Comparison of soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters

The choice of sampling method for soil solution is of great importance. In this paper soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters have been studied with the purpose of investigating systematic differences between them. The samples were taken at 4 depths from an acidified forest soil as well as from adjacent lime and ash treated soils. A centrifugation drainage method was compared with two types of suction lysimeters (‘Rhizon’ and ‘Prenart’) and zero-tension lysimeters. About half of the 27 variables measured showed a significant difference between the sampling methods used. Typically the centrifuged samples had lower pH (4.0 vs. 4.4), Ca (21 μM vs. 30 μM) and Mg (25 μM vs. 34 μM) concentrations and higher Cl (330 μM vs. 230 μM) and DOC (4.4 mM vs. 3.2 mM) concentrations than the Rhizon lysimeters. Also the other lysimeters showed significant differences compared to the centrifuged samples for about half the number of analytes. Centrifuged samples had higher concentrations of all analytes except NO₃ and PO₄ compared to zero-tension lysimeters and also for all analytes except NO₃ and Al compared to Prenart lysimeters. Among the environmental factors considered depth showed an influence to some extent, while sampling occasion had a great significant impact on the difference between the centrifugation method and the Rhizon lysimeters. Factors like individual pits or soil treatment did not show any influence on the difference between the methods.     

The geochemistry and provenance of Apollo 16 mafic glasses

The regolith of the Apollo 16 lunar landing site is composed mainly of feldspathic lithologies but mafic lithologies are also present. A large proportion of the mafic material occurs as glass. We determined the major element composition of 280 mafic glasses (>10 wt% FeO) from six different Apollo 16 soil samples. A small proportion (5%) of the glasses are of volcanic origin with picritic compositions. Most, however, are of impact origin. Approximately half of the mafic impact glasses are of basaltic composition and half are of noritic composition with high concentrations of incompatible elements. A small fraction have compositions consistent with impact mixtures of mare material and material of the feldspathic highlands. On the basis of major-element chemistry, we identified six mafic glass groups: VLT picritic glass, low-Ti basaltic glass, high-Ti basaltic glass, high-Al basaltic glass, KREEPy glass, and basaltic-andesite glass. These glass groups encompass 60% of the total mafic glasses studied. Trace-element analyses by secondary ion mass spectroscopy for representative examples of each glass group (31 total analyses) support the major-element classifications and groupings. The lack of basaltic glass in Apollo 16 ancient regolith breccias, which provide snapshots of the Apollo 16 soil just after the infall of Imbrium ejecta, leads us to infer that most (if not all) of the basaltic glass was emplaced as ejecta from small- or moderate-sized impacts into the maria surrounding the Apollo 16 site after the Imbrium impact. The high-Ti basaltic glasses likely represent a new type of basalt from Mare Tranquillitatis, whereas the low-Ti and high-Al basaltic glasses possibly represent the composition of the basalts in Mare Nectaris. Both the low-Ti and high-Al basaltic glasses are enriched in light-REEs, which hints at the presence of a KREEP-bearing source region beneath Mare Nectaris. The basaltic andesite glasses have compositions that are siliceous, ferroan, alkali-rich, and moderately titaniferous; they are unlike any previously recognized lunar lithology or glass group. Their likely provenance is within the Procellarum KREEP Terrane, but they are not found within the Apollo 16 ancient regolith breccias and therefore were likely deposited at the Apollo 16 site post-Imbrium. The basaltic-andesite glasses are the most ferroan variety of KREEP yet discovered.     

SOCIAL RELATIONS SPATIALLY FIXED: CONSTRUCTION AND MAINTENANCE OF SCHOOL DISTRICTS IN SAN ANTONIO,TEXAS

ABSTRACT. More than 140 court cases filed in the United States between 1970 and 2003 argued that unacceptable and unconstitutional funding disparities exist among school districts in most states. In those arguments, stories, statistics, and maps are used to compare various school districts to prove that conditions are indeed unequal. Both sides—plaintiff and defendant—use such information to disprove each other's contentions. In so doing, each assumes that the political spaces of the school districts are absolute, timeless, and independent. Failure to recognize that these spaces—the school districts—are not objective but, in fact, constitutive of the class and race relations actually being argued and debated in court further legitimates local geographies of privilege and deprivation. I examine the formation of the school districts around San Antonio, Texas to illustrate that these districts are far from independent of one another and were formed to isolate privileged communities from the rest of the city. A relational view of space‐time allows such spaces as school districts to assume a political role, as opposed to the absolute, independent spaces they now represent.     

