Re–Os isotope and platinum-group element geochemistry of the Pobei Ni–Cu sulfide-bearing mafic–ultramafic complex in the northeastern part of the Tarim Craton

A number of mafic–ultramafic intrusions that host Ni–Cu sulfide mineralization occur in the northeastern Tarim Craton and the eastern Tianshan Orogenic Belt (NW China). The sulfide-mineralized Pobei mafic–ultramafic complex is located in the northeastern part of the Tarim Craton. The complex is composed of gabbro and olivine gabbro, cut by dunite, wehrlite, and melatroctolite of the Poyi and Poshi intrusions. Disseminated Ni–Cu sulfide mineralization is present towards the base of the ultramafic bodies. The sulfide mineralization is typically low grade (<0.5 wt.% Ni and <2 wt.% S) with low platinum-group element (PGE) concentrations (<24.5 ppb Pt and <69 ppb Pd); the abundance of Cu in 100 % sulfide is 1–8 wt.%, and Ni abundance in 100 % sulfide is typically >4 wt.%. Samples from the Pobei complex have εNd (at 280 Ma) values up to +8.1, consistent with the derivation of the magma from an asthenospheric mantle source. Fo 89.5 mol.% olivine from the ultramafic bodies is consistent with a primitive parental magma. Sulfide-bearing dunite and wehrlite have high Cu/Pd ratios ranging from 24,000 to 218,000, indicating a magma that evolved under conditions of sulfide saturation. The grades of Ni, Cu, and PGE in 100 % sulfide show a strong positive correlation. A model for these variations is proposed where the mantle source of the Pobei magma retained ~0.033 wt.% sulfide during the production of a PGE-depleted parental magma. The parental magma migrated from the mantle to the crust and underwent further S saturation to generate the observed mineralization along with its high Cu/Pd ratio at an R-factor varying from 100 to 1,200. The mineralization at Poshi and Poyi has very high γOs (at 280 Ma) values (+30 to +292) that are negatively correlated with the abundance of Os in 100 % sulfide (5.81–271 ppb) and positively correlated with the Re/Os ratios; this indicates that sulfide saturation was triggered by the assimilation of crustal sulfide with both high γOs and Re/Os ratios. When compared to other Permian mafic–ultramafic intrusions with sulfide mineralization in the East Tianshan, the Poyi and Poshi ultramafic bodies were formed from more primitive magmas, and this helps to explain why the sulfide mineralization has high Ni tenor.     

The age of the Roter Kamm impact crater,Namibia: Constraints from 40Ar-39Ar,K-Ar,Rb-Sr,fission track,and 10Be-26Al studies

Abstract The well-preserved 2.5 km diameter Roter Kamm impact crater is located in the Namib desert in Namibia. The impact has occurred in Precambrian granitic and granodioritic orthogneisses of the 1200–900 Ma old Namaqualand Metamorphic Complex which were partly covered by Gariep metasediments; the granites are invaded by quartz veins and quartz-feldspar-pegmatites. Previous geological field evidence suggested a crater age of about 5–10 Ma. In order to constrain this age, we selected a set of basement rocks (granites, granodiorites) exposed at the crater rim and studied the Rb-Sr, K-Ar, ⁴⁰Ar-³⁹Ar, and ¹⁰Be-²⁶Al isotopic systems as well as apatite fission track ages of these samples. The Rb-Sr isotopic systematics confirm the derivation of these samples from the Namaqualand basement (age about 1.29 Ga), which underwent Damaran orogenesis at about 650 Ma. No basement rocks with Rb-Sr ages younger than about 410 Ma were identified. The K-Ar ages of pseudotachylite and melt breccia samples show that these samples are dominated by incompletely degassed fragments of basement rocks, with some retaining their original metamorphic ages of about 470 Ma. The apatite fission track ages range from 20–28 Ma, which may be interpreted as an extension of the 25 Ma Burdigalian peneplanation event, or as incomplete resetting of the apatite fission tracks during the impact event. The ¹⁰Be and ²⁶Al exposure age of a quartz sample isolated from a quartz-pegmatite was found to be 150 ka; it is likely that the exposure of the sample began after material covering it had been removed by erosion 150 ka ago. Two glassy fractions extracted from a rim granite were dated by ⁴⁰Ar-³⁹Ar analysis. One sample gives practically a plateau age of 3.7 ± 0.3 Ma, while the other gives a minimum age of 3.6 Ma. The best available age estimate for the Roter Kamm crater is therefore 3.7 ± 0.3 Ma.     

