Using lumped conceptual rainfall-runoff models to simulate daily isotope variability with fractionation in a nested mesoscale catchment

This paper presents 19 months of stable isotope (δ²H and δ¹⁸O) data to enhance understanding of water and solute transport at two spatial scales (2.3 km² and 122 km²) in the agricultural Lunan catchment, Scotland. Daily precipitation and stream isotope data, weekly lake and spring isotope data and monthly groundwater isotope data revealed important insights into flow pathways and mixing of water at both scales. In particular, a deeper groundwater flow path significantly contributes to total streamflow (25-50%). Upstream lake isotope dynamics, susceptible to evaporative fractionation, also appeared to have an important influence on the downstream isotope composition. This unique tracer data set facilitated the conceptualization of a lumped catchment-scale flow-tracer model. The incorporation of hydrological, mixing and fractionation processes based on these data improved simulations of the stream δ²H isotope response at the catchment outlet from 0.37 to 0.56 for the Nash-Sutcliffe statistic. The stable isotope data successfully aided model conceptualization and calibration in the quest for a simple water and solute transport model with improved representation of process dynamics.     

How important is it to integrate riverine suspended sediment chemical composition with depth? Clues from Amazon River depth-profiles

The vertical variability in mineralogical, chemical and isotopic compositions observed in large river suspended sediments calls for a depth-integration of this variability to accurately determine riverine geochemical fluxes. In this paper, we present a method to determine depth-integrated chemical particulate fluxes of large rivers, based on river sampling along depth-profiles, and applied to the Amazon Basin lowland tributaries. The suspended particulate matter (SPM) concentration data from depth-profiles is modeled for a number of individual grain size fractions using the Rouse model, which allows to predict the grain size distribution of suspended sediment throughout the whole river cross-section. Then, using (1) the relationship between grain size distribution and the Al/Si ratio (2) relationships between the Al/Si ratio and the chemical concentrations, the chemical composition of river sediment is predicted throughout the river cross-section, and integrated to yield the depth-integrated chemical particulate flux for a number of chemical elements (e.g. Si, Al, Fe, Na, REEs, …). For elements such as Al, Fe, REEs, Th, the depth-integrated flux is around twice as high as the one calculated from river surface sample characteristics. For Na and Si, the depth-integrated flux is three times higher than the “surface” estimate, due to the enrichment of albite and quartz at the bottom of the river. Depth-integrated ⁸⁷Sr/⁸⁶Sr composition of suspended sediment, also predictable using this method, differs by more than 10⁻³ from the surface sample composition.Finally, potential implications of depth-integrated estimates of Amazon sediment chemistry are explored. Depth-integration of particulate ⁸⁷Sr/⁸⁶Sr isotopic ratios is necessary for a reliable use of Sr isotopes as a provenance tracer. The concept of steady-state weathering of a large river basin is revisited using depth-integrated sediment composition. This analysis shows that, in the Amazon Basin river, the previously observed discrepancy between (1) weathering intensities of channel surface sediment and (2) silicate-derived dissolved fluxes is only slightly accounted for by the vertical variability of suspended sediment weathering intensities. This observation confirms that most large rivers basins are not eroding at steady-state.     

Texture and anisotropy analysis of Qusaiba shales

Scanning and transmission electron microscopy, synchrotron X‐ray diffraction, microtomography and ultrasonic velocity measurements were used to characterize microstructures and anisotropy of three deeply buried Qusaiba shales from the Rub’al‐Khali basin, Saudi Arabia. Kaolinite, illite‐smectite, illite‐mica and chlorite show strong preferred orientation with (001) pole figure maxima perpendicular to the bedding plane ranging from 2.4–6.8 multiples of a random distribution (m.r.d.). Quartz, feldspars and pyrite crystals have a random orientation distribution. Elastic properties of the polyphase aggregate are calculated by averaging the single crystal elastic properties over the orientation distribution, assuming a nonporous material. The average calculated bulk P‐wave velocities are 6.2 km/s (maximum) and 5.5 km/s (minimum), resulting in a P‐wave anisotropy of 12%. The calculated velocities are compared with those determined from ultrasonic velocity measurements on a similar sample. In the ultrasonic experiment, which measures the effects of the shale matrix as well as the effects of porosity, velocities are smaller (P‐wave maximum 5.3 km/s and minimum 4.1 km/s). The difference between calculated and measured velocities is attributed to the effects of anisotropic pore structure and to microfractures present in the sample, which have not been taken into account in the matrix averaging.     

Impact of recent climatic change on growth of low elevation eastern Mediterranean forest trees

Evidence is presented of how Pinus halepensis Miller from dry habitats at <300 m elevation of four Greek island regions have responded to climatic conditions of the last two centuries. We compared historical periods of low growth due to low precipitation with the recent period of significant precipitation decline. In all cases trees?? growth patterns across the twentieth century were consistent with trends in annual (rather than seasonal) precipitation, with lowest values in both precipitation and radial growth during the last two decades of the twentieth century, the worst conditions for tree growth in more than 200 years. The data are compared with trends across different vegetation belts of the northern Mediterranean basin. Drought related tree mortality in Greece in 2000 and 2007 coincided with the most severe fire outbreaks on record. IPCC WG I (2007) climate scenarios for the Mediterranean suggest a further decline in precipitation, particularly in the eastern regions. Should this occur, growth reduction in trees, tree mortality and damage from forest fires are likely to become more severe.     

