History of lunar meteorites Queen Alexandra Range 93069, Asuka 881757, and Yamato 793169 based on noble gas isotopic abundances,radionuclide concentrations,and chemical composition

Abstract— We investigated the characteristics and history of lunar meteorites Queen Alexandra Range 93069, Yamato 793169 and Asuka 881757 based on the abundances of all stable noble gas isotopes, the concentrations of the radionuclides ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁸¹Kr, and the abundances of Mg, Al, K, Ca, Fe, Cl, Sr, Y, Zr, Ba, and La. Based on the solar wind and cosmic-ray irradiations, QUE 93069 is the most mature lunar meteorite studied up to now. The ⁴⁰Ar/³⁶Ar ratio of the trapped component is 1.87 ± 0.16. This ratio corresponds to a time when the material was exposed to solar and lunar atmospheric volatiles ～400 Ma ago. On the other hand, Yamato 793169 and Asuka 881757 contain very little or no solar noble gases, which indicates that these materials resided in the top layer of the lunar regolith only briefly or not at all. For all lunar meteorites, we observe a positive correlation of the concentrations of cosmic-ray produced with trapped solar noble gases. The duration of lunar regolith residence for the lunar meteorites was calculated based on cosmic-ray produced ²¹Ne, ³⁸Ar, ⁷⁸Kr, ⁸³Kr, and ¹²⁶Xe and appropriate production rates that were derived based on the target element abundances and the shielding indicator ¹³¹Xe/¹²⁶Xe. For QUE 93069, Yamato 793169, and Asuka 881757, we obtained 1000 ± 400 Ma, 50 ± 10 Ma, and <1 Ma, respectively. Both Asuka 881757 and Yamato 793169 show losses of radiogenic ⁴He from U and Th decay and Yamato 793169 also ⁴⁰Ar loss from K-decay. For Asuka 881757, we calculate a K-Ar gas retention age of 3100 ± 600 Ma and a ²⁴⁴Pu-¹³⁶Xe fission age of 4240 ± 170 Ma. This age is one of the oldest formation ages ever observed for a lunar basalt. The exposure history of QUE 93069 after ejection from the Moon was derived from the radionuclide concentrations: ejection 0.16 ± 0.03 Ma ago, duration of Moon-Earth transit 0.15 ± 0.02 Ma and fall on Earth <0.015 Ma ago. This ejection event is distinguished temporally from those which produced the other lunar meteorites. We conclude that six to eight events are necessary to eject all the known lunar meteorites.     

Long-term spatio-temporal social vulnerability variation considering health-related climate change parameters particularly affecting elderly

For assessing the social dimension of vulnerability, population exposure mapping is usually considered the essential starting point. Integration of social structure then further differentiates situation-specific vulnerability patterns on a local scale. Census data available in heterogeneous spatial reference units are still considered the standard information input for assessing potentially affected people, for example, in case of an emergency. There is a strong demand for population data in homogeneous spatial units that are independent from administrative areas. Raster representations meet this demand but are not yet available for all European countries. In this paper, we present an approach of spatial disaggregation of population data for a European transect referring to current population statistics and anticipated future prospects. Recently published data providing the degree of soil sealing are applied as basic proxy for population density in the spatial disaggregation model. In order to assess future patterns of climate change-related vulnerability, results of a European regional climate model are considered for projecting the situation in the 2030s. “Heat wave frequency” is accounted for as climate variable featuring conditions regarded as especially strenuous for elderly or physically weak persons. Integrated analysis of the population and climate prospects enables identification of hot spots in the European transect examined, that is, regions of particularly demanding projected climatic patterns as well as high population density and case-specific vulnerable structure (elderly people). Integrated and consistent spatial analyses on European scale are essential for decision support in the context of climate change impact mitigation as well as for risk communication and future safety and security considerations.     

Carboniferous–Permian volcanic evolution in Central Europe—U/Pb ages of volcanic rocks in Saxony (Germany) and northern Bohemia (Czech Republic)