Microtopography,water storage and flow patterns in a fine‐textured soil under agricultural use

Agricultural use of soils implies tillage and often compaction and therefore influences processes on soil surface and affects infiltration of water into the subsoil. Although many studies on soil surface processes or flow patterns in soils exist, works relating both are rare in literature. We did two tracer experiments with Brilliant Blue FCF on a tilled and compacted plot and a non‐tilled one to investigate water storage on the soil surface during simulated rainfall and changes of soil microtopography, to analyse the associated flow patterns in the soil and to relate both to tillage and compaction. Our results show that storage was larger on the tilled and compacted plot than on the non‐tilled one. After tillage, transport processes above the plough pan were partly disconnected from those underneath because macropores were disrupted and buried by the tillage operation. However, preferential flow along cracks occurred on both plots and the macropores buried below the tillage pan still functioned as preferential flow paths. Therefore, we conclude that the studied soil is susceptible to deep vertical solute propagation at dry conditions when cracks are open, irrespective of tillage and compaction. Copyright © 2012 John Wiley & Sons, Ltd.     

Till‐forming processes beneath parts of the Cordilleran Ice Sheet,British Columbia,Canada: macroscale and microscale evidence and a new statistical technique for analysing microstructure data

This paper presents the first integrated macroscale and microscale examination of subglacial till associated with the last‐glacial (Fraser Glaciation) Cordilleran Ice Sheet (CIS). A new statistical approach to quantifying till micromorphology (multivariate hierarchical cluster analysis for compositional data) is also described and implemented. Till macrostructures, macrofabrics and microstructures support previous assertions that primary till in this region formed through a combination of lodgement and deformation processes in a temperate subglacial environment. Macroscale observations suggest that subglacial environments below the CIS were probably influenced by topography, whereby poor drainage of the substrate in topographically constricted areas, or on slopes adverse to the ice‐flow direction at glacial maximum, facilitated ductile deformation of the glacier bed. Microscale observations suggest that subglacial till below the CIS experienced both ductile and brittle deformation, including grain rotation and squeeze flow of sediment between grains under moist conditions, and microshearing, grain stacking and grain fracturing under well‐drained conditions. Macroscale observations suggest that ductile deformation events were probably followed by brittle deformation events as the substrate subsequently drained. The prevalence of ductile‐type microstructures in most till exposures investigated in this study suggests that ductile deformation signatures can be preserved at the microscale after brittle deformation events that result in larger‐scale fractures and shear structures. It is likely that microscale ductile deformation can also occur within distributed shear zones during lodgement processes. Cluster analysis of microstructure data and qualitative observations made from thin sections suggest that the relative frequency of countable microstructures in this till is influenced by topography in relation to ice‐flow direction (bed drainage conditions) as well as by the frequency and distribution of voids in the till matrix and skeletal grain shapes.     

Specification of monthly mean anomalies of surface air temperature in Canada and Alaska

Abstract

Anomalies of monthly mean surface temperature observed at 55 stations in Canada and 13 in Alaska from 1951 through 1980 are related to concurrent anomalies of monthly mean 700‐mb height at a network of 107 grid points in North America and the surrounding oceans. The data are screened by a stepwise forward selection procedure to yield multiple regression equations for specifying the monthly mean temperature anomaly at each city and for each month from the field of simultaneous 700‐mb heights plus the previous month's local temperature anomaly. On the average, the specification equations explain 70% of the temperature variance and select as predictors approxiamtely 2 heights to the west of the reference station, 1.5 heights in the vicinity, 1 height to the east, and 0.5 previous temperatures.

