Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia

Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L⁻¹), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L⁻¹ near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources.     

Mid-Holocene emergence of southern Tunisian coasts

We present new sea-level data from the coasts of southern Tunisia, between the Gulf of Gabès and the Libyan border. The work tests, previously, published evidence on Holocene shorelines, and confirmed that a distinct emergence has occurred in this area during this time. The emergence peak lies at least 186 ± 11 cm above present and is inferred from: (1) AMS radiocarbon dates of subtidal vermetids and boring shells collected in growth position, and (2) careful assessment of tidal heights. Maximum emergence took place between about 6000 and 5000 ¹⁴C years BP; it cannot be ascribed to tectonics and is probably related to post-glacial hydro-isostatic effects. It challenges the inference of a 3-m global sea-level rise since 6000 years BP due to residual Antarctic melting.     

Analysis, synthesis and modelling of high-resolution observations of salt-marsh eco-geomorphological patterns in the Venice lagoon

The present paper describes observations, analyses and models of salt-marsh channel network and vegetation patterns with the aim of contributing to the development of predictive models of ecological and morphological co-evolution. Existing and new observations are described, with particular emphasis on remote sensing and ancillary field surveys, which are shown to allow reliable, accurate and repeatable quantitative characterizations of landform and vegetation properties over the spatial scales of interest. The observed channel network morphological characters are then used as the basis and validation of models describing the emergence of channel network and vegetation spatial patterns. In particular, with reference to observations performed in the Venice Lagoon, the note describes: (i) new, 2-cm resolution, characterizations of channel network geometry obtained from “proximal sensing” photographic observations; (ii) the reliable quantitative maps of salt-marsh vegetation which may be retrieved from hyperspectral remote sensing data and field ancillary observations; (iii) a synthesis of recent and new analyses of the statistical properties of vegetation and landform spatial organization, that may be inferred from the maps so derived; (iv) recent and new conceptual and quantitative ecological and geomorphic models developed and validated by remote-sensing and field observations. A coherent observational and theoretical eco-morphodynamic framework is then proposed.     

Investigating on the 1920 Garfagnana earthquake (Mw=6.5): Evidences of site effects in Villa Collemandina (Tuscany,Italy)

This paper presents a comprehensive ground response study for the municipality of Villa Collemandina in Northern Tuscany (Italy). This site was selected following a macroseismic analysis of the 1920 Garfagnana earthquake (M_w=6.5), which, at Villa Collemandina, produced damage and losses that were larger than at any other site near the earthquake epicentre, thus indicating the presence of possible site effects. Hence, both experimental and numerical methods are applied in order to investigate the ground response at different locations within the Villa Collemandina municipality. Results obtained from the spectral analysis of earthquake recordings using the reference site method and those from a 2-dimensional dynamic simulation reveal the presence of site effects due to the buried geomorphology (basin-like effects), allowing us to explain the severe damage and losses produced by the 1920 Garfagnana earthquake. As a further result, horizontal to vertical spectral ratio techniques and 1D soil modelling are proved to be inadequate for an effective characterization of the ground response at sites that, like Villa Collemandina, present a complex local geology.     

Multisite surface reaction versus transport control during the hydrolysis of a complex oxide

Dissolution experiments of a tholeiite basalt glass carried out at different pH and T (up to 300°C) using a rotatingdisc apparatus show that, depending on pH and T, dissolution can be controlled by one of the following steps: (1) surface reaction; (2) transport of reactants in solution; and (3) mixed reaction. The activation energies of these different processes were found to be 60, 9 and 15–50 kJ mol⁻¹, respectively. Taking account of these results, it appears likely that surface reactions are not rate limiting for the hydrolysis of most crystalline silicate minerals in hydrothermal and metamorphic processes, and that caution should be exercised when predicting rate of reactions at high temperatures solely on the basis of activation energies measured at low temperatures.

Comparison of experimental and theoretical potentiometric titrations of the basalt glass and its constituent oxides indicates that the adsorption of H⁺ and OH⁻ ions at the basalt surface is metal cation specific and that the net adsorption can be predicted from the sole knowledge of the acidity constants of the network-forming constituent oxides. We found that in the acidic pH region dissolution is promoted by the adsorption of H⁺ on al and Fe surface sites while in the basic region, dissolution is promoted by the adsorption of OH⁻ on Si sites. The combination of the two distinct types of surface sites, Al and Fe on the one hand, and Si on the other hand, results in a dissolution rate minimum at a pH-value between the pH_zpc of the two groups of oxide components. Linear regressions with a slope n=3.8 are observed both in acid and alkaline solutions in logarithmic plots of the rate of dissolution vs. the surface charge. The value of n, which represents the number of protonation or hydroxylation steps prior to metal detachment, has been found equal to the mean valence of the network-forming metals.

Combining concepts of surface coordination chemistry with transition state theory afforded characterisation of the activated complexes involved in basalt dissolution processes. From the values obtained for the thermodynamic properties of activation for basalt dissolution it is assumed that the activated complexes formed during the H₂O-promoted dissolution of the basalt glass are more tightly bonded than those formed during H⁺- or OH⁻-promoted dissolution.     

