Origin of light volatile hydrocarbon gases in mud volcano fluids, Gulf of Cadiz — Evidence for multiple sources and transport mechanisms in active sedimentary wedges

Widespread mud volcanism across the thick (≤ 14 km) seismically active sedimentary prism of the Gulf of Cadiz is driven by tectonic activity along extensive strike–slip faults and thrusts associated with the accommodation of the Africa–Eurasia convergence and building of the Arc of Gibraltar, respectively. An investigation of eleven active sites located on the Moroccan Margin and in deeper waters across the wedge showed that light volatile hydrocarbon gases vented at the mud volcanoes (MVs) have distinct, mainly thermogenic, origins. Gases of higher and lower thermal maturities are mixed at Ginsburg and Mercator MVs on the Moroccan Margin, probably because high maturity gases that are trapped beneath evaporite deposits are transported upwards at the MVs and mixed with shallower, less mature, thermogenic gases during migration. At all other sites except for the westernmost Porto MV, δ¹³C–CH₄ and δ²H–CH₄ values of ~ − 50‰ and − 200‰, respectively, suggest a common origin for methane; however, the ratio of CH₄/(C₂H₆ + C₃H₈) varies from ~ 10 to > 7000 between sites. Mixing of shallow biogenic and deep thermogenic gases cannot account for the observed compositions which instead result mainly from extensive migration of thermogenic gases in the deeply-buried sediments, possibly associated with biodegradation of C₂₊ homologues and secondary methane production at Captain Arutyunov and Carlos Ribeiro MVs. At the deep-water Bonjardim, Olenin and Carlos Ribeiro MVs, generation of C₂₊-enriched gases is probably promoted by high heat flux anomalies which have been measured in the western area of the wedge. At Porto MV, gases are highly enriched in CH₄ having δ¹³C–CH₄ ~ − 50‰, as at most sites, but markedly lower δ²H–CH₄ values < − 250‰, suggesting that it is not generated by thermal cracking of n-alkanes but rather that it has a deep Archaeal origin. The presence of petroleum-type hydrocarbons is consistent with a thermogenic origin, and at sites where CH₄ is predominant support the suggestion that gases have experienced extensive transport during which they mobilized oil from sediments ~ 2–4 km deep. These fluids then migrate into shallower, thermally immature muds, driving their mobilization and extrusion at the seafloor. At Porto MV, the limited presence of petroleum in mud breccia sediments further supports the hypothesis of a predominantly deep microbial origin of CH₄.     

Accuracy and sensitivity analysis for 54 models of computing hourly diffuse solar irradiation on clear sky

Fifty-four broadband models for computation of solar diffuse irradiation on horizontal surface were tested in Romania (South-Eastern Europe). The input data consist of surface meteorological data, column integrated data, and data derived from satellite measurements. The testing procedure is performed in 21 stages intended to provide information about the sensitivity of the models to various sets of input data. There is no model to be ranked “the best” for all sets of input data. However, some of the models performed better than others, in the sense that they were ranked among the best for most of the testing stages. The best models for solar diffuse radiation computation are, on equal footing, ASHRAE 2005 model (ASHRAE 2005) and King model (King and Buckius, Solar Energy 22:297–301, 1979). The second best model is MAC model (Davies, Bound Layer Meteor 9:33–52, 1975). Details about the performance of each model in the 21 testing stages are found in the Electronic Supplementary Material.     

Sub-Cm Subsidence Measurements With The Wide-Angle Airborne Laser Ranging System

The Wide-Angle Airborne Laser Ranging System (WA-ALRS) is aninstrument developed at IGN with the aim of measuring landsubsidence with sub-cm accuracy. The instrument provides rangemeasurements that are used to estimate the co-ordinates of aground-based network of cube-corner retroreflectors (CCRs).Millimeter accuracy on relative radial co-ordinates has beendemonstrated in a ground-based experiment and centimeter accuracyhas been obtained in a recent airborne experiment. The mainlimitation in the latter experiment came from the low link budgetat longer distances. In this paper we analyze the performanceexpected with two different detector modules (avalanchephotodiodes with amplifiers). Laboratory measurements are used tocharacterize detector parameters and estimate ranging accuracy.Numerical simulations predict a 2–3 mm accuracy in the verticalco-ordinate with these detectors combined to a 2-km aircraftaltitude, a 20 laser beam divergence, a 250-m CCR separation and 10³ measurements per CCR.     

