Water quality and risk assessment of dug wells: a case study for a poor community in the city of São Paulo, Brazil

Sparsely populated areas, or peripheral communities commonly lack access to a public water supply and sewerage systems. The inhabitants of these areas must make use of excavated wells to provide their water needs, and cesspits for domestic wastewater disposal. These on-site sanitation systems can release pathogens and nutrients into shallow groundwater. These poor communities urgently require cheap and efficient techniques for the detection of sanitary conditions, in order to prevent contamination of the water resources supplied by dug wells. The sanitary risk assessment methodology, applied in an irregular settlement south of the city of São Paulo, was based on a questionnaire with yes/no questions (risk factors), which allowed the identification of problems related to the well construction and operation, and the presence of potential contamination sources in its vicinity. These risk factors were compared against nitrate and bacterial analysis using the clustering statistical method, to verify the relationship between contamination and certain aspects surveyed in the questionnaire. Questions that were more related to contaminated wells were those concerning the presence of cover and its integrity; gaps between mouth and cover; the surrounding pavement and presence of ground irregularities; infiltration in the well casing; water-suspended materials; and proximity to contamination sources. Contamination models based on variograms allowed to observe that bacterial contamination presented a strong localized component, which was associated frequently with the way residents handled the wells, whereas nitrate contamination was related more to a regional (spatial) component; that is, the distance between wells and cesspits.     

Statistical distribution of rainy events characteristics and instantaneous hyetographs generation (Merguellil watershed in central Tunisia)

In semi-arid regions, variability of rainfall inputs is high at different time and space scales. Thus, intense and highly variable hydro-meteorological events, which generate both potential resource and hazards, are of major interest. The Merguellil watershed is characterized by a large majority of rainfall in the form of storms, particularly violent in spring and autumn. Storms of summer are short and violent and can be the origin of important floods. Due to the strong rainfall variability, precipitation and hydrological regime are very irregular. This is what led us to think of a detailed study of rainy events. It was founded that two statistical distributions of parameters characterizing events are dominated (log normal, exponential).Thus, our objective consists in studying, in its globality, the collected pluviographic data in order to make a synthesis and analysis which should make it possible the generation of fictitious events to better control the rainfall risk and to study the response of the watershed faces to several types of rainfall. As result, we obtained hyetographs of the height studied rain gauges. These hyetographs show several types of events that are well in conformity with the observed reality. This generation is an advantageous tool in terms of both its robustness and its performance. Its relevance is based on the analysis of the fine time structure of recorded rainfall events. It can be made over several years, and would permit us to avoid being constrained by sample size. Generating rainfall events provides extensive time-related rainfall data that are consistent at all time steps, and can be seen as solution, even partially, of data lack in hydrological study.     

Multixenobiotic resistance, acetyl-choline esterase activity and total oxyradical scavenging capacity of the Arctic spider crab, Hyasaraneus, following exposure to bisphenol A, tetra bromo diphenyl ether and diallyl phthalate

The Arctic has become a sink for persistent organic pollutants (POPs) originating from lower latitudes, and relatively high levels have been found in different biota. Recent studies have identified detrimental effects on wildlife including endocrine disruption, impairment of enzyme activity, and reduced immune function. The Arctic spider crab, Hyas araneus, shown interesting potential for its use as sentinel organism in polar ecosystems. This study investigated the effect of 2,2',4,4'-tetra bromo diphenyl ether (BPDE), bisphenol A (BPA), and diallyl phthalte (DPA) on H. araneus in a three weeks exposure study. Expression of multixenibiotic resistance (MXR) proteins has been studied using the C219 monoclonal antibody which allows identifying an immunoreactive protein of 40 kDa in the digestive gland while no such protein could be observed in the gills. Expression of this protein was increased by exposure to DPA (+75%; p<0.05, n=10). All compounds significantly affected muscle acetylcholine esterase (AChE) activity (p<0.05, n=10) with 50 microg/L DPA having the strongest effect by lowering the value to 37% of control. The total oxyradical scavenging capacity measured in the digestive gland toward peroxyl, hydroxyl and peroxynitrite was also significantly reduced indicating a decreased resistance to oxidative stress generated by DPA (p<0.05, n=5). These results thus suggest the potential detrimental effects of DPA even at concentration as low as 50 microg/L on H. araneus.     

A 3-dimensional calculation of the atmospheric neutrino fluxes

An extensive 3-dimensional Monte Carlo calculation of the atmospheric neutrino flux is in progress with the FLUKA Monte Carlo code. The results are compared to those obtained under the 1-dimensional approximation, where secondary particles and decay products are assumed to be collinear to the primary cosmic ray, as usually done in most of the already existing flux calculations. It is shown that the collinear approximation gives rise to a wrong angular distribution of neutrinos, essentially in the Sub-GeV region. However, the angular smearing introduced by the experimental inability of detecting recoils in neutrino interactions with nuclei is large enough to wash out, in practice, most of the differences between 3-dimensional and 1-dimensional flux calculations. Therefore, the use of the collinear approximation should not have introduced a significant bias in the determination of the flavor oscillation parameters in current experiments.     

