Carboniferous–Permian volcanic evolution in Central Europe—U/Pb ages of volcanic rocks in Saxony (Germany) and northern Bohemia (Czech Republic)

Nine SHRIMP U/Pb ages on zircon and two Pb/Pb single zircon ages have been determined from Late Paleozoic volcanic rocks from Saxony and northern Bohemia. Samples came from the Teplice-Altenberg Volcanic Complex, the Meissen Volcanic Complex, the Chemnitz Basin, the Döhlen Basin, the Brandov-Olbernhau Basin, and the North Saxon Volcanic Complex. The Teplice-Altenberg Volcanic Complex is subdivided into an early Namurian phase (Mikulov Ignimbrite, 326.8 ± 4.3 Ma), thus older than assumed by previous studies, and a late caldera-forming phase (Teplice Ignimbrite, 308.8 ± 4.9 Ma). The age of the latter, however, is not well constrained due to a large population of inherited zircon and possible hydrothermal overprint. The Leutewitz Ignimbrite, product of an early explosive volcanic episode of the Meissen Volcanic Complex yielded an age of 302.9 ± 2.5 Ma (Stephanian A). Volcanic rocks intercalated in the Brandov-Olbernhau Basin (BOB, 302 ± 2.8 Ma), Chemnitz Basin (CB, 296.6 ± 3.0 Ma), Döhlen Basin (DB, 296 ± 3.0 Ma), and the North Saxon Volcanic Complex (NSVC, c. 300–290 Ma) yielded well-constrained Stephanian to Sakmarian ages. The largest Late Paleozoic ignimbrite-forming eruption in Central Europe, the Rochlitz Ignimbrite, has a well-defined middle Asselian age of 294.4 ± 1.8 Ma. Ages of palingenic zircon revealed that the Namurian-Westphalian magmatism assimilated larger amounts of crystalline basement that formed during previous Paleozoic geodynamic phases. The Precambrian inherited ages support the chronostratigraphic structure assumed for the Saxo-Thuringian Zone of the Variscan Orogen. The present results help to improve the chronostratigraphic allocation of the Late Paleozoic volcanic zones in Central Europe. At the same time, the radiometric ages have implications for the interbasinal correlation and for the geodynamic evolution of the Variscan Orogeny.     

CityGML goes mobile: application of large 3D CityGML models on smartphones

CityGML, a semantic information model for digital/virtual city models has become quite popular in various scenarios. While the data format is still actively under development, it is already supported by different software solutions, especially GIS-based desktop applications. Mobile systems on the other hand are still neglected, even though the georeferenced objects of CityGML have many application fields, for example, in the currently popular area of location-based Augmented Reality. In this paper we present an independent multi-platform CityGML viewer, its architecture and specific implementation techniques that we use to realize and optimize the process of visualizing CityGML data for use in Augmented Reality. The main focus lies in improving the implementation on mobile devices, such as smartphones, and assessing its usability and performance in comparison to web-based approaches. Due to the constrained hardware resources of smartphones, it is a particular challenge to handle complex 3D objects and large virtual worlds as provided by CityGML, not only in terms of memory and storage space, but also with respect to mobile processing units and display sizes.     

Neoproterozoic SHRIMP U–Pb zircon ages of silica-rich Dokhan Volcanics in the North Eastern Desert,Egypt

Chronology of Neoproterozoic volcanosedimentary successions remains controversial for many regions of the Arabian–Nubian Shield, including the Dokhan Volcanics of NE Egypt. New U–Pb zircon SHRIMP ages have been obtained for 10 silica-rich ignimbrites and two subvolcanic dacitic bodies, mapped as Dokhan Volcanics, from the North Eastern Desert of Egypt. Crystallization ages range between 592 ± 5 and 630 ± 6 Ma (Early Ediacaran). Apparently, the late consolidation of the Arabian–Nubian Shield was accompanied by the evolution of isolated volcanic centres and basin systems which developed during a period of approx. 40 Ma, independently in space and time and probably under changing tectonic regimes. The obtained age data together with other previously published reliable ages for Dokhan Volcanics suggest two main pulses of volcanic activity: 630–623 Ma and 618–592 Ma. Five samples contain inherited zircons, with ages of 669, 715–746, 847 and 1530 Ma, supporting models that North Eastern Desert crust is mainly juvenile Neoproterozoic crust.     

