Saturn's Titan: Surface change, ammonia, and implications for atmospheric and tectonic activity

Titan is known to have a young surface. Here we present evidence from the Cassini Visual and Infrared Mapping Spectrometer that it is currently geologically active. We report that changes in the near-infrared reflectance of a 73,000 km² area on Titan (latitude 26° S, longitude 78° W) occurred between July 2004 and March of 2006. The reflectance of the area increased by a factor of two between July 2004 and March-April 2005; it then returned to the July 2004 level by November 2005. By late December 2005 the reflectance had surged upward again, establishing a new maximum. Thereafter, it trended downward for the next three months. Detailed spectrophotometric analyses suggest these changes happen at or very near the surface. The spectral differences between the region and its surroundings rule out changes in the distribution of the ices of reasonably expected materials such as H₂O, CO₂, and CH₄ as possible causes. Remarkably, the change is spectrally consistent with the deposition and removal of NH₃ frost over a water ice substrate. NH₃ has been proposed as a constituent of Titan's interior and has never been reported on the surface. The detection of NH₃ frost on the surface might possibly be explained by episodic effusive events occur which bring juvenile ammonia from the interior to the surface. If so, its decomposition would feed nitrogen to the atmosphere now and in the future. The lateral extent of the region exceeds that of active areas on the Earth (Hawaii) or Io (Loki).     

Hydrogeological modeling as a tool supporting the interpretation of pollen proxies for palaeoclimate reconstitution: The Senegalese “niayes” case-study

The Niayes of Senegal are sahelian interdunal fens, that hosted an azonal subguinean vegetation during the Holocene thanks to the availability of fresh groundwater despite contrasted climatic conditions. Exploratory scenario-based modeling of the zonal hydrogeology has been conducted for different periods with the Cast3M code. The results show that the delay in the onset of humid vegetation ca. 10 ky cal. BP could be ecosystemic and denote a start of the African Humid Period (AHP) ca. 11.5 ky cal. BP. Alternatively, the AHP could have started earlier while its beneficial effects would have been canceled by low sea levels. Vegetation degradation around 7.5 ky cal. BP is shown to have resulted from a climate minoration, that possibly alleviated until 4 ky cal. BP. The rising watertable allowed the degraded forest to persist during that period however. The forest expansion that followed ca. 3.5 ky cal. BP had then clearly a climatic origin. The interpretation of pollens for climate research requires a careful filtering-out of local groundwater availability.     

A combined modelling and geochemical study of the fate of terrigenous inputs from mixed natural and mining sources in a coral reef lagoon (New Caledonia)

Open-cast mining for Ni, Cr and Co was conducted in the south-west part of New Caledonia during the 20th century. Abandoned mining and prospecting sites were severely affected by erosion, resulting in an increase in the load of terrigenous particles transported to the coral reef lagoon. This article assesses the impact of a typical small catchment area (La Coulée River, 85 km2 watershed) on two bays (Boulari and Sainte Marie) located near Noumea, New Caledonia's main city. This multi-disciplinary study combines geochemical, sedimentological, and hydrodynamic approaches. Ni and Cr concentrations contained in the geochemical matrix phase of the pelitic fraction were determined. The study of the geochemical signatures together with sedimentological data and 3D numerical simulations of the transport of non-settling particles throughout the lagoon demonstrated that terrigenous inputs from the Coulée River were mainly transported and deposited along the shoreline, reaching areas as distant as Sainte Marie Bay. Although quantitatively low (about 3% of the pelite mass of the bay sediments), the terrigenous inputs in Sainte Marie Bay originating from the Coulée River could be traced. The metal content in suspended matter was over 7000 mg kg(-1) for Ni and 4200 mg kg(-1) for Cr.     