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

Flow dynamics at the origin of thin clayey sand lacustrine turbidites: Examples from Lake Hazar,Turkey

Turbidity currents and their deposits can be investigated using several methods, i.e. direct monitoring, physical and numerical modelling, sediment cores and outcrops. The present study focused on thin clayey sand turbidites found in Lake Hazar (Turkey) occurring in eleven clusters of closely spaced thin beds. Depositional processes and sources for three of those eleven clusters are studied at three coring sites. Bathymetrical data and seismic reflection profiles are used to understand the specific geomorphology of each site. X‐ray, thin sections and CT scan imagery combined with grain‐size, geochemical and mineralogical measurements on the cores allow characterization of the turbidites. Turbidites included in each cluster were produced by remobilization of surficial slope sediment, a process identified in very few studies worldwide. Three types of turbidites are distinguished and compared with deposits obtained in flume studies published in the literature. Type 1 is made of an ungraded clayey silt layer issued from a cohesive flow. Type 2 is composed of a partially graded clayey sand layer overlain by a mud cap, attributed to a transitional flow. Type 3 corresponds to a graded clayey sand layer overlain by a mud cap issued from a turbulence‐dominated flow. While the published experimental studies show that turbulence is damped by cohesion for low clay content, type 3 deposits of this study show evidence for a turbulence‐dominated mechanism despite their high clay content. This divergence may in part relate to input variables, such as water chemistry and clay mineralogy, that are not routinely considered in experimental studies. Furthermore, the large sedimentological variety observed in the turbidites from one coring site to another is related to the evolution of a sediment flow within a field‐scale basin made of a complex physiography that cannot be tackled by flume experiments.     

External controls on the distribution,fabrics and mineralization of modern microbial mats in a coastal hypersaline lagoon,Cayo Coco (Cuba)

Active, carbonate‐mineralizing microbial mats flourish in a tropical, highly evaporative, marine‐fed lagoonal network to the south of Cayo Coco Island (Cuba). Hypersaline conditions support the development of a complex sedimentary microbial ecosystem with diverse morphologies, a variable intensity of mineralization and a potential for preservation. In this study, the role of intrinsic (i.e. microbial) and extrinsic (i.e. physicochemical) controls on microbial mat development, mineralization and preservation was investigated. The network consists of lagoons, forming in the interdune depressions of a Pleistocene aeolian substratum; they developed due to a progressive increase in sea‐level since the Holocene. The hydrological budget in the Cayo Coco lagoonal network changes from west to east, increasing the salinity. This change progressively excludes grazers and increases the saturation index of carbonate minerals, favouring the development and mineralization of microbial mats in the easternmost lagoons. Detailed mapping of the easternmost lagoon shows four zones with different flooding regimes. The microbial activity in the mats was recorded using light–dark shifts in conjunction with microelectrode O₂ and HS^? profiles. High rates of O₂ production and consumption, in addition to substantial amounts of exopolymeric substances, are indicative of a potentially strong intrinsic control on mineralization. Seasonal, climate‐driven water fluctuations are key for mat development, mineralization, morphology and distribution. Microbial mats show no mineralization in the permanently submersed zone, and moderate mineralization in zones with alternating immersion and exposure. It is suggested that mineralization is also driven by water‐level fluctuations and evaporation. Mineralized mats are laminated and consist of alternating trapping and binding of grains and microbially induced magnesium calcite and dolomite precipitation. The macrofabrics of the mats evolve from early colonizing Flat mats to complex Cerebroid or Terrace structures. The macrofabrics are influenced by the hydrodynamic regime: wind‐driven waves inducing relief terraces in windward areas and flat morphologies on the leeward side of the lagoon. Other external drivers include: (i) storm events that either promote (for example, by bioclasts covering) or prevent (for example, by causing erosion) microbial mat preservation; and (ii) subsurface degassing, through mangrove roots and desiccation cracks covered by Flat mats (i.e. forming Hemispheroids and Cerebroidal structures). These findings provide in‐depth insights into understanding fossil microbialite morphologies that formed in lagoonal settings.     

Interannual predictability of Arctic sea ice in a global climate model: regional contrasts and temporal evolution

The predictability of the Arctic sea ice is investigated at the interannual time scale using decadal experiments performed within the framework of the fifth phase of the Coupled Model Intercomparison Project with the CNRM-CM5.1 coupled atmosphere–ocean global climate model. The predictability of summer Arctic sea ice extent is found to be weak and not to exceed 2 years. In contrast, robust prognostic potential predictability (PPP) up to several years is found for winter sea ice extent and volume. This predictability is regionally contrasted. The marginal seas in the Atlantic sector and the central Arctic show the highest potential predictability, while the marginal seas in the Pacific sector are barely predictable. The PPP is shown to decrease drastically in the more recent period. Regarding sea ice extent, this decrease is explained by a strong reduction of its natural variability in the Greenland–Iceland–Norwegian Seas due to the quasi-disappearance of the marginal ice zone in the center of the Greenland Sea. In contrast, the decrease of predictability of sea ice volume arises from the combined effect of a reduction of its natural variability and an increase in its chaotic nature. The latter is attributed to a thinning of sea ice cover over the whole Arctic, making it more sensitive to atmospheric fluctuations. In contrast to the PPP assessment, the prediction skill as measured by the anomaly correlation coefficient is found to be mostly due to external forcing. Yet, in agreement with the PPP assessment, a weak added value of the initialization is found in the Atlantic sector. Nevertheless, the trend-independent component of this skill is not statistically significant beyond the forecast range of 3 months. These contrasted findings regarding potential predictability and prediction skill arising from the initialization suggest that substantial improvements can be made in order to enhance the prediction skill.