Evidence for short-lived oscillations in the biological records from the sediments of Lago Albano (Central Italy) spanning the period ca. 28 to 17 k yr BP

We report the results of analyses of pigments (derived from algae and photosynthetic bacteria), diatoms and invertebrate fossil remains (ostracods, cladocerans, chironomids) in two late Pleistocene sediment cores from Lago Albano, a crater lake in Central Italy. The record contains evidence for oscillations in lake biota throughout the period ca. 28 to 17 k yr BP. The earliest of these are contained in the basal 3.5 m of light olive-gray and yellowish-gray spotted muds sampled in core PALB 94-1E from 70 m water depth. The later oscillations are best represented in the more extended sediment sequence recovered from a second core site, PALB 94-6B, in 30 m water depth. The sediments at site 1E, containing the earlier oscillations (ca. 28-24 k yr BP), predate any sedimentation at the shallower site, from which we infer an initially low lake level rising to permit sediment accumulation at site 6B from ca. 24 k yr onwards. At site 6B, massive silts rich in moss remains are interbedded with laminated silts and carbonates. These sediments span the period ca. 24 to 17 k yr and are interpreted as representing, respectively, times of shallow water alternating with higher lake stands, when the lake was stratified and bottom water was stagnant. A range of mutually independent chronological constraints on the frequency and duration of the oscillations recorded in the lake biota indicate that they were aperiodic and occurred on millennial to century timescales. We interpret them as responses to climate forcing through its impact on lake levels and changing aquatic productivity. The time span they occupy, their frequency and their duration suggest that at least some of these changes may parallel both the Dansgaard-Oeschger events recorded in Greenland Ice Cores and the contemporary oscillations in North Atlantic circulation documented in marine sediment cores.     

Geoelectrical investigations in the Cheb Basin/W-Bohemia: An approach to evaluate the near-surface conductivity structure

The Cheb Basin, located in the western Eger (Ohře) Rift, is part of the European Cenozoic Rift system. Although presently non-volcanic, it is the most active area within the European Rift with signs of recent geodynamic activity like emanations of mantle derived CO₂, and the repeated occurrence of swarm earthquakes, which are common features in active volcanic regions. It is assumed that the fluids, uprising in permeable channels, play a key role for the genesis of these earthquake swarms.     

Effects of chronic exposure to dispersed oil on selected reproductive processes in adult blue mussels (Mytilus edulis) and the consequences for the early life stages of their larvae

Mussels (Mytilus edulis) were continuously exposed to dispersed crude oil (0.015-0.25 mg/l) for 7 months covering the whole gamete development cycle. After 1 month exposure to 0.25 mg oil/l, the level of alkali-labile phosphates (ALP) and the volume density of atretic oocytes in female gonads were higher than those in the gonads of control females, indicating that oil affected the level of vitellogenin-like proteins and gamete development. Spawning of mussels was induced after 7 months oil exposure. Parental oil exposure did not affect subsequent fertilization success in clean seawater but this was reduced in 0.25 mg oil/l. Parental exposure to 0.25 mg oil/l caused both slow development and a higher percentage of abnormalities in D-shell larvae 2 days post-fertilization; reduced growth 7 days post-fertilization. These effects were greatly enhanced when larval stages were maintained at 0.25 mg oil/l. Similar studies are warranted for risk assessment prognosis.     

Proposed methods for potential evapotranspiration calculation of the Red River basin (North Vietnam)

Potential evapotranspiration (ETP) is an important part of a climatic water balance and a crucial variable in many kinds of models in computing actual evapotranspiration. The objective of this study was to find a reasonable approach of ETP calculation for a height‐differentiated landscape in subtropical climate. From the pool of diverse approaches, six common methods [Hamon, Priestley–Taylor, Thornthwaite, Blaney–Criddle, Turc and Food and Agricultural Organization Irrigation and Drainage Paper No. 56 (FAO‐56)] were selected. With the meteorological data for long‐term period (1964–2008), the calculation of ETP values was performed for 12 different meteorological stations in the Red River basin. Among the applied ETP calculation methods, the Turc and the FAO‐56 methods agreed well at most stations and represent best the expectations for the ETP values of the Thao and Da subbasins. The findings of our investigations indicate that in highly structured (land use and elevation) regions, not all methods provide satisfying results. Copyright © 2011 John Wiley & Sons, Ltd.     

Mapping iron abundances on the surface of Mercury: Predicted spatial resolution of the MESSENGER Gamma-Ray Spectrometer

To illustrate the spatial resolution of measurements of Mercury's surface elemental composition by the Gamma-Ray Spectrometer on the MESSENGER spacecraft after one year of orbital observations, we have simulated a global coverage map of the 846-keV iron gamma-ray count rate. The simulated map suggests that distinct geologic units larger than 800 km in horizontal dimension will be discernable when the difference in Fe abundance between adjacent geologic units exceeds 4 wt%. These results imply that the MESSENGER Gamma-Ray Spectrometer dataset will provide useful information for regional geological studies of the surface of Mercury.     