Transparency: aid or obstacle to effective defence of vulnerable environments from reservoir construction? Dam decisions and democracy in North East England

Public participation in transparent decisionmaking has been proposed as a panacea for environmental protection. Bargaining theory suggests drawbacks to transparency such as hardening of attitudes and intransigence. Yet achievement of consensus on environmental values for integrated water resource management demands public involvement. Historical study of attempts to prevent reservoir construction in upland valleys designated for protection of nature suggests that 'closed-door' bargaining proved more effective for environmentalists than open, public debate. Records now open for analysis of disputes over Teesdale and Farndale, 1950–1970, allow comparisons to be made between behind-the-scenes deliberations and 'open-door' public discussion. The ambition of progressing from public participation to devolution of environmental decisionmaking and responsibility to the local scale demands more conceptualization of the process of decisionmaking on water resource development.     

Large-scale mass wasting in ancient volcanic materials

Giant landslides are significant hazards associated with many active volcanic edifices. We describe a similar feature on ancient (>4 Ma) volcanic deposits subject to active tectonism. The landslide is approximately 3 km long by 1 km wide, with an estimated depth of 400 m. Side margins are straight and parallel, mimicking regional structure; narrow valleys incised down these margins provide low-strength side-release surfaces. Between these is a giant slump consisting of at least four, largely intact, discrete blocks that have moved down-dip a distance of >500 m. A series of flows with areal extents ranging from 0.01 to 0.5 km² extends from the front of the failure. The materials represent an eroded sequence of andesite flows on the flanks of a stratovolcano. These have undergone two phases of hydrothermal alteration, and are deeply weathered to low-density (1040±80 kg m⁻³) silt (59%) and clay (35%) materials with strength properties typical of weathered silts (c=26±3 kN m⁻²; φ=42±8°). The size and location of this landslide preclude detailed geotechnical investigation of the failure. The worth of numerical stability analysis as an alternative technique in assessing the nature of the failure and hence the risk it poses to nearby communities is investigated. Sensitivity analysis identified likely conditions under which initial failure may have occurred: analyses for sensitivity to strength and earthquake acceleration needed conversion to critical combinations (F=1.0) of water table and strength/acceleration to remove the overriding influence of water table fluctuations. Failure was likely initiated either by a high water table level (83-84%), or some combination of intensity VII-IX earthquake waves together with water table heights of 40-80%. A general hazard assessment indicates that the risk associated with creep and catastrophic failure of the main mass is small, whereas the risk from flow failures near the toe of the landslide may be high. Important parameters (hydrological regime, flow failure morphology, age of initiation, and rates of movement) requiring closer investigation are identified. Development of a model is crucial to assessing the hazard associated with a feature such as that described here. With limited resources, a detailed stability analysis is a powerful tool as an initial stage in hazard analysis.     

Chemical alteration and REE mobilization in meteorites from hot and cold deserts

The effects of terrestrial weathering on REE mobilization are evaluated for a variety of uncommon meteorites found in Antarctica and in hot deserts. The meteorites analyzed include 7 non-cumulate eucrites, 10 shergottites, 3 nakhlites, 2 lunar meteorites, 4 angrites, 10 acapulcoites, 1 winonaite, and 1 brachinite. In-situ concentration measurements of lanthanides and selected other minor and trace elements were made on individual grains by secondary ion mass spectrometry (SIMS). In Antarctic meteorites, oxidation converts Ce³⁺ to Ce⁴⁺, which is less soluble than the trivalent REE, resulting in Ce anomalies. The mineral most affected is low-Ca pyroxene. However, not all grains of a given mineral are, and distinct analyses of a single grain can even yield REE patterns with and without Ce anomalies. The effect is most pronounced for Antarctic eucrites in which Ce anomalies are observed not only in individual minerals but also in whole rock samples. Although Ce anomalies are observed in meteorites from hot deserts as well, the most characteristic signs of chemical alteration in this environment are a LREE enrichment with a typical crustal signature, as well as Sr, Ba and U contaminations. These can modify the whole rock REE patterns and disturb the isotope systematics used to date these objects. The LREE contamination is highly heterogeneous, affecting some grains and not others of a given mineral (mainly olivine and low-Ca pyroxene, the two minerals with the lowest REE concentrations). The major conduit for REE movement is through shock-induced cracks and defects, and the highest levels of contamination are found in altered material filling such veins and cracks. Meteorites that experienced low shock levels and those that are highly recrystallized are the least altered.