Equilibrium coexistence of three amphiboles

Electron probe and wet chemical analyses of amphibole pairs from the sillimanite zone of central Massachusetts and adjacent New Hampshire indicated that for a particular metamorphic grade there should be a restricted composition range in which three amphiboles can coexist stably. An unequivocal example of such an equilibrium three amphibole rock has been found in the sillimanite-orthoclase zone. It contains a colorless primitive clinoamphibole, space group P2₁/m, optically and chemically like cummingtonite with blue-green hornblende exsolution lamellae on (100) and (¯101) of the host; blue-green hornblende, space group C2/m, with primitive cummingtonite exsolution lamellae on (100) and (¯101) of the host; and pale pinkish tan anthophyllite, space group Pnma, that is free of visible exsolution lamellae but is a submicroscopic intergrowth of two orthorhombic amphiboles. Mutual contacts and coarse, oriented intergrowths of two and three host amphiboles indicate the three grew as an equilibrium assemblage prior to exsolution. Electron probe analyses at mutual three-amphibole contacts showed little variation in the composition of each amphibole. Analyses believed to represent most closely the primary amphibole compositions gave atomic proportions on the basis of 23 oxygens per formula unit as follows: for primitive cummingtonite (Na_0.02Ca_0.21 ^– Mn_0.06Fe²⁺ _2.28Mg_4.12Al_0.28) (Al_0.17Si_7.83), for hornblende (Na_0.35Ca_1.56Mn_0.02Fe_1.71Mg_2.85Al_0.92) (Al_1.37Si_6.63), and for anthophyllite (Na_0.10Ca_0.06Mn_0.06Fe_2.25Mg_4.11Al_0.47) (Al_0.47Si_7.53). The reflections violating C-symmetry, on X-ray single crystal photographs of the primitive cummingtonite, are weak and diffuse, and suggest a partial inversion from a C-centered to a primitive clinoamphibole. Single crystal photographs of the anthophyllite show split reflections indicating it is an intergrowth of about 80% anthophyllite and about 20% gedrite which differ in their b crystallographic dimensions. Split reflections are characteristic of all analyzed orthorhombic amphiboles so far examined from Massachusetts and New Hampshire except the most aluminous gedrites, and the relative intensity of the gedrite reflections is roughly proportional to the degree of Na and Al substitution. Thin sections of a few of these anthophyllite specimens show lamellae parallel to (010) that are just resolved with a high power objective.Publication approved by the Director, U.S. Geological Survey.     

Enhanced data and methods for improving open and free global population grids: putting ‘leaving no one behind’ into practice

ABSTRACT

Data on global population distribution are a strategic resource currently in high demand in an age of new Development Agendas that call for universal inclusiveness of people. However, quality, detail, and age of census data varies significantly by country and suffers from shortcomings that propagate to derived population grids and their applications. In this work, the improved capabilities of recent remote sensing-derived global settlement data to detect and mitigate major discrepancies with census data is explored. Open layers mapping built-up presence were used to revise census units deemed as ‘unpopulated’ and to harmonize population distribution along coastlines. Automated procedures to detect and mitigate these anomalies, while minimizing changes to census geometry, preserving the regional distribution of population, and the overall counts were developed, tested, and applied. The two procedures employed for the detection of deficiencies in global census data obtained high rates of true positives, after verification and validation. Results also show that the targeted anomalies were significantly mitigated and are encouraging for further uses of free and open geospatial data derived from remote sensing in complementing and improving conventional sources of fundamental population statistics.     

The Mars oxidant experiment (MOx) for Mars '96

The MOx instrument was developed to characterize the reactive nature of the martian soil. The objectives of MOx were: (1) to measure the rate of degradation of organics in the martian environment; (2) to determine if the reactions seen by the Viking biology experiments were caused by a soil oxidant and measure the reactivity of the soil and atmosphere: (3) to monitor the degradation, when exposed to the martian environment, of materials of potential use in future missions; and, finally, (4) to develop technologies and approaches that can be part of future soil analysis instrumentation. The basic approach taken in the MOx instrument was to place a variety of materials composed as thin films in contact with the soil and monitor the physical and chemical changes that result. The optical reflectance of the thin films was the primary sensing-mode. Thin films of organic materials, metals, and semiconductors were prepared. Laboratory simulations demonstrated the response of thin films to active oxidants.     