Holocene salt‐marsh sedimentary infilling and relative sea‐level changes in West Brittany (France) using foraminifera‐based transfer functions

In order to reconstruct former sea‐levels and to better characterize the history of Holocene salt‐marsh sedimentary infillings in West Brittany (western France), local foraminifera‐based transfer functions were developed using weighted‐average‐partial‐least‐squares (WAPLS) regression, based on a modern data set of 26 and 51 surface samples obtained from salt‐marshes in the bay of Tresseny and the bay of Brest, respectively. Fifty cores were retrieved from Tresseny, Porzguen, Troaon and Arun salt‐marshes, which were litho‐ and biostratigraphically analysed in order to reconstruct palaeoenvironmental changes. A total of 26 AMS ¹⁴C age determinations were performed within the sediment successions. The Holocene evolution of salt‐marsh environments can be subdivided into four stages: (i) a development of brackish to freshwater marshes (from c. 6400 to 4500 cal. a BP); (ii) salt‐marsh formation behind gravel barriers in the bay of Brest (from 4500 to 2900 cal. a BP); (iii) salt‐marsh erosion and rapid changes of infilling dynamics due to the destruction of coastal barriers by storm events (c. 2900?2700 cal. a BP); (iv) renewed salt‐marsh deposition and small environmental changes (from 2700 cal. a BP to present). From the application of transfer functions to fossil assemblages, 14 new sea‐level index points were obtained, indicating a mean relative sea‐level rise of around 0.90±0.12 mm a^?1 since 6300 cal. a BP.     

Sensitivity and inversion of marine electromagnetic data in a vertically anisotropic stratified earth

The controlled‐source electromagnetic (CSEM) and magnetotelluric method (MT) are two techniques that can be jointly used to explore the resistivity structure of the earth. Such methods have, in recent years, been applied in marine environments to the exploration and appraisal of hydrocarbons. In many situations the electric properties of the earth are anisotropic, with differences between resistivity in the vertical direction typically much higher than those in the horizontal direction. In cases such as this, the two modes of the time‐harmonic electromagnetic field are altered in different ways, implying that the sensitivity to the earth resistivity may vary significantly from one particular resistivity component (scalar, horizontal or vertical) to another, depending on the measurement configuration (range, azimuth, frequency or water depth). In this paper, we examine the sensitivity of the electromagnetic field to a vertically anisotropic earth for a typical set of configurations, compare inversion results of synthetic data characterizing a vertically anisotropic earth obtained using the isotropic and anisotropic assumptions and show that correctly accounting for anisotropy can prevent artefacts in inversion results.     

Vulnerability and resilience of remote rural communities to shocks and global changes: Empirical analysis from Solomon Islands

Successful management of socio-ecological systems not only requires the development and field-testing of robust and measurable indices of vulnerability and resilience but also improved understanding of the contextual factors that influence societal capacity to adapt to change. We present the results of an analysis conducted in three coastal communities in Solomon Islands. An integrated assessment map was used to systematically scan the communities’ multiple dimensions of vulnerability and to identify factors affecting households’ perception about their capacity to cope with shocks (resilience). A multivariate probit approach was used to explore relationships amongst factors. Social processes such as community cohesion, good leadership, and individual support to collective action were critical factors influencing the perception that people had about their community's ability to build resilience and cope with change. The analysis also suggests a growing concern for a combination of local (internal) and more global (external) contingencies and shocks, such as the erosion of social values and fear of climate change.     

First records, pathways and distributions of four new Ponto-Caspian amphipods in France

In Europe, the number of establishment of non-native species, especially from Ponto-Caspian area, has dramatically increased over the past decades and induced important changes in macroinvertebrate assemblages, mainly in large rivers. However, although many Ponto-Caspian species were established in adjacent countries, only two Ponto-Caspian amphipods were formally observed in French hydrosystems since 1996. To update our knowledge on the present distribution of the Ponto-Caspian species in France, we collected amphipods from 203 sites in the Rhine, Meuse and Seine River basins in 2008 and again in 2009. Thirteen amphipod species were found in the study area. Among them, four were first formally recorded in France (Dikerogammarus haemobaphes, Dikerogammarus bispinosus, Echinogammarus ischnus, and Echinogammarus trichiatus). Our study revealed three different corridors used by these species to arrive in France. We also observed a different pattern of colonization for each species, which might indicate some between-species differences in their preferences for environmental conditions. The snapshot of the early distributions of these recently established species may hence be used to study the invasion pattern in France in order to manage their potential impact in and outside France.     

