An electron microprobe study of P645/T390: Evidence for an Early Helladic III Lerna–Aegina connection

Middle Helladic Aeginetan Ware is widely distributed throughout the Aegean. It is characterized by a “gold mica or volcanic ash” fabric and is abundant at Lerna on the Argive plain, Greece, in the Middle Helladic and Late Helladic I periods. A group of Early Helladic III ceramics at Lerna includes P645/T390, which also has a volcanic fabric. We have sampled all the major rock types of the separate volcanic episodes on Aegina, Methana, and Poros and analyzed the constituent minerals with the electron microprobe. These analyses provide a reference standard against which the mineralogy of P645/T390 and other potential Aeginetan wares can be compared. The compositions of amphibole, clinopyroxene, plagioclase, and biotite in P645/T390 are identical to the same minerals in dacites on Aegina, suggesting an origin on that island. Compositional mismatches with the minerals of Methana and Poros indicated the ceramic was not manufactured at these locations. This narrow‐necked jar represents the earliest occurrence of Aeginetan Ware on mainland Greece that has been confirmed by a quantitative method. © 2002 Wiley Periodicals, Inc.     

An in situ investigation on the origins and processing of circumstellar oxide and silicate grains in carbonaceous chondrites

We report on the isotopic, chemical, and structural properties of four O‐rich presolar grains identified in situ in the Adelaide ungrouped C2, LaPaZ Icefield (LAP) 031117 CO3.0, and Dominion Range (DOM) 08006 CO3.0 chondrites. All four grains have oxygen‐isotopic compositions consistent with origins in the circumstellar envelopes (CSE) of low‐mass O‐rich stars evolved along the red‐giant and asymptotic‐giant branch (RGB, AGB, respectively) of stellar evolution. Transmission electron microscope (TEM) analyses, enabled by focused‐ion‐beam scanning electron microscope extraction, show that the grain from Adelaide is a single‐crystal Mg‐Al spinel, and comparison with equilibrium thermodynamic predictions constrains its condensation to 1500 K assuming a total pressure ≤10^?3 atm in its host CSE. In comparison, TEM analysis of two grains identified in the LAP 031117 chondrite exhibits different microstructures. Grain LAP‐81 is composed of olivine containing a Ca‐rich and a Ca‐poor domain, both of which show distinct orientations, suggesting changing thermodynamic conditions in the host CSE that cannot be precisely constrained. LAP‐104 contains a polycrystalline assemblage of ferromagnesian silicates similar to previous reports of nanocrystalline presolar Fe‐rich silicates that formed under nonequilibrium conditions. Lastly, TEM shows that the grain extracted from DOM 08006 is a polycrystalline assemblage of Cr‐bearing spinel. The grains occur in different orientations, likely reflecting mechanical assembly in their host CSE. The O‐isotopic and Cr‐rich compositions appear to point toward nonequilibrium condensation. The spinel is surrounded by an isotopically solar pyroxene lacking long‐range atomic order and could have served as a nucleation site for its condensation in the interstellar medium or the inner solar protoplanetary disk.     

The effects of secondary processing in the unique carbonaceous chondrite Miller Range 07687

Our detailed mineralogical, elemental, and isotopic study of the Miller Range (MIL) 07687 meteorite showed that, although this meteorite has affinities to CO chondrites, it also exhibits sufficient differences to warrant classification as an ungrouped carbonaceous chondrite. The most notable feature of MIL 07687 is the presence of two distinct matrix lithologies that result from highly localized aqueous alteration. One of these lithologies is Fe‐rich and exhibits evidence for interaction with water, including the presence of fibrous (dendritic) ferrihydrite. The other lithology, which is Fe‐poor, appears to represent relatively unaltered protolith material. MIL 07687 has presolar grain abundances consistent with those observed in other modestly altered carbonaceous chondrites: the overall abundance of O‐rich presolar grains is 137 ± 3 ppm and the overall abundance of SiC grains is 71 ± 11 ppm. However, there is a large difference in the observed O‐rich and SiC grain number densities between altered and unaltered areas, reflecting partial destruction of presolar grains (both O‐ and C‐rich grains) due to the aqueous alteration experienced by MIL 07687 under highly oxidizing conditions. Detailed coordinated NanoSIMS‐TEM analysis of a large hotspot composed of an isotopically normal core surrounded by a rim composed of ¹⁷O‐rich grains is consistent with either original condensation of the core and surrounding grains in the same parent AGB star, or with grain accretion in the ISM or solar nebula.     

