity and facies heterogeneities of shallow carbonate ramp cycles (Sinemurian,Lower Jurassic,North‐east Spain)

The lateral continuity and facies heterogeneities of metre‐scale cycles in a greenhouse Lower Jurassic (Sinemurian) carbonate ramp from the northern Iberian Basin (Spain) was evaluated from extensive field analysis carried out on a well‐exposed 12 km long outcrop. Eleven high‐frequency continuous cycles and their bounding surfaces are traceable laterally through the entire outcrop. However, three of these cycles are found to split laterally into discontinuous cycles of more limited distribution (up to 3 to 5 km of lateral extent). The continuous and discontinuous cycles have a similar field expression in one‐dimensional logs. As a consequence, the number of cycles that can be differentiated is variable along the logged sections (i.e. from 11 to 16). Cycles have variable facies heterogeneities and sedimentary trends depending on the environment of formation: shallowing‐upward and symmetrical cycles occur in protected lagoon–tidal flat areas and in the open‐marine, high‐energy domain. These cycles show significant facies heterogeneities, which were controlled mainly by lateral migration of a mosaic of facies over an irregular topography. Deepening‐upward and aggradational cycles are generated in low‐energy, sub wave‐base, open‐marine areas. Facies are laterally homogeneous, reflecting low potential for carbonate accumulation and inability to fill the created accommodation space in this low‐relief and relatively deep area. Cycle boundaries are generated by stages of rapid accommodation gain, involving the flooding of the carbonate ramp; they are more likely to originate from regional tectonic pulses (related to the extensional tectonics operating in the northern Iberian Basin) rather than greenhouse low‐amplitude eustacy. Discontinuous cycles tend to occur in thickened areas and are interpreted as originating from the infill of wedge‐shaped accommodation space resulting from differential subsidence (i.e. local tectonic pulses). In conclusion, where thickness variations occur in extensional settings lateral continuity of cycles should not be expected. In less well‐exposed, or in one‐dimensional sections and in wells, it would not be possible to distinguish continuous from discontinuous cycles, or to understand such two‐dimensional heterogeneities. Identification of unique cycle‐forming mechanisms or attempting cyclostratigraphic long‐distance correlation of cycles is unrealistic without a detailed analysis of the architecture of cycles in laterally continuous outcrops.     

Climate Change Scenarios for the Hudson Bay Region: An Intermodel Comparison

General circulation models (GCMs) are unanimous in projecting warmer temperatures in an enhanced CO₂ atmosphere, with amplification of this warming in higher latitudes. The Hudson Bay region, which is located in the Arctic and subarctic regions of Canada, should therefore be strongly influenced by global warming. In this study, we compare the response of Hudson Bay to a transient warming scenario provided by six-coupled atmosphere-ocean models. Our analysis focuses on surface temperature, precipitation, sea-ice coverage, and permafrost distribution. The results show that warming is expected to peak in winter over the ocean, because of a northward retreat of the sea-ice cover. Also, a secondary warming peak is observed in summer over land in the Canadian and Australian-coupled GCMs, which is associated with both a reduction in soil moisture conditions and changes in permafrost distribution. In addition, a relationship is identified between the retreat of the sea-ice cover and an enhancement of precipitation over both land and oceanic surfaces. The response of the sea-ice cover and permafrost layer to global warming varies considerably among models and thus large differences are observed in the projected regional increase in temperature and precipitation. In view of the important feedbacks that a retreat of the sea-ice cover and the distribution of permafrost are likely to play in the doubled and tripled CO₂ climates of Hudson Bay, a good representation of these two parameters is necessary to provide realistic climate change scenarios. The use of higher resolution regional climate model is recommended to develop scenarios of climate change for the Hudson Bay region.     

20th-CENTURY CHANGES OF TEMPERATURE IN THE MOUNTAIN REGIONS OF CENTRAL EUROPE

Daily maximum and minimum temperatures from 29 low-lying and mountain stations of 7 countries in Central Europe were analyzed. The analysis of the annual variation of diurnal temperature range helps to distinguish unique climatic characteristics of high and low altitude stations. A comparison of the time series of extreme daily temperatures as well as mean temperature shows a good agreement between the low-lying stations and the mountain stations. Many of the pronounced warm and cold periods are present in all time series and are therefore representative for the whole region. A linear trend analysis of the station data for the period 1901–1990 (19 stations) and 1951–1990 (all 29 stations) shows spatial patterns of similar changes in maximum and minimum daily temperatures and diurnal temperature range. Mountain stations show only small changes of the diurnal temperature range over the 1901–1990 period, whereas the low-lying stations in the western part of the Alps show a significant decrease of diurnal temperature range, caused by strong increase of the minimum temperature. For the shorter period 1951–1990, the diurnal temperature range decreases at the western low-lying stations, mainly in spring, whereas it remains roughly constant at the mountain stations. The decrease of diurnal temperature range is stronger in the western part than in the eastern part of the Alps.     