Dissolution kinetics of synthetic Na-smectite. An integrated experimental approach

The effect of pH and Gibbs energy on the dissolution rate of a synthetic Na-montmorillonite was investigated by means of flow-through experiments at 25 and 80 °C at pH of 7 and 9. The dissolution reaction took place stoichiometrically at 80 °C, whereas at 25 °C preferential release of Mg over Si and Al was observed. The TEM-EDX analyses (transmission electronic microscopy with quantitative chemical analysis) of the dissolved synthetic phase at 25 °C showed the presence of newly formed Si-rich phases, which accounts for the Si deficit. At low temperature, depletion of Si concentration was attributed to incongruent clay dissolution with the formation of detached Si tetrahedral sheets (i.e., alteration product) whereas the Al behaviour remains uncertain (e.g., possible incorporation into Al-rich phases). Hence, steady-state rates were based on the release of Mg. Ex situ AFM measurements were used to investigate the variations in reactive surface area. Accordingly, steady-state rates were normalized to the initial edge surface area (11.2 m² g⁻¹) and used to propose the dissolution rate law for the dissolution reactions as a function of ΔG_r at 25 °C and pH∼9:

     

Type I eclogites from Roberts Victor kimberlites: Products of extensive mantle metasomatism

Type I and Type II eclogite xenoliths from the Roberts Victor kimberlite (South Africa) show marked differences in terms of microstructures, mineralogy, major- and trace-element compositions and oxygen-isotope compositions. The unequilibrated microstructures of Type I eclogites, their typical accessory assemblages (phologopite, diamond, sulphides, fluid inclusions) and the ubiquitous presence of “melt pockets” in garnets provide strong evidence of metasomatism. Type II eclogites systematically lack such features and are microstructurally more equilibrated. Type I eclogites are more magnesium-rich than most Type II (mean Mg# = 0.56 vs. 0.46), while Type II eclogites are generally more Ca-rich (mean CaO = 9 vs. 12 wt%) and Fe-rich (mean FeO = 10 vs. 12 wt%). Type I eclogites are systematically enriched in LREE, Sr, Ba, alkali elements, HFSE, Th and U compared to the more depleted Type II eclogites. Calculated trace-element patterns of fluids in equilibrium with Type I eclogites are closely similar to those of volatile-rich small-volume mantle melts in the carbonatite-kimberlite spectrum commonly inferred to be responsible for mantle metasomatism. Although oxygen isotopes are often used to argue for a subduction origin of mantle eclogites, correlations between δ¹⁸O of garnet and typical metasomatic tracers suggest that the metasomatic process also has shifted the oxygen-isotope compositions of the Type I eclogites toward heavier values. Roberts Victor Type I eclogites thus carry the imprint of a metasomatic process that strongly modified their major-element, trace-element and isotopic compositions, while the more pristine Type II eclogites escaped this modification. Therefore, attempts to constrain the origin of Roberts Victor eclogites should not be based on the much more abundant Type I eclogites, which retain little geochemical memory of their protoliths. The most suitable materials for such investigations may be the less metasomatised, but more rare, Type II eclogites.     

粘土矿物在气候环境变化研究中的应用进展

在古环境和古气候的重建中,粘土矿物和碳-氧同位素、孢粉、树轮、冰芯等代用指标一样具有同等重要的地位。在没有地质构造运动影响时,气候是影响粘土矿物形成的主要因素,沉积物中的粘土矿物可用来分析古气候和古环境。粘土矿物及其组合可以独立或作为主要指标反映气候和环境变化,并已应用于高分辨率的晚第四纪地层的气候环境研究中。粘土矿物在很短的时间内也会发生明显地变化,不仅可以反映千年-百年尺度的气候环境变化,而且也可以反映几十年尺度的古气候环境变化过程。粘土矿物与其它指标对同一气候环境响应的相位差有待深入研究。不同的半定量分析方法测量出的同一剖面中粘土矿物的含量变化趋势和特征具有一致性。