Major and trace-element composition and pressure–temperature evolution of rock-buffered fluids in low-grade accretionary-wedge metasediments, Central Alps

The chemical composition of fluid inclusions in quartz crystals from Alpine fissure veins was determined by combination of microthermometry, Raman spectroscopy, and LA-ICPMS analysis. The veins are hosted in carbonate-bearing, organic-rich, low-grade metamorphic metapelites of the Bündnerschiefer of the eastern Central Alps (Switzerland). This strongly deformed tectonic unit is interpreted as a partly subducted accretionary wedge, on the basis of widespread carpholite assemblages that were later overprinted by lower greenschist facies metamorphism. Veins and their host rocks from two locations were studied to compare several indicators for the conditions during metamorphism, including illite crystallinity, graphite thermometry, stability of mineral assemblages, chlorite thermometry, fluid inclusion solute thermometry, and fluid inclusion isochores. Fluid inclusions are aqueous two-phase with 3.7–4.0 wt% equivalent NaCl at Thusis and 1.6–1.7 wt% at Schiers. Reproducible concentrations of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, B, Al, Mn, Cu, Zn, Pb, As, Sb, Cl, Br, and S could be determined for 97 fluid inclusion assemblages. Fluid and mineral geothermometry consistently indicate temperatures of 320 ± 20 °C for the host rocks at Thusis and of 250 ± 30 °C at Schiers. Combining fluid inclusion isochores with independent geothermometers results in pressure estimates of 2.8–3.8 kbar for Thusis, and of 3.3–3.4 kbar for Schiers. Pressure–temperature estimates are confirmed by pseudosection modeling. Fluid compositions and petrological modeling consistently demonstrate that chemical fluid-rock equilibrium was attained during vein formation, indicating that the fluids originated locally by metamorphic dehydration during near-isothermal decompression in a rock-buffered system.     

Geochemical evidence for melting of carbonated peridotite on Santa Maria Island, Azores

The islands of the Azores archipelago emerge from an oceanic plateau built on lithosphere increasing in age with distance from the Mid-Atlantic Ridge from 10 to 45 Ma. Here, we present the first comprehensive major and trace element and Sr–Nd–Pb isotope data from Santa Maria, the easternmost island of the archipelago, along with published data from the other Azores islands situated much closer to the Mid-Atlantic Ridge axis. We can show that the distinctively more variable and more enriched trace element ratios at Santa Maria combined with a relatively small range in Sr–Nd–Pb isotope ratios are the result of low degrees of partial melting of a common Azores mantle plume source underneath thicker lithosphere. This implies that melt extraction processes and melting dynamics may be able to better preserve the trace element mantle source variability underneath thicker lithosphere. These conclusions may apply widely for oceanic melts erupted on relatively thick lithosphere. In addition, lower Ti/Sm and K/La ratios and SiO₂ contents of Santa Maria lavas imply melting of a carbonated peridotite source. Mixing of variable portions of deep small-degree carbonated peridotite melts and shallow volatile-free garnet peridotite could explain the geochemical variability underneath Santa Maria in agreement with the volatile-rich nature of the Azores mantle source. However, Santa Maria is the Azores island where the CO₂-rich nature of the mantle source is more evident, reflecting a combination of a smaller extent of partial melting and the positioning at the edge of the tilted Azores mantle plume.     

Neotectonics and recent uplift at Kamchatka and Aleutian arc junction, Kamchatka Cape area, NE Russia

The tectonic position of the Kamchatka Cape Peninsula at the junction of the active Kuril–Kamchatka and Aleutian arcs exposes the coastline of the peninsula to strong neotectonic activities. Fracture zones have variable influence on uplift of the Kamchatka Cape Peninsula. Relevant morphologic indicators of neotectonic activity are multilevel, highly uplifted marine terraces and terraces displaced along active faults. Recent uplift rates of coastal sediments are determined by remote sensing via ASTER and SRTM DEM combined with optically stimulated luminescence dating (OSL). On the Kamchatka Cape Peninsula, terraces from the same generation are mapped at different elevations by remote sensing methods. After defining different areas of uplifted terraces, four neotectonic blocks are identified. According to apatite fission track data, the mean differential exhumation rates range from 0.2 to 1.2 mm year^?1 across the blocks since Late Miocene. The OSL data presented point to significant higher uplift rates of up to 3 ± 0.5 and 4.3 ± 1 mm year^?1, which indicates an acceleration of the vertical movement along the coast of Kamchatka Cape Peninsula in Upper Pleistocene and Holocene times.     

A symplectic mapping for the synchronous spin-orbit problem

We derive a symplectic mapping model based on Hadjidemetriou’s method for the synchronous spin-orbit problem with and without the additional precession of the nodes. The mapping is derived from the averaged potential of the spin-orbit dynamical model and includes the main spin-orbit interactions, i.e. the non-zero obliquity and wobble motion of the rotating body. In addition the orbit of the perturbing body allows non-zero inclination and eccentricity. To obtain the equilibrium configuration we calculate the position and stability of the fixed points in the 1:1 spin-orbit resonance and relate them to the equilibria of the continuous system. We use the mapping equations to investigate the long-term stability close to the fixed point solutions of the mapping. We also apply the mapping method to the case of the moon Titan and validate the mapping approach by means of numerical integrations. The mapping model reproduces all the characteristics of Deprit’s model of free rotation as well as the dynamical features of Henrard’s averaged model of spin-orbit interaction with great precision.     

