Determination of total dissolved phosphorus in New Zealand fresh waters (note)

Ultraviolet digestion was found to be simpler and more convenient than perchloric acid digestion in the determination of total dissolved phosphorus in a variety of New Zealand freshwaters, but had limitations when used on waters with a high humic acid content.

Perchloric acid digestion was more powerful, breaking down polyphosphate bonds not affected by ultraviolet, but was subject to phosphorus losses from “bumping” during evaporation to dryness.     

Reaction induced fracturing during replacement processes

Replacement processes are common transformation mechanisms in minerals and rocks at a variety of conditions and scales. The underlying mechanisms are, in general, poorly understood, but both mechanical and chemical processes are thought to be important. Replacement of leucite (KAlSi₂O₆) by analcime (NaAlSi₂O₆ ^.H₂O) is common in silica-poor igneous rocks. A 10% increase in volume is associated with the replacement process, and this generates stresses that eventually cause fracturing of the reacting leucite. Experimentally reacted leucite samples display characteristic fracturing patterns that include both spalling of concentric ‘onion-skin’-like layers near the reacting interface and the formation of cross-cutting, often hierarchically arranged, sets of fractures that divide the remaining leucite into progressively smaller domains. These structures may explain the ‘patchy’ alteration patterns observed in natural leucite samples and similar, so-called, mesh-textures associated with the serpentinization of olivine grains during hydration of mafic or ultramafic rocks. They are also strikingly similar to larger scale patterns formed during spheroidal weathering processes. A simple discrete element model illustrates the mechanics that control the formation of such systems, and shows how these replacement processes may be accelerated due to the generation of new reactive surface area by hierarchical fracturing processes.     

Preliminary Results on the 3-dimensional Seismic Structure of the Lithosphere under the USGS Central California Seismic Array

About 1500 readings of teleseismic P -time residuals obtained from the US Geological Survey seismograph network in central California have been used to obtain a three-dimensional image of seismic velocity anomalies for this area by the method of Aki, Christoffersson & Husebye We found that the California network is less suitable than the LASA and NORSAR arrays for this kind of studies because of its greater proportion of peripheral blocks in which the resolution is very poor for the stochastic inverse solution and the random error effect is severe for the generalized inverse solution. Nevertheless, the resultant velocity anomalies show a remarkable correlation with the San Andreas fault zone to a depth of 75 km. The anomaly pattern changes drastically as the depth exceeds 75 km, suggesting that the asthenosphere has been reached.     

Aperture synthesis observations of individual molecular clouds in M33

Aperture synthesis maps of six fields in the nearby spiral galaxy M33 have revealed the presence of a population of molecular clouds whose masses, sizes, velocity widths, and brightness temperatures are similar to Galactic giant molecular clouds. The masses of the clouds obtained from the virial theorem and from the integrated CO flux are in relatively good agreement, suggesting that the conversion factor from CO flux to molecular mass in M33 is unlikely to be much different from the value measured in our own Galaxy. The star formation properties of these regions are under study with deep optical CCD imaging and near-infrared data.     

Continental growth and volatile exchange during Earth''s evolution

We investigate the thermal and degassing history of the Earth with the help of a parameterized mantle convection model including the volatile exchange between mantle and surface reservoirs. The weakening of mantle silicates by dissolved volatiles is described by a functional relationship between creep rate and water fugacity. We use flow law parameters of diffusion creep in olivine under dry and wet conditions. The mantle degassing rate is considered as directly proportional to the seafloor spreading rate, which is also dependent on the mantle heat flow and the continental area. To calculate the spreading rate, we assume three different continental growth models: constant growth, delayed growth, and the one proposed by Reymer and Schubert (1984, Tectonics, 3: 63–77). The rate of regassing also depends on the seafloor spreading rate, as well as on other factors. Both mechanisms (degassing and regassing) are coupled self-consistently with the help of a parameterized convection model under implementation of a temperature and volatile-content dependent mantle viscosity. We calculate time series for the Earth's evolution over 4.6 Gyr for the average mantle temperature, the mantle heat flow, the mantle viscosity, the Rayleigh number, the Urey ratio, the volatile loss, and the seafloor spreading rate. In those numerical simulations with continental growth from the beginning and a high initial average mantle temperature water is outgassed rapidly. In the delayed continental growth model there is a very early outgassing event and the delayed continental growth has no remarkable influence on the thermal and outgassing history. A similar situation is found for the linear continental growth model but not for the Reymer and Schubert (1984) model.     