Nine SHRIMP U/Pb ages on zircon and two Pb/Pb single zircon ages have been determined from Late Paleozoic volcanic rocks from Saxony and northern Bohemia. Samples came from the Teplice-Altenberg Volcanic Complex, the Meissen Volcanic Complex, the Chemnitz Basin, the Döhlen Basin, the Brandov-Olbernhau Basin, and the North Saxon Volcanic Complex. The Teplice-Altenberg Volcanic Complex is subdivided into an early Namurian phase (Mikulov Ignimbrite, 326.8 ± 4.3 Ma), thus older than assumed by previous studies, and a late caldera-forming phase (Teplice Ignimbrite, 308.8 ± 4.9 Ma). The age of the latter, however, is not well constrained due to a large population of inherited zircon and possible hydrothermal overprint. The Leutewitz Ignimbrite, product of an early explosive volcanic episode of the Meissen Volcanic Complex yielded an age of 302.9 ± 2.5 Ma (Stephanian A). Volcanic rocks intercalated in the Brandov-Olbernhau Basin (BOB, 302 ± 2.8 Ma), Chemnitz Basin (CB, 296.6 ± 3.0 Ma), Döhlen Basin (DB, 296 ± 3.0 Ma), and the North Saxon Volcanic Complex (NSVC, c. 300–290 Ma) yielded well-constrained Stephanian to Sakmarian ages. The largest Late Paleozoic ignimbrite-forming eruption in Central Europe, the Rochlitz Ignimbrite, has a well-defined middle Asselian age of 294.4 ± 1.8 Ma. Ages of palingenic zircon revealed that the Namurian-Westphalian magmatism assimilated larger amounts of crystalline basement that formed during previous Paleozoic geodynamic phases. The Precambrian inherited ages support the chronostratigraphic structure assumed for the Saxo-Thuringian Zone of the Variscan Orogen. The present results help to improve the chronostratigraphic allocation of the Late Paleozoic volcanic zones in Central Europe. At the same time, the radiometric ages have implications for the interbasinal correlation and for the geodynamic evolution of the Variscan Orogeny.     

Rock magnetic study of basic intrusions and massive sulphides in the Hercynian central Jebilets Massif (Occidental-Meseta), Morocco

This paper describes a multidisciplinary study approach (petrography and rock magnetism) conducted on samples collected from the study area to characterise the magnetic mineralogy and to determine if the magnetisation of both lithologies were induced or retain a remnant component. Petrophysical, mineralogical and geochemical analyses confirm bimodal aspects, particularly in basic rocks; the two magnetic modes depend essentially on the mineralogical and geochemical characteristics of the samples. The ultramafic rocks comprise a highly altered primary mineralogy with chromite and magnetite as magnetic phases. The second type is of mafic composition with a less altered primary mineralogy and essentially magnetite and/or (hemo-ilmenite) as a carrier of magnetic mineralisation. Sulphides are characterised by high concentrations of Cu, Zn and Pb. The mineralogy is composed mainly of pyrrhotite (85% to 90%), sphalerite, galena, chalcopyrite, arsenopyrite and, occasionally, stannite. Monocline pyrrhotite seems to be the magnetic carrier of magnetisation in both Draa Sfar and Koudiat Aïcha. However, we suspect a different amount of hexagonal pyrrhotite as the cause of different magnetic behaviour. Paleomagnetic and thermomagnetic analyses reveal different. The calculated characteristic direction of natural remnant magnetisation for sulphides was used to model the magnetic anomaly of Draa Sfar. The proposed model match the geological features concluded from geological mapping and boreholes. Results from this work can be very useful for any modelling processes of magnetic anomalies suspected due to a sulphide mineralisation in an area with poor outcrops and no presence of boreholes information or of any geological or geochemical data.     

Characteristics of intra-, inter-annual and decadal sea-level variability and the role of meteorological forcing: the long record of Cuxhaven

This paper addresses the role of meteorological forcing on mean sea level (MSL) variability at the tide gauge of Cuxhaven over a period from 1871 to 2008. It is found that seasonal sea level differs significantly from annual means in both variability and trends. The causes for the observed differences are investigated by comparing to changes in wind stress, sea level pressure and precipitation. Stepwise regression is used to estimate the contribution of the different forcing factors to sea level variability. The model validation and sensitivity analyses showed that a robust and timely independent estimation of regression coefficients becomes possible if at least 60 to 80 years of data are available. Depending on the season, the models are able to explain between 54 % (spring, April to June) and 90 % (winter, January to March) of the observed variability. Most parts of the observed variability are attributed to changes in zonal wind stress, whereby the contribution of sea level pressure, precipitation and meridional wind stress is rather small but still significant. On decadal timescales, the explanatory power of local meteorological forcing is considerable weaker, suggesting that the remaining variability is attributed to remote forcing over the North Atlantic. Although meteorological forcing contributes to linear trends in some sub-periods of seasonal time series, the annual long-term trend is less affected. However, the uncertainties of trend estimation can be considerably reduced, when removing the meteorological influences. A standard error smaller than 0.5 mm/year requires 55 years of data when using observed MSL at Cuxhaven tide gauge. In contrast, a similar standard error in the meteorologically corrected residuals is reached after 32 years.     