Analyzing the genesis, intensity, and tracks of western Mediterranean cyclones

Midlatitude cyclones are analyzed on a selected region covering most of southern Europe and the western part of the Mediterranean Sea (35–50°N, 10°W–25°E). On the basis of mean sea level pressure fields of the ECMWF (European Centre for Medium-range Weather Forecast) Reanalysis Dataset (ERA-40), detailed evaluation of Mediterranean cyclones is accomplished for the period between 1957 and 2002 on a 1° horizontal resolution grid. Cyclone centers are identified and their paths are tracked with a 6-h time step (using 00 UTC, 06 UTC, 12 UTC, and 18 UTC). Decadal, annual, and seasonal statistical analysis of cyclone tracks includes the study of the genesis, frequency, and activity of the Mediterranean cyclones as well as the variability of cyclone tracks. The results suggest that the cyclone frequency in the western Mediterranean region increased in summer and autumn, and decreased in winter and spring. A special belt-shaped area is identified, which plays a special role in cyclogenesis, and also, the cyclone tracks often remain within this belt. An overall decreasing trend is detected in winter and spring in the entire Mediterranean belt, while cyclone frequency increased in autumn. The largest positive and negative trend coefficients are identified in summer.     

Black crusts on travertine: factors controlling development and stability

The travertine buildings of Budapest show extensive black crust formation, which is related to high concentration of atmospheric pollution and a continental climate. Laminar black crusts, framboidal black crusts and leached white surfaces are compared. Physical properties (Schmidt hammer rebound, Duroscope rebound), mineralogical composition and elemental composition are measured. Framboidal black crusts contain more than 50% of acicular gypsum. The crust surface displays idiomorphic rosette-like gypsum crystals with particulates, calcite and gypsum crystal aggregates. The sulphur isotopic composition of the black crusts pinpoints the involvement of rain and dust in crust formation. Thick framboidal black crust has the lowest strength while thin laminar black crust and white dissolved surfaces show minor decrease in surface strength compared to unaltered travertine. The crusts adhere to the travertine surface and rarely show mechanical decay forms that are typical features of porous limestone ashlars in Budapest.     

Redox and nonredox reactions of magnetite and hematite in rocks

Redox and nonredox reactions causing pseudomorphic replacement of hematite by magnetite and magnetite by hematite are compared.Pseudomorphic replacements resulting from redox reactions are known as martitization [replacement of magnetite by hematite due to oxidation; reaction (1)] and mushketovitization [replacement of hematite by magnetite due to reduction; reaction (2)]. These two replacements cause characteristic ore textures and volume changes (reaction (1): increase of 1.66%; reaction (2): decrease of 1.64%). These small volume changes are the reason that martitization and mushketovitization are widespread in many rocks under condition, however, that oxidizing or reducing fluids (solutions) are present.The same initial and end products may also be involved in nonredox reactions. Reaction (3) is the replacement of hematite by magnetite due to simple addition of Fe²⁺ atoms under basic conditions. This reaction causes an increase of the volume of 47.6%. Reaction (4), causing a volume decrease of 32.2%, is the replacement of magnetite by hematite due to leaching of Fe²⁺ atoms under acidic conditions. From these volume changes it is concluded that reaction (4) may occur in many rock types, whereas reaction (3) is restricted to unlithified sediments only. However, ore textures caused by nonredox reactions are unknown and therefore their occurrence in rocks is hypothetical.     

Landslide kinematics inferred from in situ measurements: the Cliets rock-slide (Savoie,French Alps)

This paper presents an analysis of two large rock toppling/sliding events which occurred in January 2014 and February 2019 at the Cliets unstable slope (Savoie, French Alps). To understand the mechanism involved and its control by external forcings, a multi-technique analysis approach is used combining geological observations, meteorological data analysis, topographic measurements and simple physical modeling. The pre-failure stage of the events is more particularly analyzed. No direct relationships are found between triggering factors and surface motion though a kinematics analysis highlights the transition toppling-sliding. It showed that, at first order, this transition occurred 4 years before the first failure of 2014, while it happened 2 months before the second failure of 2019. From this date, the environment is considered like a block sliding on an inclined plane. By applying a frictional model (Helmstetter et al. in Journal of Geophysical Research: Solid Earth 109(B2), 2004), we illustrated that the two events belong to an unstable velocity-weakening sliding regime. The time to failure (Voight in Science 243(4888):200–203, 1989) is forecasted with the model, and the results are consistent with the observations. They confirm that the gravitational factor is predominant over the triggering factors for the two events.

     

Paleoenvironmental dynamics in central-eastern Brazil during the last 23 000 years: tropical peatland record in the Cerrado biome

The Cerrado biome is the second largest in Brazil, but the evolution of the Cerrado during the late Quaternary is not yet fully known. This study identifies paleoenvironmental changes during the last 23 000 years, based on a tropical mountain peatland record, in the Serra do Espinhaço Meridional in central-eastern Brazil. A multi-proxy approach was used that involved palynological analysis, stable isotopes (δ¹³C, δ¹⁵N), geochemistry, radiocarbon dating and multivariate statistics derived from a peatland core from Rio Preto (Minas Gerais state). The study reveals a very humid and cold climate during the late Pleistocene, with an increase in temperature and decrease in humidity at the Pleistocene–Holocene transition. During this period there was strong instability in the landscape (episodes of erosion). At the beginning of the Holocene there was a reduction in humidity with greater landscape stability. The current sub-humid climatic conditions seem to have been established in the mid-/late Holocene, with periods of landscape instability. Our findings agree with other Cerrado records that contradict previously established hypotheses, such as the Amazonian Refuge and the Pleistocene Arc.