Palaeoecological constraints on late Glacial and Holocene ice retreat in the Southern Andes (53°S)

Late Glacial to Holocene ice retreat was investigated along a 120 km long fjord system, reaching from Gran Campo Nevado (GCN) to Seno Skyring in the southernmost Andes (53°S). The aim was to improve the knowledge on regional and global control on glacier recession with special emphasis on latitudinal shifting of the westerlies. The timing of ice retreat was derived from peat and sediment cores, using mineralogical and chemical characteristics, and pollen as proxies. Stratigraphy was based on ¹⁴C-AMS ages and tephrochronology. The ice retreat of the Seno Skyring Glacier lobe is marked by an ice rafted debris layer which was formed around 18,300 to 17,500 cal. yr B.P. Subsequently, fast glacier retreat occurred until around 15,000 to 14,000 cal. yr B.P. during which around 84% of Skyring Glacier were lost. This fast recession was probably also triggered by an increase of the Equilibrium Line Altitude (ELA) from 200 to 300 m. Subsequently, the ice surface was lowered below the ELA in an area that previously made up more than 50% of the accumulation area. Much slower retreat and glacier fluctuations of limited extent in the fjord channel system northeast of GCN occurred between around 14,000 to 11,000 cal. yr B.P. during both the Antarctic Cold Reversal and the Younger Dryas. This slow down of retreat indicates a decline in the general warming trend and/or increased precipitation, due to a southward migration of the westerlies. After around 11,000 cal. yr B.P. pollen distribution shows evolved Magellanic Rainforest and similar climate as at present, which lasted throughout most of the Holocene. Only Late Neoglacial moraine systems were formed in the period 1220–1460 AD, and subsequently in the 1620s AD, and between 1870 and 1910 AD. The results indicate that the Gran Campo Nevado ice cap has reacted more sensitive and partly distinct to climate change, compared to the Patagonian Ice Field.     

U–Pb dating, Hf-isotope characteristics and trace-REE-patterns of zircons from Medet porphyry copper deposit, Bulgaria: implications for timing, duration and sources of ore-bearing magmatism

Precise U–Pb geochronology, Hf isotope compositions and trace element distributions in zircons are combined in the present study to define the timing and sources of the magmatism forming the Medet porphyry copper deposit, Bulgaria. ID-TIMS U–Pb-zircon dating demonstrates that ore-bearing magmatism extended for less than 1.12 Ma. As inferred from the field relationships, it started with the intrusion of a quartz-monzodiorite at 90.59?±?0.29 Ma followed by granodiorite porphyries at 90.47?±?0.30 and 90.27?±?0.60 Ma and by crosscutting aplite dykes at 90.12?±?0.36 Ma. These units were overprinted by potassic alteration and host economic copper-(Mo–Au) mineralization. The main magmatic–hydrothermal activity ceased after that, and a later quartz-granodiorite porphyry dyke, dated at 89.26?±?0.32 Ma, only contains an uneconomic quartz–pyrite mineralization. Assimilation of Lower Paleozoic rocks with a mantle to mantle–crust signature is characteristic of the fertile magma in the Medet deposit, as defined by positive ?-Hf values of the inherited zircons. The positive Ce-anomalies and the higher Eu/Eu* ratios of the zircons in the mineralized Cretaceous rocks of Medet deposit argue for crystallization from a generally more oxidized magma compared to the later quartz-granodiorite porphyry dyke. A change in paleostress conditions occurred during the intrusion of the Medet pluton and its dykes. The initial stage reveals E–W extension associated with N–S compression, whereas the younger granodiorite dyke was emplaced during subsequent N–S extension. The large-scale switch of the extensional stress regime during the mineralization was favourable for ore deposition by channelling the fluids and increasing the effective permeability.     