Le magmatisme basique hercynien et post-hercynien du Système central espagnol : essai de caractérisation des sources mantelliques

Basic magmatism in central Spain occurred sporadically during a long period of ca. 140 Ma. The geochemical data on representative samples from the five igneous episodes show that different mantle reservoirs were tapped. Crustal involvement (via recycling in mantle sources or by hybridization at emplacement levels) was important in the basic magmas related to the Hercynian orogeny (Gb1 to Gb3 suites). Samples occurring as later dykes have signatures ranging from OIB-like values (Gb4 alkaline lamprophyres) to those of a formerly enriched subcontinental lithospheric mantle (tholeiites Gb5). To cite this article: C. Villaseca et al., C. R. Geoscience 336 (2004).     

The record of Miocene impacts in the Argentine Pampas

Abstract— Argentine Pampean sediments represent a nearly continuous record of deposition since the late Miocene (～10 Ma). Previous studies described five localized concentrations of vesicular impact glasses from the Holocene to late Pliocene. Two more occurrences from the late Miocene are reported here: one near Chasicó (CH) with an ⁴⁰Ar/³⁹Ar age of 9.24 ± 0.09 Ma, and the other near Bahía Blanca (BB) with an age of 5.28 ± 0.04 Ma. In contrast with andesitic and dacitic impact glasses from other localities in the Pampas, the CH and BB glasses are more mafic. They also exhibit higher degrees of melting with relatively few xenoycrysts but extensive quench crystals. In addition to evidence for extreme heating (>1700 °C), shock features are observed (e.g., planar deformation features [PDFs] and diaplectic quartz and feldspar) in impact glasses from both deposits. Geochemical analyses reveal unusually high levels of Ba (～7700 ppm) in some samples, which is consistent with an interpretation that these impacts excavated marine sequences known to be at depth. These two new impact glass occurrences raise to seven the number of late Cenozoic impacts for which there is evidence preserved in the Pampean sediments. This seemingly high number of significant impacts over a 10⁶ km² area in a time span of 10 Myr is consistent with the number of bolides larger than 100 m expected to enter the atmosphere but is contrary to calculated survival rates following atmospheric disruption. The Pampean record suggests, therefore, that either atmospheric entry models need to be reconsidered or that the Earth has received an enhanced flux of impactors during portions of the late Cenozoic. Evidence for the resulting collisions may be best preserved and revealed in rare dissected regions of continuous, low‐energy deposition such as the Pampas. Additionally, the rare earth element (REE) concentrations of the target sediments and impact melts associated with the Chasicó event resemble the HNa/K australites of similar age. This suggests the possibility that those enigmatic tektites could have originated as high‐angle, distal ejecta from an impact in Argentina, thereby accounting for their rarity and notable chemical and physical differences from other Australasian impact glasses.     

Experimental evidence of fast groundwater responses in a hillslope/floodplain area in the Black Forest Mountains,Germany

Analysis of water flow pathways from hillslopes to streams is essential for the optimal protection of water resources as well as for ecohydrological studies. This study addresses runoff generation processes at a hillslope and near‐stream shallow groundwater system in the Black Forest Mountains, southwestern Germany. The changing spatial and temporal flow patterns during differing hydrological situations were examined using a combined hydraulic and hydrochemical approach. Groundwater levels at 10 wells, discharge at a near‐stream saturated area, and several natural tracers (deuterium, dissolved silica, and major anions and cations) were observed at different locations during high and low flows. The importance of the groundwater component during flood formation was clearly demonstrated: its contribution was about 80% during a double peak flood event at the saturated area. In addition, a rapid change of the shallow groundwater levels was observed along two transects of groundwater wells in the floodplain. This led to an enhanced groundwater discharge into the saturated area located at the end of one study transect. The amount of groundwater additionally activated during the event was about 30% of total discharge recorded at the outlet of the saturated area. Two alternative hypotheses are discussed to explain this phenomenon: the establishment of locally confined conditions and the development of a pressure wave (hypothesis A), or the significant change of the three‐dimensional groundwater flow lines that caused a large increase of the groundwater catchment at the saturated area during the investigated event (hypothesis B). Even if the exact flow paths and mechanisms could not be clearly identified, the importance of rapid responding hillslope groundwater was undoubtedly demonstrated by a combination of tracer and hydrometric methods. Copyright © 2004 John Wiley & Sons, Ltd.     