Accumulation of dietary organochlorines and vitamins in Baltic seals

We studied the accumulation of polychlorinated biphenyls (PCBs), 1,1,1.trichloro-2,2-bis[p-chlorophenyl]ethane (DDT) and its metabolites, and vitamins A and E in the top levels of the Baltic Sea food web. The investigation focused on the transfer of contaminants and vitamins to the ringed seal (Phoca hispida baltica) and the grey seal (Halichoerus grypus) from their main prey species. The trophic level of the seals was investigated using stable isotopes of nitrogen and the results indicated that both species of Baltic seal feed at approximately the same level. PCBs accumulated to a greater extent in the grey seal than in the ringed seal. Biomagnification factors for DDT compounds were similar for both species of Baltic seal (85-140). Differences in observed DDT levels were due to different prey selection by the two species, while differences in PCB levels indicated a species-specific metabolic system. There was a clearly greater accumulation of DDT compounds than of PCBs in both species of seal. The supply of dietary vitamin A was normally above the recommended level in all the seal populations studied. Low levels of hepatic vitamin A in the Baltic seals could therefore indicate the toxic effects of a high level of persistent organic pollutants on vitamin A dynamics, at least in the ringed seal. In the grey seals, low hepatic vitamin A levels could also be explained by lower levels of dietary vitamin A, compared to the reference grey seals, as it is not known if seals can store unlimited amounts of vitamin A. The greater uptake of vitamin E by Baltic seals, compared to seals in the reference areas, demonstrated by elevated levels of vitamin E in the blubber, could be a response to oxidative stress caused by the high contaminant load. These results further support our previous hypothesis that the toxic effects of environmental contaminants could be causing the observed divergence in vitamin levels between the Baltic seals and the reference seal populations.     

Architecture and temporal variations of a terrestrial CO2 degassing site using electric resistivity tomography and self-potential

International Journal of Earth Sciences - The Hartoušov mofette field in NW Bohemia, Czech Republic, is characterized by strong CO2 degassing from the Lithospheric Mantle. In a test survey...     

Monitoring the impact of de-icing salt on roadside soils with time-lapse resistivity measurements

Monitoring systems along roads are needed to facilitate decisions on improving protection of water resources and decreasing the impact of road-related pollutants on the roadside environment. This paper presents a monitoring system using permanently installed electrodes and monthly measurements of resistivity at a motorway in Sweden with heavy loads of de-icing salt. A significant increase in resistivity in the vadose zone with increasing distance from the road was shown in both sand and glacial till areas during the whole year. By measuring temporal variations in a less affected environment further from the road, a distinction could be made between more natural variations and variations due to de-icing salt and melting of roadside snowbanks. The highest resistivities occurred in October–November and the lowest in January–March, while the more natural resistivities showed an opposing temporal variation. The difference was up to 35% on a log-scale in the sand area during the latter period. Hence, the time-lapse resistivity measurements clearly showed a strong influence of de-icing salt on roadside soils and groundwater during winter and spring. The measurement system and the analysis methods proved useful for monitoring both the spatial and seasonal variation in resistivity.     

Chalcophile element geochemistry and petrogenesis of high-Ti and low-Ti magmas in the Permian Emeishan large igneous province,SW China

Sulfide-poor mafic layered intrusions, sills/dykes and lava flows in the Funing region, SW China, are part of the ~260 Ma Emeishan large igneous province. They belong to either a high-Ti group (TiO₂ = 1.6–4.4 wt%) with elevated Ti/Y ratios (351–1,018), or a low-Ti group (TiO₂ < 1.2 wt%) with low Ti/Y ratios (133–223). This study investigates the role of fractionation of olivine, chromite and sulfide on the distributions of chalcophile elements, Ni, Cu and PGE, of the high-Ti and low-Ti group rocks at Funing. The high-Ti group rocks contain 1.6–5.3 ppb Pt + Pd, 0.06–0.43 ppb Ir and 0.01–0.13 ppb Ru, and show relative constant (Cu/Pd)_PM ratios (4.0–9.7) and a negative correlation between Ni/Pd and Cu/Ir ratios. Fractionated IPGE/PPGE patterns and very negative Ru anomalies of the high-Ti group rocks, together with low Fo values (59–62 mol%) of olivine, indicate that the high-Ti magmas may have experienced fractionation of olivine and chromite under S-undersaturated condition. Based on the PGE concentrations, the low-Ti group rocks can be further divided into two subgroups; a high-PGE low-Ti subgroup and a low-PGE low-Ti subgroup. The high-PGE low-Ti group rocks are rich in MgO (10–20 wt%), but Fo values of olivine from the rocks are low (74–76 mol%). The rocks contain highly variable PGE (Pt + Pd = 1.7–88 ppb, Ir = 0.05–1.3 ppb), Ni (179 –1,380 ppm) and Cu (59–568 ppm). They have Cu/Zr ratios >1, low (Y/Pd)_PM ratios (0.2–7.1) and nearly constant (Cu/Pd)_PM ratios (1.5–3.8). The even and parallel chalcophile element patterns of the high-PGE low-Ti subgroup rocks are likely a result of olivine-dominated fractionation under S-undersaturated condition. The low-PGE low-Ti group rocks have low MgO (4.5–8.9 wt%) and very poor PGE (Pt + Pd 0.5–1.6 ppb, Ir 0.004–0.02 ppb) with low Cu/Zr ratios (0.1–0.5), high (Y/Pd)_PM (26–70) and variable (Cu/Pd)_PM ratios (2.8–14). The trough-like chalcophile element patterns of the low-PGE low-Ti subgroup rocks indicate that the magmas were sulfide saturation and sulfide melts were extracted from the magmas. The extracted sulfide melts might be potential Ni–Cu sulfide ores at depth in the Funing region.