A Multiple Flare Scenario where the Classic Long-Duration Flare Was Not the Source of a CME

A series of flares (GOES class M, M and C) and a CME were observed in close succession on 20 January 2004 in NOAA 10540. Radio observations, which took the form of types II, III and N bursts, were associated with these events. We use the combined observations from TRACE, EIT, Hα images from Kwasan, MDI magnetograms and GOES to understand the complex development of this event. Contrary to a standard interpretation, we conclude that the first two impulsive flares are part of the CME launch process while the following long-duration event flare represents simply the recovery phase. Observations show that the flare ribbons not only separate but also shift along the magnetic inversion line so that magnetic reconnection progresses stepwise to neighboring flux tubes. We conclude that “tether cutting” reconnection in the sheared arcade progressively transforms it to a twisted flux tube, which becomes unstable, leading to a CME. We interpret the third flare, a long-duration event, as a combination of the classical two-ribbon flare with the relaxation process following forced reconnection between the expanding CME structure and neighboring magnetic fields. Electronic Supplementary Material  The online version of this article () contains supplementary material, which is available to authorized users.     

Energetic Particle Acceleration and Propagation in Strong CME-Less Flares

Flares and coronal mass ejections (CMEs) contribute to the acceleration and propagation of solar energetic particles (SEP) detected in the interplanetary space, but the exact roles of these phenomena are yet to be understood. We examine two types of energetic particle tracers related with 15 CME-less flares that emit bright soft X-ray bursts (GOES X class): radio emission of flare-accelerated electrons and in situ measurements of energetic electrons and protons near 1 AU. The CME-less flares are found to be vigorous accelerators of microwave-emitting electrons, which remain confined in low coronal structures. This is shown by unusually steep low-frequency microwave spectra and by lack of radio emission from the middle and high corona, including dm?–?m wave type IV continua and metre-to-hectometre type III bursts. The confinement of the particles accelerated in CME-less flares agrees with the magnetic field configuration of these events inferred by others. Two events produced isolated metric type II bursts revealing coronal shock waves. None of the seven flares in the western hemisphere was followed by enhanced particle fluxes in the GOES detectors, but one, which was accompanied by a type II burst, caused a weak SEP event detected at SoHO and ACE. Three of the CME-less flares were followed within some hours by SEP-associated flares from the same active region. These SEP-producing events were clearly distinct from the CME-less ones by their association with fast and broad CMEs, dm?–?m wave radio emission, and intense DH type III bursts. We conclude that radio emission at decimetre and longer waves is a reliable indication that flare-accelerated particles have access to the high corona and interplanetary space. The absence of such emission can be used as a signal that no SEP event is to be expected despite the occurrence of a strong soft X-ray burst.     

Recent past and future patterns of the Etesian winds based on regional scale climate model simulations

The aim of this work is to investigate the recent past and future patterns of the Etesian winds, one of the most persistent localized wind systems in the world, which dominates the wind regime during warm period over the Aegean Sea and eastern Mediterranean. An objective classification method, the Two Step Cluster Analysis (TSCA), is applied on daily data from regional climate model simulations carried out with RegCM3 for the recent past (1961–1990) and future periods (2021–2050 and 2071–2100) constrained at lateral boundaries either by ERA-40 reanalysis fields or the global circulation model (GCM) ECHAM5. Three distinct Etesian patterns are identified by TSCA with the location and strength of the anticyclonic action center dominating the differences among the patterns. In case of the first Etesian pattern there is a ridge located over western and central Europe while for the other two Etesian patterns the location of the ridge moves eastward indicating a strong anticyclonic center over the Balkans. The horizontal and vertical spatial structure of geopotential height and the vertical velocity indicates that in all three Etesian patterns the anticyclonic action center over central Europe or Balkan Peninsula cannot be considered as an extension of the Azores high. The future projections for the late 21st century under SRES A1B scenario indicate a strengthening of the Etesian winds associated with the strengthening of the anticyclonic action center, and the deepening of Asian thermal Low over eastern Mediterranean. Furthermore the future projections indicate a weakening of the subsidence over eastern Mediterranean which is rather controlled by the deepening of the south Asian thermal Low in line with the projected in future weakening of South Asian monsoon and Hadley cell circulations.     

