A dated cave sediment record of Pleistocene transgressions on Berry Head,Southwest England

Berry Head, a limestone headland in Torbay, southwest England, exhibits a series of subaerial marine erosion platforms and raised beaches spanning an altitude range of 97 m. Solution caves on the headland show preferred horizontal development at elevations that are correlated with the marine erosion platforms, and developed in a marine/freshwater mixing zone whose position was controlled by high sea-level still-stands. Corbridge Cave in Berry Head Quarry lies below the raised beaches in Torbay, and contains evidence of three marine transgressions in the form of fine-grained marine ponding deposits with a marine microfauna. Uranium-series dating of intercalated speleothems indicates that a transgression during oxygen isotope stage 5e reached an elevation of 5.8 m OD, while an earlier transgression (probably during stage 7) reached at least 7.2 m OD. These findings are used to constrain possible interpretations of the aminostratigraphy of raised beaches in Southwest Britain, and a correlation of the Unnamed Stage of Bowen, Sykes, Reeves, Miller, Andrews, Brew and Hare with oxygen isotope stage 5e is proposed.     

The western lapidary tradition in early geological literature: medicinal and magical minerals

Nowadays, when someone refers to lapidary they usually mean the process of polishing, engraving or working stones. The term is much broader than that, however, encompassing an entire genre of literature which formed the basis of much geological observation even before the word 'geology' was ever coined.     

An assessment of geologic sequestration potential in the panhandle of Florida USA

One alternative to reduce global greenhouse gas emissions is to store the emissions in underground geologic sequestration repositories. The efficacy of this approach has been favorably evaluated by numerous authors over the last 15 years. This paper discusses an assessment of the overall feasibility of storing emissions in three different repositories in the Florida panhandle located in the Southeastern United States. The feasibility assessment evaluates both saline aquifers and oil reservoirs located in the panhandle region. The overall feasibility is driven by the available geologic sequestration capacity, the transportation cost to deliver emissions to a respective repository, and other engineering and regulatory issues. The geologic sequestration capacity is generally controlled by the so-called storage efficiency, a variable dependent on the site-specific geology, reservoir conditions, and the injected fluid characteristics. For this paper, storage efficiency for saline repositories was assessed in more detail using numerical modeling. Based on the work completed, the 3 repositories studied have at least 4.55 gigatonnes of capacity to sequester CO₂.     

Can Plant Competition and Diversity Reduce the Growth and Survival of Exotic <Emphasis Type="Italic">Phragmites australis</Emphasis> Invading a Tidal Marsh?

The rapid proliferation of Phragmites australis in North America has challenged resource managers to curb its expansion and reduce the loss of functional tidal marsh. We investigated whether native plant competition could reduce the ability of Phragmites to invade a tidal marsh, and if plant diversity (species richness, evenness, and composition) altered the competitive outcome. Immature Phragmites shoots and four native halophytes were transplanted to small but dense field plots (~1,200 shoots m⁻²) comprising three community structure types (Phragmites alone, Phragmites + 1 native species, and Phragmites + 4 native species). Interspecific competition significantly reduced Phragmites aboveground biomass, shoot length production, density, and survival by approximately 60%. Additionally, plots planted with greater native diversity contained Phragmites with the lowest growth and survival, potentially indicating diversity-enhanced resource competition. Competition consistently reduced the growth of Phragmites even under favorable conditions: lack of strong tidal flooding stresses as well as elevated nutrient pools.     

Anatomically preserved plants in siderite concretions in the shale split of the Foord Seam: mineralogy, geochemistry, genesis (Upper Carboniferous, Canada)

A shale split in the well-studied Foord Seam (Upper Carboniferous), Stellarton Basin, Nova Scotia, provides a rare opportunity to study little known siderite concretions with anatomically preserved plants from a limnic basin. Siderite concretions occur throughout the split, commonly as sheet-like, inter-connected lepidodendrid logs, or less frequently as spherical masses; they are typically vuggy. A sample of 14 stratigraphically oriented concretions in the split shows that primary siderite varies from 45% to 80% (wt.%) due to selective replacement by 5% to 40% ferroan dolomite or ankerite in plant tissues. These two minerals show large Mg/Fe and Mg/Ca variability and are Fezoned. Clay content ranges from trace to 20%, and quartz from 5% to 10%. Partial cell-wall destruction by erosion and changeable oxic/anoxic conditions, prior to siderite permineralization, resulted in preservation mainly of the more resistant plant tissues. On average, carbon from siderite is isotopically heavier (+4.8±1.9 0/00) than that from ‘dolomite' (−7.2±1.1 0/00). The distribution of and the positive correlation between δ¹³C and δ¹⁸O probably reflects the two fractionation processes associated with methanogenesis and ‘dolomitization', respectively, in the genetic history of the siderite concretions in the split. Siderite concretions formed diagenetically early from bicarbonate under reducing conditions in a slightly alkaline freshwater environment that precluded calcite deposition.     

