FIB‐TEM analysis of cometary material in 10 Stardust foil craters

Aluminum foils from the Stardust cometary dust collector contain impact craters formed during the spacecraft's encounter with comet 81P/Wild 2 and retain residues that are among the few unambiguously cometary samples available for laboratory study. Our study investigates four micron‐scale (1.8–5.2 μm) and six submicron (220–380 nm) diameter craters to better characterize the fine (<1 μm) component of comet Wild 2. We perform initial crater identification with scanning electron microscopy, prepare the samples for further analysis with a focused ion beam, and analyze the cross sections of the impact craters with transmission electron microscopy (TEM). All of the craters are dominated by combinations of silicate and iron sulfide residues. Two micron‐scale craters had subregions that are consistent with spinel and taenite impactors, indicating that the micron‐scale craters have a refractory component. Four submicron craters contained amorphous residue layers composed of silicate and sulfide impactors. The lack of refractory materials in the submicron craters suggests that refractory material abundances may differentiate Wild 2 dust on the scale of several hundred nanometers from larger particles on the scale of a micron. The submicron craters are enriched in moderately volatile elements (S, Zn) when normalized to Si and CI chondrite abundances, suggesting that, if these craters are representative of the Wild 2 fine component, the Wild 2 fines were not formed by high‐temperature condensation. This distinguishes the comet's fine component from the large terminal particles in Stardust aerogel tracks which mostly formed in high‐temperature events.     

A new systematic approach using the Modified Gaussian Model: Insight for the characterization of chemical composition of olivines, pyroxenes and olivine-pyroxene mixtures

An automatic procedure has been implemented on the original MGM approach (Sunshine et al., 1990) in order to deal with an a priori unknown mafic mineralogy observed in the visible-near infrared by reflectance spectroscopy in the case of laboratory or natural rock spectra. We consider all the mixture possibilities involving orthopyroxene, clinopyroxene and olivine, and use accordingly for each configuration different numbers of Gaussians, depending on the potential complexity of the mixture. A key issue is to initialize the MGM procedure with a proper setting for the Gaussians parameters. An automatic analysis of the shape of the spectrum is first performed. The continuum is handled with a second order polynomial adjusted on the local maxima along the spectrum and Gaussians parameters initial settings are made on the basis of laboratory results available in the literature in the case of simple mixtures of mafic minerals. The returned MGM solutions are then assessed on spectroscopic grounds and either validated or discarded, on the basis of a mineralogical sorting.The results presented in this paper are a first quantitative step to characterize both modal and chemical compositions of pyroxenes and olivines. A demonstration of the methodology on specific examples of binary and ternary olivine-pyroxenes mixtures has been made, which shows that the different non-linear effects which affect the Gaussian parameters (center and strength) can be successfully handled. Of note is the fact that the band center positions associated with the different mafic minerals are not set here in the inverse problem, and thus the MGM outputs are truly informative of the chemical composition of pyroxenes and olivines. With the consideration of some limits on the detection thresholds, these results are quite promising for increasing the operational use of the Modified Gaussian Model with large hyperspectral data sets in view of establishing detailed mineralogical mappings of magmatic units.     

The end of moai quarrying and its effect on Lake Rano Raraku, Easter Island

We reconstruct aspects of the history of Easter Island over the last 4-5 centuries based on the study of a core from Rano Raraku Lake, situated in the crater that contains the quarry of the island's giant statues or moai. We use microfossils of plants and animals to identify five zones. The last three of these are separated by waves of immigration from South America and from the subantarctic. We argue that the first or South American wave, dated to the second half of the 14th century, may represent a visit by South American Indians. Magnetic information, pollen, diatoms, chrysophyte stomatocysts and fossil plant pigments reveal a synchronism between the South American contact and the cessation of moai quarrying. We therefore suggest that Amerindians contributed to the cultural collapse of the island. The second or subantarctic wave may reflect an early European visit to the island, possibly by Cpt. James Cook in 1774, or by Jacob Roggeveen in 1722.     

Environmental corrections to gamma-ray log data: Strategies for geophysical logging with geological and technical drilling

Correction concepts for the elimination of environmental influences on gamma-ray logs have been published in a number of articles and in guidelines by service companies. However, these widely-used processing rules for open- and cased-hole measurement conditions have been presented in different forms using different assumptions. For a detailed comparison, these concepts were reduced to simple analytical formula with the application of the same units and scaling to common, standardised conditions. For geological and technical drilling, environmental influences like borehole geometry, casing configuration and material, as well as mud density have turned out to represent the most important effects for a characterisation of environmental conditions. Typical case histories show that correction processing may lead to differing results, depending on the chosen presumptions. A thorough analysis of different types of influences and a careful choice of adequate correction procedures substantially improve the quality of gamma-ray log data. Further implications of these analytical correction rules permit also the quantitative interpretation of logs in dry cased-hole intervals and with the presence of tool joints or casing collars. The latter effect is widely underrated but is proven here to be a necessary step in precise gamma-ray log processing.     

L'ı̂le de la Dominique, à l'origine des avalanches de débris les plus volumineuses de l'arc des Petites AntillesThe Island of Dominica,site for the generation of the most voluminous debris avalanches in the Lesser Antilles Arc

Results from recent fieldwork and the Aguadomar marine survey in the Lesser Antilles clearly indicate that the volcanic field of southern Dominica has experienced three major edifice collapse events. This led to formation of the most voluminous debris avalanches known in the Caribbean Arc. Submarine hummocky morphology with plurikilometric megablocks is characteristic of debris avalanche deposits. We propose that steep slopes on the western Caribbean side of the island and intense hydrothermal alteration lead to recurrent large-scale edifice collapses. Therefore islands in the Lesser Antilles face a non-negligible risk from generation of tsunamis associated with potential future edifice collapse. To cite this article: A. Le Friant et al., C. R. Geoscience 334 (2002) 235–243.     

Exploring aberrant bivalve shell ultrastructure and geochemistry as proxies for past sea water acidification

Throughout much of Earth's history, marine carbonates have represented one of the most important geological archives of environmental change. Several pivotal events during the Phanerozoic, such as mass extinctions or hyperthermal events have recently been associated with ocean acidification. Nevertheless, well‐defined geological proxies for past ocean acidification events are, at best, scarce. Here, experimental work explores the response of bivalve shell ultrastructure and isotope geochemistry (δ¹³C, δ¹⁸O and δ²⁶Mg) to stressful environments, in particular to sea water acidification. In this study, the common blue mussel, Mytilus edulis, was cultured (from early juvenile stages to one year of age) at four pH regimes (pH_NBS 7·2 to pH 8·0). Shell growth rate and ultrastructure of mainly the calcitic portion of the shells were compared between experimental treatments. Specimens exposed to low‐pH environments show patches of disordered calcitic fibre orientation in otherwise well‐structured shells. Furthermore, the electron backscattered diffraction analyses reveal that, under acidified conditions, the c‐axis of the calcite prisms exhibits a bimodal or multi‐modal distribution pattern. Similar shell disorder patterns have been reported from mytilids kept under naturally acidified sea water conditions. In contrast, this study found no evidence that different pH regimes affect shell carbon, oxygen or magnesium isotope ratios. Based on these observations, it is proposed that: (i) stressful environments, in this case low sea water pH, predictably affect bivalve biomineralization patterns; and (ii) these findings bear potential as a novel (petrographic) proxy for ancient sea water acidification. An assessment of the applicability of these data to well‐preserved fossil shell material from selected time intervals requires additional work.