Shocked rocks and impact glasses from the El'gygytgyn impact structure,Russia

Abstract— The El'gygytgyn impact structure is about 18 km in diameter and is located in the central part of Chukotka, arctic Russia. The crater was formed in volcanic rock strata of Cretaceous age, which include lava and tuffs of rhyolites, dacites, and andesites. A mid‐Pliocene age of the crater was previously determined by fission track (3.45 ± 0.15 Ma) and ⁴⁰Ar/³⁹Ar dating (3.58 ± 0.04 Ma). The ejecta layer around the crater is completely eroded. Shock‐metamorphosed volcanic rocks, impact melt rocks, and bomb‐shaped impact glasses occur in lacustrine terraces but have been redeposited after the impact event. Clasts of volcanic rocks, which range in composition from rhyolite to dacite, represent all stages of shock metamorphism, including selective melting and formation of homogeneous impact melt. Four stages of shocked volcanic rocks were identified: stage I (≤35 GPa; lava and tuff contain weakly to strongly shocked quartz and feldspar clasts with abundant PFs and PDFs; coesite and stishovite occur as well), stage II (35–45 GPa; quartz and feldspar are converted to diaplectic glass; coesite but no stishovite), stage III (45–55 GPa; partly melted volcanic rocks; common diaplectic quartz glass; feldspar is melted), and stage IV (>55 GPa; melt rocks and glasses). Two main types of impact melt rocks occur in the crater: 1) impact melt rocks and impact melt breccias (containing abundant fragments of shocked volcanic rocks) that were probably derived from (now eroded) impact melt flows on the crater walls, and 2) aerodynamically shaped impact melt glass “bombs” composed of homogeneous glass. The composition of the glasses is almost identical to that of rhyolites from the uppermost part of the target. Cobalt, Ni, and Ir abundances in the impact glasses and melt rocks are not or only slightly enriched compared to the volcanic target rocks; only the Cr abundances show a distinct enrichment, which points toward an achondritic projectile. However, the present data do not allow one to unambiguously identify a meteoritic component in the El'gygytgyn impact melt rocks.     

On some properties of prominence eruptions and the associated CMEs in solar cycle 23

This work includes a study of some properties such as speed, apparent width, acceleration and latitudes, etc. of all types of Prominence Eruptions (PEs) and the associated Coronal Mass Ejections (CMEs) observed during the period of 1997–2006 by Nobeyama Radioheliograph (NORH) and SOHO/LASCO covering the solar cycle 23. The average speed of prominences and associated CMEs are 51 km/sec and 559 km/sec, respectively. The average angular width is 32^° and 74^°, respectively. As expected the associated CMEs are relatively faster and wider than the prominences.     

Quantifying the social equity of carbon mitigation strategies

Many tools that are helpful for evaluating emissions mitigation measures, such as carbon abatement cost curves, focus exclusively on cost and emissions reduction potential without quantifying the direct and indirect impacts on stakeholders. The impacts of climate change will be the most severe and immediate for billions of poor people, especially for those whose livelihoods are based on agriculture and subsistence activities and are directly dependent on weather patterns. Thus, equity and vulnerability considerations must be central to GHG emissions reduction strategies. A case study of a carbon abatement cost curve for an electricity system in two Nicaraguan rural villages is presented and is complemented with assessments based on the poverty metrics of the poverty headcount, the Gini coefficient, and the Kuznets ratios. Although these metrics are relatively easy to calculate, the study provides a general indication as to how the social impacts of mitigation strategies on the poor (whether they are in rural or urban environments, developed or developing countries) can be revealed and highlights the inequalities that are embedded in them. Further work analysing how mitigation measures affect the various more detailed poverty indices, such as the Human Development, Gender Equality, or Multidimensional Poverty indices, is needed.