Raman study of apatite amorphised with swift heavy ions under various irradiation conditions

Crystallographically oriented Durango fluorapatites were exposed to swift heavy ions (Xe, Ta, Au, U) at different irradiation conditions. Beam-induced sample modifications were investigated with respect to the effect of fluence (10⁹–10¹³ ions/cm²), electronic energy loss (18–27 keV/nm), and pressure (3.6–11.5 GPa) applied during irradiation. In situ high-pressure irradiation was performed in diamond anvil cells. Confocal Raman spectroscopy was used to trace the occurring changes in the crystal lattice. Fragmentation of the crystal specimen depends on the orientation and sample thickness and was found to scale with energy loss and fluence. The radiation damage for irradiation along the c-axis was found to be larger than for the 〈hk0〉 direction, independent of the confining pressure. Observations on samples irradiated at high pressures indicate a stabilising effect, leading to reduced amorphisation in comparison to the samples irradiated without pressure.     

Rock magnetic study of basic intrusions and massive sulphides in the Hercynian central Jebilets Massif (Occidental-Meseta), Morocco

This paper describes a multidisciplinary study approach (petrography and rock magnetism) conducted on samples collected from the study area to characterise the magnetic mineralogy and to determine if the magnetisation of both lithologies were induced or retain a remnant component. Petrophysical, mineralogical and geochemical analyses confirm bimodal aspects, particularly in basic rocks; the two magnetic modes depend essentially on the mineralogical and geochemical characteristics of the samples. The ultramafic rocks comprise a highly altered primary mineralogy with chromite and magnetite as magnetic phases. The second type is of mafic composition with a less altered primary mineralogy and essentially magnetite and/or (hemo-ilmenite) as a carrier of magnetic mineralisation. Sulphides are characterised by high concentrations of Cu, Zn and Pb. The mineralogy is composed mainly of pyrrhotite (85% to 90%), sphalerite, galena, chalcopyrite, arsenopyrite and, occasionally, stannite. Monocline pyrrhotite seems to be the magnetic carrier of magnetisation in both Draa Sfar and Koudiat Aïcha. However, we suspect a different amount of hexagonal pyrrhotite as the cause of different magnetic behaviour. Paleomagnetic and thermomagnetic analyses reveal different. The calculated characteristic direction of natural remnant magnetisation for sulphides was used to model the magnetic anomaly of Draa Sfar. The proposed model match the geological features concluded from geological mapping and boreholes. Results from this work can be very useful for any modelling processes of magnetic anomalies suspected due to a sulphide mineralisation in an area with poor outcrops and no presence of boreholes information or of any geological or geochemical data.     

Development of an instantaneous GNSS/MEMS attitude determination system

Global navigation satellite systems (GNSS) are well suited for attitude determination. The key to high-precision GNSS-attitude determination is the ambiguity resolution. In case of kinematic applications, the rapidity of this process is of particular importance. We present a new instantaneous attitude determination system for GNSS-challenged environments. The single-epoch ambiguity resolution is performed by the ambiguity function method aided by a micro-electro-mechanical system (MEMS), leading to success rates above 99 %. The GNSS/MEMS fusion is realized by the use of an extended Kalman filter. When the system is stationary, a state vector augmentation with a shaping filter reduces systematic effects in the GNSS-attitudes. By means of two field experiments, the system was tested successfully. Despite poor GNSS measurement conditions, it provided reliable and accurate results, with empirical standard deviations in the range of 0.03–0.1 deg for the yaw angle.     

Nye kandidater udgået fra Københavns Universitets Geografiske Institut

Danish Journal of Geography: 71–82, 1995.

This paper presents two mega events as tools in the strategic planning of the Copenhagen area. Due to growing inter-metropolitan competition, increasingly offensive and complex means are applied. This demands strong leadership, stable longterm planning and willingness to accept the costs in order to reach the objectives. Marketing versus strategic planning is discussed. The general position of Copenhagen in the European urban system gives perspective to a potential change on the South Scandinavian urban scene. New instruments of strategic planning in Greater Copenhagen are introduced. The competitive level of Copenhagen is analyzed in relation to Stockholm, Berlin and Hamburg. Two examples of mega events are discussed that represent typical elements in urban competition: cultural events and infrastructure improvements. 1) Copenhagen as ‘The cultural City of Europe’ in 1996 represents a temporary mega event. 2) The planned bridge between Copenhagen and the south Swedish city of Malmö, combined with Swedish entrance into EU, opens up for development of the first cross-national integrated large-city region outside the European centre. This is an example of a mega event which will alter the scene permanently. Both events are important issues used in developing a growth strategy for Greater Copenhagen. But neither the cultural city nor the bridge may by themselves guarantee any advantages. It depends upon the ability of local actors to develop and promote the quality of their city. The paper represents a continuation and elaboration on earlier papers, see Matthiessen (1990, 1992) and Andersen &; Jørgensen (1994).