Late Pleistocene and Holocene terrestrial geomorphodynamics and soil formation in northeastern Germany: a review of geochronological data

ABSTRACT

This study is based on 616 geochronological ages from aeolian and colluvial sediments as well as paleosols, representing the largest database of geochronological data from northeastern Germany available to date. Cumulative probability density functions for radiocarbon data and kernel density estimates for luminescence data were created covering the last 15 ka. The data analysis aimed at the identification of changes and their drivers in geomorphodynamics and soil formation. The ages representing aeolian activity cluster in the Late Glacial, the Early Holocene, and the Late Holocene, where the first two clusters are assumed to result mostly from climatic impact with only a minor share of human impact triggering the mobilization of aeolian sediments. The third cluster is considered to result mainly from human impact. The Late Glacial to Early Holocene activity phase is interrupted by a phase of surface stability around 11.5–12.7 ka, which is indicated by the occurrence of initial soil formations of Finow and Usselo types. Colluvial sedimentation predominantly occurred during the last 7 ka and clearly accelerated since the last 1000 a. According to the ages of specific paleosol types, related soil-forming processes started already in the Late Glacial and were completed in the Holocene.     

Relations between denudation,glaciation, and sediment deposition: implications from the Plio‐Pleistocene Central Alps

Despite abundant data on the early evolution of the Central Alps, the latest stage exhumation history, potentially related to relief formation, is still poorly constrained. We aim for a better understanding of the relation between glaciation, erosion and sediment deposition. Addressing both topics, we analysed late Pliocene to recent deposits from the Upper Rhine Graben and two modern river sands by apatite fission‐track and (U‐Th‐Sm)/He thermochronology. From the observed age patterns we extracted the sediment provenance and paleo‐erosion history of the Alpine‐derived detritus. Due to their pollen and fossil record, the Rhine Graben deposits also provide information on climatic evolution, so that the erosion history can be related to glacial evolution during the Plio‐Pleistocene. Our data show that Rhine Graben deposits were derived from Variscan basement, Hegau volcanics, Swiss Molasse Basin, and the Central Alps. The relations between glaciation, Alpine erosion, and thermochronological age signals in sedimentary rocks are more complex than assumed. The first Alpine glaciation during the early Pleistocene did not disturb the long‐term exhumational equilibrium of the Alps. Recent findings indicate that main Alpine glaciation occurred at ca. 1 Ma. If true, then main Alpine glaciation was coeval with an apparent decrease of hinterland erosion rates, contrary to the expected trend. We suggest that glaciers effectively sealed the landscape, thus reducing the surface exposed to erosion and shifting the area of main erosion north toward the Molasse basin, causing sediment recycling. At around 0.4 Ma, erosion rates increased again, which seems to be a delayed response to main glaciation. The present‐day erosion regime seems to be dominated by mass‐wasting processes. Generally, glacial erosion rates did not exceed the pre‐glacial long‐term erosion rates of the Central Alps.     

Quaternary coastline evolution of Lake Ohrid (Macedonia/Albania)

Lake Ohrid (between FYR of Macedonia and Albania), situated in an active tectonic region of the Balkanides, is characterized by N ?? S trending active faults. To reconstruct the Holocene shoreline evolution we investigated the coastline using sediment cores and geophysical methods to image sedimentary and tectonic structures. We revealed areas of differing sedimentation regimes. The plains north and south of the lake are dominated by clastic input related to climate variations and uplift/erosion, whereas the steep western and eastern margins are controlled by recent tectonics. Furthermore, no evidence for a much higher lake-level during the Holocene was found in the plains north and south of the lake, except rare temporary floodings. This is supported by mappings of the limestone cliffs around Lake Ohrid, which yielded no evidence for abrasional platforms or notches as indicators for past highstands.     

A chromate-contaminated site in southern Switzerland – Part 2: Reactive transport modeling to optimize remediation options

A 2D horizontal reactive transport model of a chromate-contaminated site near Rivera, Switzerland, was developed using the computer code CrunchFlow to evaluate site remediation strategies. Transport processes were defined according to the results of an existing hydrological model, and the definition of geochemical (reactive) processes is based on the results of a detailed mineralogical and geochemical site characterization leading to a comprehensive conceptual site model. Kinetics of naturally occurring Cr(VI) reduction by Fe(II) and natural solid organic matter is quantified by fitting measured Cr isotope ratios to a modeled 1D section along the best constrained flow line. The simulation of Cr isotope fractionation was also incorporated into the 2D model. Simulation of the measured present day Cr(VI) plume and δ⁵³Cr value distribution was used for the 2D model calibration and corresponds to a situation where only monitored natural attenuation (MNA) is occurring. Other 2D model runs simulate alternate excavation scenarios. The simulations show that with an excavation of the top 2–4 m the groundwater Cr(VI) plume can be minimized, and that a deeper excavation depth only diminishes the plume if all the contaminants can be removed. A combination of an excavation of the top 2–4 m and monitoring of the ongoing natural Cr(VI) reduction is suggested as the most ecological and economical remediation strategy, even though a remaining time period with ongoing subsoil Cr(VI) contamination in the order of 1 ka is predicted.