Downstream migration of juvenile European sturgeonAcipenser sturio L. in the Gironde estuary

The European sturgeon (Acipenser sturio) is an endangered diadromous fish species that spawns in the rivers in late spring and early summer. The juveniles spend their first years in the brackish waters (5‰ to 25‰) of the estuary zone before moving out to sea. This study describes the downstream migration pattern of juvenile sturgeon, belonging to the 1994 cohort, the only one born naturally in the Gironde basin, France since the end of the 1980s. During October 1994 to December 1996 the inland section of the Gironde estuary was sampled monthly by trawl (n=818 tows) and all European sturgeon caught (n=381) were marked and released. The first sturgeon of the 1994 cohort (TL=27 cm) were caught in early March 1995 in the zones furthest upstream. During their second fall of life, juveniles gradually acclimatized, and spread over a wide range of salinity conditions. A first incursion into marine water was also observed (at least for a few fish) by the end of the second winter. During this second period, sturgeon showed preference for two particular zones situated at 18 and 38 km, respectively, from the mouth of the estuary. These zones, belonging to two different salinity sectors of the estuary, did not appear to be any different to their neighbors with regards to depth and type of substrate. There were no significant size differences among estuarine zones. Seasonal movements of sturgeon seem to be motivated by a search for warmer temperatures. After a period of early acclimatization of 15 months, juvenile European sturgeon appear to be highly tolerant of salinity variations.     

Effect of restored freshwater inflow on macrofauna and meiofauna in upper Rincon Bayou, Texas, USA

Construction of two dams in 1958 and 1982 reduced freshwater inflow events to Rincon Bayou, part of the Nueces Delta near Corpus Christi, Texas, USA. Inflow reduction led to a reverse estuary, where low-salinity water flooded the delta on incoming tides and higher salinities were found near the Nueces River. Hypersaline conditions caused by high evaporation rates and low water levels were common during summer in the upper reaches. In October 1995, an overflow diversion channel was created by lowering the bank of the Nueces River to restore inflow events into Rincon Bayou, which is the main stem creek that runs through the center of the Delta. Hypersaline conditions occurred four times from mid-1994 to mid-1997 and only once after mid-1997. Lower, rather than higher, salinity conditions were found after August 1997 in the upper reaches. Benthic faunal recovery was monitored by changes in macrofauna and meiofauna communities. Macrofauna responded to inflow events with increased abundances, biomass, and diversity but decreased during hypersaline conditions. Meiofauna abundance also increased with increasing inflow. Benthic characteristics were different in Rincon Bayou than in a reference site, upstream from introduced inflow. As inflow events have increased due to the diversion, the opportunities for positive responses to increased flow have increased. Although the oveflow channel was filled in at the end of the demonstration project in fall 2000, the City of Corpus Christi reopened the channel in fall 2001 because the ecological benefits were credited toward the state-mandated minimum flow requirement for the Nueces Estuary.     

Multimedia Risk-Based Soil Cleanup at a Gasoline-Contaminated Site Using Vapor Extraction

At a utility service center, gasoline from an underground storage tank had leaked into subsurface vadose zone soils for several years. To remediate the site, a soil vapor extraction (SVE) system was installed and operated. At the completion of the SVE operation, gasoline-containing residues in several confirmation soil borings exceeded agency-mandated cleanup levels. Rather than continue with SVE, a risk-based approach was developed to evaluate what levels of gasoline-containing residues could be left in the soil and still protect human health. The risk-based approach consisted of simulating the fate of chemical residues through the vadose zone and then into both the ground water and atmosphere. Receptor point concentrations were predicted, and health risks were assessed. The risk assessment concluded that ingestion of contaminated ground water and inhalation of air while showering were the largest potential contributors to risk, and that risks associated with inhalation of vapor-containing ambient air are small. However, all predicted risks are below the acceptable risk levels of 10⁻⁶ individual cancer risk probability and 1.0 hazard index. Therefore, the lead agency accepted the recommendation that the site requires no further remediation. The service center continues normal operations today.