Multi-stage volcanic events: A statistical investigation

Volcanic events comprising multiple eruptive stages are common in the historical and geological record and display activity of variable intensity ranging, in some cases, through to several centuries. To better understand the characteristics of such events globally, this study explores a database of historical events having Volcanic Explosivity Indices 4 or greater. The database was compiled for the most part from published and unpublished material provided by the Smithsonian Institution. The database was examined to find common statistical relationships, within and between the variables characterising multi-stage explosive events.     

Lateral bedrock erosion and valley formation in a heterogeneously layered landscape,Northeast Kansas

In this study, we present direct field measurements of modern lateral and vertical bedrock erosion during a 2-year study period, and optically stimulated luminescence (OSL) ages of fluvial material capping a flat bedrock surface at Kings Creek located in northeast Kansas, USA. These data provide insight into rates and mechanisms of bedrock erosion and valley-widening in a heterogeneously layered limestone-shale landscape. Lateral bedrock erosion outpaced vertical incision during our 2-year study period. Modern erosion rates, measured at erosion pins in limestone and shale bedrock reveal that shale erosion rate is a function of wetting and drying cycles, while limestone erosion rate is controlled by discharge and fracture spacing. Variability in fracture spacing amongst field sites controls the size of limestone block collapse into the stream, which either allowed continued lateral erosion following rapid detachment and transport of limestone blocks, or inhibited lateral erosion due to limestone blocks that protected the valley wall from further erosion. The OSL ages of fluvial material sourced from the strath terrace were older than any material previously dated at our study site and indicate that Kings Creek was actively aggrading and incising throughout the late Pleistocene. Coupling field measurements and observations with ages of fluvial terraces can be useful to investigate the timing and processes linked to how bedrock rivers erode laterally over time to form wide bedrock valleys.     

Heterogeneous mantle source and magma differentiation of quaternary arc-like volcanic rocks from Tengchong,SE margin of the Tibetan Plateau

The Tengchong volcanic field north of the Burma arc comprises numerous Quaternary volcanoes in the southeastern margin of the Tibetan Plateau. The volcanic rocks are grouped into four units (1–4) from the oldest to youngest. Units 1, 3 and 4 are composed of olivine trachybasalt, basaltic trachyandesite and trachyandesite, and Unit 2 consists of hornblende dacite. The rocks of Units 1, 3, and 4 form a generally alkaline suite in which the rocks plot along generally linear trends on Harker diagrams with only slight offset from unit to unit. They contain olivine phenocrysts with Fo values ranging from 65 to 85 mol% and have Cr-spinel with Cr# ranging from 23 to 35. All the rocks have chondrite-normalized REE patterns enriched in LREE and primitive mantle-normalized trace element patterns depleted in Ti, Nb and Ta, but they are rich in Th, Ti and P relative to typical arc volcanics. Despite minor crustal contamination, ⁸⁷Sr/⁸⁶Sr ratios (0.706–0.709), εNd values (−3.2 to −8.7), and εHf values (+4.8 to −6.4) indicate a highly heterogeneous mantle source. The Pb isotopic ratios of the lavas (²⁰⁶Pb/²⁰⁴Pb = 18.02–18.30) clearly show an EMI-type mantle source. The underlying mantle source was previously modified by subduction of the Neo-Tethyan oceanic and Indian continental lithosphere. The present heterogeneous mantle source is interpreted to have formed by variable additions of fluids and sediments derived from the subducted Indian Oceanic lithosphere, probably the Ninety East Ridge. Magma generation and emplacement was facilitated by transtensional NS-trending strike-slip faulting.     

Experimental study of the aragonite to calcite transition in aqueous solution

The experimental replacement of aragonite by calcite was studied under hydrothermal conditions at temperatures between 160 and 200 °C using single inorganic aragonite crystals as a starting material. The initial saturation state and the total [Ca²⁺]:[CO₃²⁻] ratio of the experimental solutions was found to have a determining effect on the amount and abundance of calcite overgrowths as well as the extent of replacement observed within the crystals. The replacement process was accompanied by progressive formation of cracks and pores within the calcite, which led to extended fracturing of the initial aragonite. The overall shape and morphology of the parent aragonite crystal were preserved. The replaced regions were identified with scanning electron microscopy and Raman spectroscopy.Experiments using carbonate solutions prepared with water enriched in ¹⁸O (97%) were also performed in order to trace the course of this replacement process. The incorporation of the heavier oxygen isotope in the carbonate molecule within the calcite replacements was monitored with Raman spectroscopy. The heterogeneous distribution of ¹⁸O in the reaction products required a separate study of the kinetics of isotopic equilibration within the fluid to obtain a better understanding of the ¹⁸O distribution in the calcite replacement. An activation energy of 109 kJ/mol was calculated for the exchange of oxygen isotopes between [C¹⁶O₃²⁻]_aq and [H₂¹⁸O] and the time for oxygen isotope exchange in the fluid at 200 °C was estimated at ∼0.9 s. Given the exchange rate, analyses of the run products imply that the oxygen isotope composition in the calcite product is partly inherited from the oxygen isotope composition of the aragonite parent during the replacement process and is dependent on access of the fluid to the reaction interface rather than equilibration time. The aragonite to calcite fluid-mediated transformation is described by a coupled dissolution-reprecipitation mechanism, where aragonite dissolution is coupled to the precipitation of calcite at an inwardly moving reaction interface.     

Chronic exposure of adults and embryos of Pandalus borealis to oil causes PAH accumulation, initiation of biomarker responses and an increase in larval mortality

Adult shrimps (Pandalus borealis) and their embryos were exposed to an oil-water dispersion (OWD) at concentrations of 0.015, 0.06 and 0.25 mg/L using a continuous flow system. Lysosomal membrane stability was analysed in haemocytes using the neutral red retention assay and an alkaline unwinding assay was used to measure DNA damage in hepatopancreas tissue. Exposure to oil induced concentration and time dependent biomarker responses in adult shrimps together with the accumulation of PAH in their tissues. Oil exposure of shrimp embryos caused increased mortality in the resultant larvae, even if the larvae were kept in clean water after hatching. There were minor differences observed in larval stage development times in the first part of the experiments. The fatty acid composition of embryos exposed to oil was different to that of non-exposed larvae. PAH tissue concentration and biomarker responses correlated to the reduced survival of the shrimp larvae.     

Variography of submarine morphology: Problems of deregularization, and cartographical implications

During the German Antarctic Expedition VI (leg 3, December 1987 to March 1988), bathymetric surveys were made in the Weddell Sea by the SEABEAM sonar system. For the first time geostatistical methods were applied in the SEABEAM-postprocessing. The investigations of variography that were necessary prior to the cartographical-geomorphological evaluation shed new light on classical geostatistical concerns. SEABEAM data provide a good example of a mean square, differentiable regionalized variable, where data are sampled over a two-dimensional support due to the technique of the sonar device. By deregularizations of the sample variograms, spatial continuity can be shown to be a property of seafloor depth as well as a point variable. The results are discussed in a sedimentological context. As an application of the regional variogram analyses, large-scale kriged bathymetric maps are presented.