Late Holocene lake level dynamics inferred from magnetic susceptibility and stable oxygen isotope data: Lake Elsinore, southern California (USA)

Southern California faces an imminent freshwater shortage. To better assess the future impact of this water crisis, it is essential that we develop continental archives of past hydrological variability. Using four sediment cores from Lake Elsinore in Southern California, we reconstruct late Holocene (3800 calendar years B.P.) hydrological change using a twentieth-century calibrated, proxy methodology. We compared magnetic susceptibility from Lake Elsinore deep basin sediments, lake level from Lake Elsinore, and regional winter precipitation data over the twentieth century to calibrate the late Holocene lake sediment record. The comparison revealed a strong positive, first-order relationship between the three variables. As a working hypothesis, we suggest that periods of greater precipitation produce higher lake levels. Greater precipitation also increases the supply of detritus (i.e., magnetic-rich minerals) from the lake's surrounding drainage basin into the lake environment. As a result, magnetic susceptibility values increase during periods of high lake level. We apply this modern calibration to late Holocene sediments from the lake's littoral zone. As an independent verification of this hypothesis, we analyzed ¹⁸O_(calcite), interpreted as a proxy for variations in the precipitation:evaporation ratio, which reflect first order hydrological variability. The results of this verification support our hypothesis that magnetic susceptibility records regional hydrological change as related to precipitation and lake level. Using both proxy data, we analyzed the past 3800 calendar years of hydrological variability. Our analyses indicate a long period of dry, less variable climate between 3800 and 2000 calendar years B.P. followed by a wet, more variable climate to the present. These results suggest that droughts of greater magnitude and duration than those observed in the modern record have occurred in the recent geological past. This conclusion presents insight to the potential impact of future droughts on the over-populated, water-poor region of Southern California.     

An approach for shake table performance evaluation during repair and retrofit actions

Large‐scale, servo‐hydraulic shake tables are a central fixture of many earthquake engineering and structural dynamics laboratories. Wear and component failure from frequent use may lead to control problems resulting in reduced motion fidelity, necessitating repairs and replacement of major components. This paper presents a methodology to evaluate shake table performance pre‐ and post‐repair, including the definition of important performance metrics. The strategy suggested is presented in the context of the rebuilding of a 4.9 × 3.1 m, 350‐kN‐capacity uniaxial shake table. In this case, the rebuild consisted of characterization of wear to table components, replacement of worn bearing surfaces, and replacement of hydraulic accumulators. To assess the effectiveness of the repair actions, sinusoidal and triangular waves, white noise, and earthquake histories were run on the table before and after the rebuild. The repair actions were successful in reducing the position and velocity dependence of friction, improving the ability of control algorithms to accurately reproduce earthquake motions. The maximum and average response spectral misfits in the period range of 0.1–2 seconds were reduced from approximately 50% to 15%, and from 5% to less than 2.5%, respectively.     

Surface complexation of U(VI) on goethite (α-FeOOH)

Sorption of U(VI) to goethite is a fundamental control on the mobility of uranium in soil and groundwater. Here, we investigated the sorption of U on goethite using EXAFS spectroscopy, batch sorption experiments and DFT calculations of the energetics and structures of possible surface complexes. Based on EXAFS spectra, it has previously been proposed that U(VI), as the uranyl cation , sorbs to Fe oxide hydroxide phases by forming a bidentate edge-sharing (E2) surface complex, >Fe(OH)₂UO₂(H₂O)_n. Here, we argue that this complex alone cannot account for the sorption capacity of goethite (α-FeOOH). Moreover, we show that all of the EXAFS signal attributed to the E2 complex can be accounted for by multiple scattering. We propose that the dominant surface complex in CO₂-free systems is a bidentate corner-sharing (C2) complex, (>FeOH)₂UO₂(H₂O)₃ which can form on the dominant {101} surface. However, in the presence of CO₂, we find an enhancement of UO₂ sorption at low pH and attribute this to a (>FeO)CO₂UO₂ ternary complex. With increasing pH, U(VI) desorbs by the formation of aqueous carbonate and hydroxyl complexes. However, this desorption is preceded by the formation of a second ternary surface complex (>FeOH)₂UO₂CO₃. The three proposed surface complexes, (>FeOH)₂UO₂(H₂O)₃, >FeOCO₂UO₂, and (>FeOH)₂UO₂CO₃ are consistent with EXAFS spectra. Using these complexes, we developed a surface complexation model for U on goethite with a 1-pK model for surface protonation, an extended Stern model for surface electrostatics and inclusion of all known UO₂-OH-CO₃ aqueous complexes in the current thermodynamic database. The model gives an excellent fit to our sorption experiments done in both ambient and reduced CO₂ environments at surface loadings of 0.02-2.0 wt% U.     

Assessing spatial associations between perceptions of landscape value and climate change risk for use in climate change planning

This study examines spatially referenced perceived landscape values and climate change risks collected through public participation geographic information systems for potential use in climate change planning. Using survey data from the Southern Fleurieu Peninsula, South Australia, we present a method for identifying perceived landscape values and climate change risks to describe and quantify their spatial associations. Two spatial data models??vector and raster??and two analytical methods??Jaccard coefficients and spatial cross-correlations were used to describe the spatial associations. Results indicate that perceptions of climate change risk are driven, in part, by the values people assign or hold for places on the landscape. Biodiversity and intrinsic landscape values have strong spatial association with biodiversity loss risk while recreation values have strong spatial association with riparian flooding, sea-level rise and wave action risks. Other landscape values show weak to no spatial association with perceived climate change risks. The methodology described in this research provides a mechanism for government agencies to develop place-based adaptation strategies based on these associations.