Control on seafloor spreading geometries by stress- and strain-induced lithospheric weakening

Seafloor spreading typically occurs along ridge segments oriented at right angles to plate motion and offset by orthogonal transform faults. Few regions exhibit different patterns, such as the East Pacific Rise (EPR), which additionally displays overlapping spreading centres (OSCs) and microplates. We introduce a dynamical model using two independent, scalar types of damage in an elastic plate that generates most observed spreading geometries as natural failure modes, suggesting that the dynamics of the underlying mantle have only a minor influence on accretionary plate margins. The elastic modulus that is affected by the damage determines the type of localized deformation. Damage reducing the bulk modulus tends to result in tensile fractures, while a reduction in shear modulus leads to shear fractures. The damage source determines the fracture orientation. Material weakening in tension results in fractures perpendicular to the most tensile principal stress, while shear weakening results in two conjugate fractures at 45° relative to the applied stress. Strain or energy-dependent damage results in propagating, localized fractures. Stress-dependent damage tends to evolve into diffuse regions that may eventually focus into narrow zones. Starting from small perturbations with reduced elastic moduli as nucleation points, all ridge geometries start with ridge propagation caused by tensile energy reducing both elastic moduli by a model of damage caused by tensile energy reducing both moduli. Orthogonal transform faults develop in regions between offset segments if there is an additional reduction in shear modulus due to shear stress. The orthogonality of the transform faults does not derive from the local stress orientation but from the dynamics of damage focusing which causes the fault to converge towards an optimal geometry that concentrates nearly all deformation into damaged zones. OSCs form when the shear damage leading to transform faults is suppressed, while microplate formation requires additional reduction of the shear modulus by tensile energy. Oblique spreading at 45°, recently discovered along ultraslow spreading ridges, occurs when both moduli are weakened by shear energy. A parameter regime exists in which ridge-transform patterns develop at low applied tension, while microplates form at higher stresses. These results indicate that at least three different micromechanical processes operate with different evolution rates. OSCs and oblique spreading require different material properties.     

Processes affecting dissolved iron across the Subtropical North Atlantic: a model study

Ocean Dynamics - Trace metal measurements in recent years have revealed a complex distribution of dissolved iron (dFe) in the ocean that models still struggle to reproduce. The GEOTRACES section...     

First GOCE gravity field models derived by three different approaches

Three gravity field models, parameterized in terms of spherical harmonic coefficients, have been computed from 71 days of GOCE (Gravity field and steady-state Ocean Circulation Explorer) orbit and gradiometer data by applying independent gravity field processing methods. These gravity models are one major output of the European Space Agency (ESA) project GOCE High-level Processing Facility (HPF). The processing philosophies and architectures of these three complementary methods are presented and discussed, emphasizing the specific features of the three approaches. The resulting GOCE gravity field models, representing the first models containing the novel measurement type of gravity gradiometry ever computed, are analysed and assessed in detail. Together with the coefficient estimates, full variance-covariance matrices provide error information about the coefficient solutions. A comparison with state-of-the-art GRACE and combined gravity field models reveals the additional contribution of GOCE based on only 71 days of data. Compared with combined gravity field models, large deviations appear in regions where the terrestrial gravity data are known to be of low accuracy. The GOCE performance, assessed against the GRACE-only model ITG-Grace2010s, becomes superior at degree 150, and beyond. GOCE provides significant additional information of the global Earth gravity field, with an accuracy of the 2-month GOCE gravity field models of 10?cm in terms of geoid heights, and 3?mGal in terms of gravity anomalies, globally at a resolution of 100?km (degree/order 200).     

Inspecting the Reliability of Geochemical Facies Identified for the Waterworks' Capture Zone in Germany

Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake-groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike-and-Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from <0.2 to >0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.