Oceanic origin of southeast tropical Atlantic biases

Most coupled general circulation models suffer from a prominent warm sea surface temperature bias in the southeast tropical Atlantic Ocean off the coast of Africa. The origin of the bias is not understood and remains highly controversial. Previous studies suggest that the origin of the bias stems from systematic errors of atmospheric models in simulating surface heat flux and coastal wind, or poorly simulated coastal upwelling. In this study, we show, using different reanalysis and observational data sets combined with a set of eddy-resolving regional ocean model simulations, that systematic errors in ocean models also make a significant contribution to the bias problem. In particular (1) the strong warm bias at the Angola-Benguela front that is maintained by the local wind and the convergence of Angola and Benguela Currents is caused by an overshooting of the Angola Current in ocean models and (2) the alongshore warm bias to the south of the front is caused by ocean model deficiencies in simulating the sharp thermocline along the Angola coast, which is linked to biases in the equatorial thermocline, and the complex circulation system within the Benguela upwelling zone.     

Hydrochemistry and hydrogen sulfide generating processes in the Malm aquifer,Bavarian Molasse Basin,Germany

Knowledge about the hydrochemical conditions of deep groundwater is crucial for the design and operation of geothermal facilities. In this study, the hydrochemical heterogeneity of the groundwaters in the Malm aquifer, Germany, is assessed, and reasons for the extraordinarily high H₂S concentrations in the central part of the Bavarian Molasse Basin are proposed. Samples were taken at 16 sites, for a total of 37 individual wells, to analyze cations, anions, gas loading and composition. The hydrochemical characteristics of the Malm groundwater in the center of the Molasse Basin are rather heterogeneous. Although the groundwater in the central basin is dominated by meteoric waters, there is a significant infiltration of saline water from higher strata. Care has to be taken in the interpretation of data from geothermal sites, as effects of chemical stimulation of the boreholes may not be fully removed before the final analyses. The distribution of H₂S in the gas phase is correlated to the gas loading of the water which increases in the central basin. Temperatures, isotopic data and the sulfur mass balance indicate that H₂S in the central basin is related to thermochemical sulfate reduction (south of Munich) and bacterial sulfate reduction (north of Munich).     

The age of the Roter Kamm impact crater,Namibia: Constraints from 40Ar-39Ar,K-Ar,Rb-Sr,fission track,and 10Be-26Al studies

Abstract The well-preserved 2.5 km diameter Roter Kamm impact crater is located in the Namib desert in Namibia. The impact has occurred in Precambrian granitic and granodioritic orthogneisses of the 1200–900 Ma old Namaqualand Metamorphic Complex which were partly covered by Gariep metasediments; the granites are invaded by quartz veins and quartz-feldspar-pegmatites. Previous geological field evidence suggested a crater age of about 5–10 Ma. In order to constrain this age, we selected a set of basement rocks (granites, granodiorites) exposed at the crater rim and studied the Rb-Sr, K-Ar, ⁴⁰Ar-³⁹Ar, and ¹⁰Be-²⁶Al isotopic systems as well as apatite fission track ages of these samples. The Rb-Sr isotopic systematics confirm the derivation of these samples from the Namaqualand basement (age about 1.29 Ga), which underwent Damaran orogenesis at about 650 Ma. No basement rocks with Rb-Sr ages younger than about 410 Ma were identified. The K-Ar ages of pseudotachylite and melt breccia samples show that these samples are dominated by incompletely degassed fragments of basement rocks, with some retaining their original metamorphic ages of about 470 Ma. The apatite fission track ages range from 20–28 Ma, which may be interpreted as an extension of the 25 Ma Burdigalian peneplanation event, or as incomplete resetting of the apatite fission tracks during the impact event. The ¹⁰Be and ²⁶Al exposure age of a quartz sample isolated from a quartz-pegmatite was found to be 150 ka; it is likely that the exposure of the sample began after material covering it had been removed by erosion 150 ka ago. Two glassy fractions extracted from a rim granite were dated by ⁴⁰Ar-³⁹Ar analysis. One sample gives practically a plateau age of 3.7 ± 0.3 Ma, while the other gives a minimum age of 3.6 Ma. The best available age estimate for the Roter Kamm crater is therefore 3.7 ± 0.3 Ma.