Most of this paper describes various properties of the specification equations and related atmospheric characteristics on a regional, seasonal and month‐to‐month basis. Five statistical features are mapped for the months of January, April, July and October, and marked regional differences are noted. The above features are then averaged for the entire region and graphed month by month; the annual cycle of other properties is also described. Systematic spatial and temporal variations in the characteristics of temperature variability, persistence, correlation with height, and specification equations are illustrated.     

PM2.5 co-benefits of climate change legislation part 2: California governor’s executive order S-3-05 applied to the transportation sector

California Governor’s Executive Order (CGEO) S-3-05 requires that California greenhouse gas (GHG) emissions be reduced to 80 % below 1990 levels by the year 2050. Meeting this target will require drastic changes in transportation technology, fuel, and behavior which will reduce criteria pollutant emissions as well as GHG emissions. The improvement to local air quality caused by the reduced criteria pollutant emissions must be calculated to fully evaluate the overall benefits and costs of CGEO S-3-05. In the present study, seven different transportation scenarios that move towards the goals of CGEO S-3-05 in the transportation sector were examined to determine how they would affect future airborne particulate matter (PM_2.5) concentrations in California: (1) hydrogen fuel cells, (2) electric vehicles, (3) high efficiency vehicles, (4) public mass transit, (5) biofuels, (6) biofuels + hybrid electric vehicles, and (7) hydrogen fuel cells + electric vehicles. The air quality implications of each scenario were evaluated using a chemical transport model applied during a wintertime stagnation episode representing future climate in California. Scenarios (6) and (7) reduced population-weighted PM_2.5 mass concentrations by ~9 % and PM_2.5 elemental carbon (EC) concentrations by ~30 % relative to base-case predictions.     

Solar Energetic Particles and Associated EIT Disturbances in Solar Cycle 23

We explore the link between solar energetic particles (SEPs) observed at 1 AU and large-scale disturbances propagating in the solar corona, named after the Extreme ultraviolet Imaging Telescope (EIT) as EIT waves, which trace the lateral expansion of a coronal mass ejection (CME). A comprehensive search for SOHO/EIT waves was carried out for 179 SEP events during Solar Cycle 23 (1997?–?2006). 87 % of the SEP events were found to be accompanied by EIT waves. In order to test if the EIT waves play a role in the SEP acceleration, we compared their extrapolated arrival time at the footpoint of the Parker spiral with the particle onset in the 26 eastern SEP events that had no direct magnetic connection to the Earth. We find that the onset of proton events was generally consistent with this scenario. However, in a number of cases the first near-relativistic electrons were detected too early. Furthermore, the electrons had in general only weakly anisotropic pitch-angle distributions. This poses a problem for the idea that the SEPs were accelerated by the EIT wave or in any other spatially confined region in the low corona. The presence of weak electron anisotropies in SEP events from the eastern hemisphere suggests that transport processes in interplanetary space, including cross-field diffusion, play a role in giving the SEPs access to a broad range of helio-longitudes.     

Long-term variations in the microwave brightness temperature of the Uranus atmosphere

We present a self-consistent, 36-year record of the disk-averaged radio brightness of Uranus at wavelengths near 3.5 cm. It covers nearly half a uranian year, and includes both equatorial and polar viewing geometries (corresponding to equinox and solstice, respectively). We find large (greater than 30 K) changes over this time span. In agreement with analyses made of more limited microwave data sets, our observations suggest the changes are not caused by geometric effects alone, and that temporal variations may exist in the deep uranian troposphere down to pressures of tens of bars. Our data also support an earlier suggestion that a rapid, planetary-scale change may have occurred in late 1993 and early 1994. The seasonal record presented here will be useful for constraining dynamical models of the deep atmosphere, and for interpreting observations made during Uranus' 2007 equinox passage. As part of a multi-wavelength observing campaign for this event, the Goldstone-Apple Valley Radio Telescope (GAVRT) project will continue to make frequent, single-dish observations near 3.5 cm.