Inspecting the Reliability of Geochemical Facies Identified for the Waterworks' Capture Zone in Germany

Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake-groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike-and-Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from <0.2 to >0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.     

Discrimination of Nuclear Explosions against Civilian Sources Based on Atmospheric Xenon Isotopic Activity Ratios

A global monitoring system for atmospheric xenon radioactivity is being established as part of the International Monitoring System that will verify compliance with the Comprehensive Nuclear-Test-Ban Treaty (CTBT) once the treaty has entered into force. This paper studies isotopic activity ratios to support the interpretation of observed atmospheric concentrations of ¹³⁵Xe, ^133mXe, ¹³³Xe and ^131mXe. The goal is to distinguish nuclear explosion sources from civilian releases. Simulations of nuclear explosions and reactors, empirical data for both test and reactor releases as well as observations by measurement stations of the International Noble Gas Experiment (INGE) are used to provide a proof of concept for the isotopic ratio based method for source discrimination.     

U–Pb dating of speleothems from Spannagel Cave,Austrian Alps: A high resolution comparison with U–series ages

U–Pb dating is increasingly used to date speleothems that are too old for precise U–Th disequilibrium dating; however there is little data that can independently validate its application to such material. This study presents U–Pb ages for speleothems from the Spannagel Cave in the Austrian Alps including a detailed comparison with U–Th ages from an unusually U–rich sample that yields precise ages by both methods. Sample SPA4 is a flowstone with three growth phases separated by distinct hiatuses. For the youngest growth phase the U–Pb and U–Th ages are 267 ± 1 ka and 267 ± 5 ka respectively; the middle growth phase is 291 ± 1 versus 295 ± 11 ka while for the oldest growth phase a single sub-sample, assuming the same initial Pb composition as for the younger phases, yields an age of 340 ± 2 ka compared to 353 ± 9 ka by U–Th. Correlation of these ages with the marine isotope stages confirms that these speleothems grew during glacial stages as suggested by previous work on the same sample. Sample SPA 15 has U–Th isotopic compositions indistinguishable from secular equilibrium; the U–Pb data on the main growth phase of this sample give an age of 551 ± 10 ka, whereas a single analysis from the oldest phase suggests it may be on the order of 40 ka older. This detailed comparison of U–Pb and U–Th ages provides important support for the potential validity of the U–Pb method in older samples beyond the range of U–Th.     

Insights into rock avalanche emplacement processes from detailed morpho‐lithological studies of the Tschirgant deposit (Tyrol,Austria)

Large, rapid rockslope failures generate deposits with complex morphologies due to a number of causal and influencing factors. To investigate these, we conducted a detailed case study at the carbonate Tschirgant deposit (Tyrol, Austria). It preserved evidence of simultaneous rock sliding (very large, coherent hummocks) and rock avalanche spreading (smaller, more scattered hummocks and ridges). Motion indicators, such as longitudinal ridges furthermore pinpoint the transition between linear sliding and radial spreading. The lithological distribution in the Tschirgant deposit shows that it retained source stratigraphy despite being split into two accumulation lobes by a high bedrock ridge. Furthermore, lithology had a very strong control on the final deposit morphology in that the different lithologic units form individual deposit surfaces. River erosion has created fortuitous outcrops that reveal the basal rock avalanche contact. The underlying valley‐fill sediments (substrates) have been intricately involved in shaping the rock avalanche morphology and, where entrained, highlight internal rock avalanche deformation features. This study shows that intrinsic dynamic properties of granular media (e.g. tendency for longitudinal alignments), emplacement mode, lithology (and source predisposition), runout path topography, and substrates form the quintet of causal factors that shape rock avalanche morphology. Copyright © 2015 John Wiley & Sons, Ltd.     

Should carbon-exporting countries strive for consumption-based accounting in a global cap-and-trade regime?

In the context of the post-Kyoto policy debate, the question was raised whether the current practice of production-based emissions accounting should be replaced by a consumption-based approach. In this paper, we qualify the conditions under which the way of carbon accounting makes a difference, and show how this affects the incentive of countries to opt for one or the other alternative. Two main insights are presented: First, it is emphasized—and formally shown with a general equilibrium trade model—that the way of accounting has neither efficiency nor distributive effects in the presence of a global cap-and-trade regime with full coverage and given national emission caps. Second, the accounting scheme does matter whenever the initial allocation rule for emission rights is related to past emissions. However, for a net exporter of carbon such as China, the preference for one or the other turns out to be ambiguous, since the current production-based accounting would be favored under grandfathering, whereas consumed carbon would be the preferred measure whenever higher current or historic emissions imply a lower initial allowance, as e.g. under the principle of historical responsibility.