Agn Jet Modeling: Setting the Stage

I review the most recent results obtained in numerical simulations of jets from accretion disks, with specific reference to the phases of acceleration, propagation and termination. The approximations adopted, both in the physics and the numerical methods, are pointed out and possible developments are suggested.     

Towards a 4D topographic view of the Norwegian sea margin

The present-day topography/bathymetry of the Norwegian mainland and passive margin is a product of complex interactions between large-scale tectonomagmatic and climatic processes that can be traced back in time to the Late Silurian Caledonian Orogeny. The isostatic balance of the crust and lithosphere was clearly influenced by orogenic thickening during the Caledonian Orogeny, but was soon affected by post-orogenic collapse including overprinting of the mountain root, and was subsequently affected by a number of discrete extensional events eventually leading to continental break-up in Early Eocene time. In the mid-Jurassic the land areas experienced deep erosion in the warm and humid climate, forming a regional paleic surface. Rift episodes in the Late Jurassic and Early Cretaceous, with differential uplift along major fault zones, led to more pronounced topographic contrasts during the Cretaceous, and thick sequences of clastic sediments accumulated in the subsiding basins on the shelf. Following renewed extension in the Late Cretaceous, a new paleic surface developed in the Paleocene. Following break-up the margin has largely subsided thermally, but several Cenozoic shortening events have generated positive contraction structures. On the western side of the on-shore drainage divide, deeper erosion took place along pre-existing weakness zones, creating the template of the present day valleys and fjords. In the Neogene the mainland and large portions of the Barents Sea were uplifted. It appears that this uplift permitted ice caps to nucleate and accumulate during the Late Pliocene northern hemisphere climatic deterioration. The Late Pliocene to Pleistocene glacial erosion caused huge sediment aprons to be shed on to the Norwegian Sea and Barents Sea margins. Upon removal of the ice load the landmass adjusted isostatically, and this still continues today.     

An improved lunar moment of inertia determination: a proposed strategy

The current error of 0.0025 on the lunar homogeneity parameterI/MR ² is dominated by the uncertainties in theC ₂₀ andC ₂₂ gravity harmonics. This error level is equivalent to a 4.20 gm cm^–3 density uncertainty for a lunar interior model having a core 300 km in radius. Covariance analyses are performed using Doppler data from the relay satellite of the proposed Lunar Polar Orbiter mission to determine an optimum reduction strategy which obtains an order of magnitude improvement in the gravity estimates. Error studies show the long-arc reduction method obtains results which are an order of magnitude more accurate than the short-arc technique. The nominal 4000 km circular orbit of the relay satellite is very sensitive to the unmodeled effects of gravity harmonics of degree 5 through 9. Results from this orbital geometry indicate that it may not be possible to achieve the desired order of magnitude accuracy improvement. A modified orbit having the identical orbital conditions as the nominal one, but with a larger semi-major axis of 7000 km is studied. Results show the desired order of magnitude improvement can be achieved when a complete fourth degree and order model and some fifth and sixth degree terms are estimated while considering the unmodeled effects of the remaining harmonics through degree and order eight. Studies also show a 50% additional improvement inC ₂₂ can be achieved if differential differenced Doppler is also processed with the direct Doppler. The improved uncertainty inI/MR ² reduces the core density error from 4.20 gm cm^–3 to 0.1 gm cm^–3 for the case of a lunar density model having a 300 km core radius.Contribution #2885 of the Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A.     

Magnetic fields around highly magnetized objects

The structure of the magnetic fields of a collapsed star is studied by tracing the flux lines in the quasi-vacuum approximation. The existence of a magnetic neutral line in a system of reference corotating with the star is studied, where magnetic energy dissipations into particle kinetic energy via plasma instabilities could occur.     

Spectroscopic anatomy of a meteor trail cross section with the European Southern Observatory Very Large Telescope

Abstract— A meteor spectrum was recorded serendipitously at the European Southern Obrervatory (ESO) Very Large Telescope (VLT) during a long exposure in long‐slit spectroscopic mode with FORS1. The ?8 magnitude fireball crossed the narrow 1Î × 7î slit during the observation of a high z supernova in normal service mode operation on May 12, 2002. The spectrum covered the range of 637–1050 nm, where the meteor's air plasma emissions from N₂, N, and O dominate. Carbon atom emission was not detected in the relatively unexplored wavelength range above 900 nm, but the observed upper limit was only 3 sigma less than expected from the dissociation of atmospheric CO₂. The meteor trail was resolved along the slit, and the emission had a Gaussian distribution with a dimension of FWHM = 7.0 (±0.4) * sin(α) * H (km)/90 m, where α is the unknown angle between the orientation of the meteor path and slit and H the assumed altitude of the meteor in km. To our knowledge, this is the first observation of a spatially resolved spectrum across a meteor trail. Unlike model predictions, the plasma excitation temperature varied only from about 4,300 to 4,365 K across the trail, based on the ratio of atomic and molecular nitrogen emissions. Unfortunately, we conclude that this was because the meteor at 100 km altitude was out of focus.