康定黄金坪金矿床原生晕分带特征及找矿意义

黄金坪金矿床以自然金(银金矿)—多金属硫化物—碲金银系列矿物—碲化物以及石英、黄铁矿等矿物组合为特征;典型元素组合为Au(Ag)-Te-Cu-Pb-Zn-Ba-As。本文应用数理统计方法研究Ⅰ号矿体的原生晕及其分带特征,结果表明侧向分带(矿体向围岩)趋势As-Zn-Pb-Au-Ag-Te-Cu-Ba,垂向分带(由上至下)为Pb-Ag-Au-Zn-As-Te-Cu-Ba。该分带模式对于深部矿化预测与其它矿化带的远景评价具有现实意义。     

A new method for the stability analysis of geosynthetic-reinforced slopes

This paper is concerned with the stability analysis of reinforced slopes. A new approach based on the limit equilibrium principle is proposed to evaluate the stability of the reinforced slopes. The effect of reinforcement is modeled as an equivalent restoring force acting the bottom of the slice and added into the general limit equilibrium (GLE) method. The equations of force and moment equilibrium of the slice are derived and corresponding iterative solution methods are provided. The new method can satisfy both the force and the moment equilibrium and be applicable to the critical failure surface of arbitrary form. Furthermore, the results predicted by the proposed method are compared with the calculation examples of other researchers and the centrifuge model test results to validate its correctness and effectiveness.     

Molecular weight controllable degradation of <Emphasis Type="Italic">Laminaria japonica</Emphasis> polysaccharides and its antioxidant properties

In this study, molecular weight controllable degradation of algal Laminaria japonica polysaccharides（LPS） was investigated by ultrasound combined with hydrogen peroxide. Three main factors, i.e., ultrasonic power（A）, ultrasonic time（B）, and H₂O₂ concentration（C） were chosen for optimizing parameters by employing three-factors, three-levels BBD. The influence of degradation on structure change and antioxidant activities was also investigated. A second-order polynomial equation including molecular weight（Y） of Laminaria japonica polysaccharides and each variable parameter, i.e., ultrasonic power（A）, ultrasonic time（B）, and H₂O₂ concentration（C）, was established: Y=20718.67-4273.13A-4000.38B-1438.75C+2333.25AB+1511.00AC+873.00BC+2838.29A² + 2490.79B²+873.04C². The equation regression coefficient value（R² = 0.969） indicated that this equation was valid. The value of the adjusted determination coefficient（adjusted R² = 0.914） also confirmed that the model was highly significant. The results of selected experimental degradation conditions matched with the predicted value. FT-IR spectra revealed that the structures of LPS before and after degradation were not significantly changed. Antioxidant activities of LPS revealed that low Mws possessed stronger inhibitory than the original polysaccharides. The scavenging effects on superoxide radicals was the highest when IC50 of crude LPS was 4.92 mg mL^-1 and IC50 of Mw 18.576 KDa was 1.02 mg mL^-1, which was fourfold higher than initial polysaccharide.     

青海南祁连巴龙贡噶尔组变火山岩LA-ICP-MS锆石U-Pb年龄及其地质意义

广泛分布于南祁连的巴龙贡噶尔组一直缺少精确的化石和同位素测年依据,其地质时代备受关注。1∶5万区域地质调查在青海省天峻县织合玛乡南部的该套地层中新发现了英安质火山熔岩。采用LA-ICP-MS锆石U-Pb定年方法,获得1件英安岩样品的锆石U-Pb年龄为457.6±2.4Ma,表明该套火山岩形成于晚奥陶世。这是首次获得的有关巴龙贡噶尔组的高精度测年数据,为该组的解体及其时代归属提供了可靠的同位素年代学依据。这一新发现和成果对于研究南祁连的早古生代地层层序及构造演化具有重要意义。