Temporal trends in δ18O composition of precipitation in Germany: insights from time series modelling and trend analysis

Temporal and spatial variations of stable oxygen (¹⁸O) and hydrogen (²H) isotope measurements in precipitation act as important proxies for changing hydro‐meteorological and regional and global climate patterns. Temporal trends in time series of the stable isotope composition in precipitation were rarely observed, and they are poorly understood. These might be a result of a lack of proper trend detection tools and effort for exploring trend processes. Here, we investigate temporal trends of δ¹⁸O in precipitation at 17 observation stations in Germany between 1978 and 2009. We test if significant trends in the isotope time series from different models can be observed. Mann–Kendall trend tests are applied on the isotope series, using general multiplicative seasonal autoregressive integrate moving average (ARIMA) models, which account for first and higher order serial correlations. Effects of temperature, precipitation, and geographic parameters on isotope trends are also investigated in the proposed models. To benchmark our proposed approach, the ARIMA results are compared with a trend‐free pre‐whitening procedure, the state of the art method for removing the first order autocorrelation in environmental trend studies. Moreover, we further explore whether higher order serial correlations in isotope series affects our trend results. Overall, three out of the 17 stations show significant changes when higher order autocorrelation are adjusted, and four show a significant trend when temperature and precipitation effects are considered. The significant trends in the isotope time series generally occur only at low elevation stations. Higher order autoregressive processes are shown to be important in the isotope time series analysis. Results suggest that the widely used trend analysis with only the first order autocorrelation adjustment may not adequately take account of the high order autocorrelated processes in the stable isotope series. The investigated time series analysis method including higher autocorrelation and external climate variable adjustments is shown to be a better alternative. Copyright © 2014 John Wiley & Sons, Ltd.     

Geochemistry of natural chromium occurrence in a sandstone aquifer in Bauru Basin, São Paulo State, Brazil

Anomalous concentrations of Cr(VI) occur in groundwaters of the Adamantina Aquifer, in a large region in the western state of São Paulo, sometimes exceeding the potability limit (0.05 mg L⁻¹). To identify the possible geochemical reactions responsible for the occurrence of Cr in groundwater in Urânia, borehole rock samples were collected in order to carry out mineralogical and chemical analyses. In addition, multilevel monitoring wells were installed and groundwater samples were analyzed. Analyses of the borehole rock samples show the occurrence of a geochemical anomaly of Cr in the quartzose sandstones (average concentrations of 221 ppm). Chrome-diopside is one of the main minerals contributing to this anomaly, having an average Cr content of 1505 ppm. Sequential extraction experiments indicated weakly adsorbed Cr in the order of 0.54 ppm, and this quantity is enough to provide the Cr concentrations observed in groundwater. Groundwaters from the monitoring wells proved to be stratified, with the highest concentrations of Cr(VI) (0.13 mg L⁻¹) being associated with high redox and pH values (over 10) and high concentrations of Na. Geochemical reactions that may explain the release of Cr from the solid phase to groundwater involve the release of Cr(III) from minerals (like chrome-diopside and Cr-Fe hydroxide), followed by oxidation of Cr(III) to Cr(VI), probably related to the reduction of Mn oxides present in the aquifer. Then cation exchange occurs and dissolution of carbonates which increases the pH of groundwater, resulting in the desorption and mobilization of Cr(VI) into groundwater.     

Trial by Fire: natural hazards,mixed-methods and cultural research

This paper considers the issues of research ‘relevance’ and ‘use’ to reflect upon a cultural geography research project on bushfire that did not begin with any specific aim of being useful to policy makers but which has garnered considerable and ongoing interest from a broad audience. It provides an example of how the integration of quantitative and qualitative research methods and data can enhance research into cultural aspects of natural hazards whilst simultaneously playing a key role in ensuring that the research results are of interest to a wide range of groups. Using a mixed-methods research approach was found to provide insight into complex factors that influence attitudes and actions towards bushfire amongst diverse landholders in rural–urban interface areas in south-east Australia. We argue that mixed-methods research is a powerful tool in building and enhancing a cultural geography that has policy relevance, retains analytical depth, and is acceptable to risk managers. The ability of cultural geography through mixed-methods research to illuminate how socio-cultural processes are central to environmental attitudes and preparedness behaviour has direct relevance to recent international discussions of how to manage the vulnerability of the growing number of people living in bushfire-prone rural–urban interface areas.     

Geochronological arguments for a close relationship between surficial formation profiles and environmental crisis (c. 3000–2000 BP) in Gabon (Central Africa)

We present new ¹⁴C data on charcoal fragments recovered from the lower (coarse-grained Stone Line) and upper (fine-grained Cover Horizon) portions of surficial formation profiles in Gabon. These data and others compiled from the literature enable a reconstruction of the Upper Holocene geological regional history of Gabon. The connection between the geological events recorded in the surficial formations and the Upper Holocene environmental crisis is discussed and a scenario connecting geological events with climatic and environmental changes is proposed. Such a scenario suggests that following the climatic crisis, the reconstitution of soils by aeolian sedimentation could have been an important factor of Bantu expansion.