Size distribution of the Late Devonian ammonoid Prolobites: indication for possible mass spawning events

Worldwide, the ammonoid genus Prolobites is only known from a few localities, and from these fossil beds almost all of the specimens are adults as shown by the presence of a terminal growth stage. This is in marked contrast to the co-occurring ammonoid genera such as Sporadoceras, Prionoceras, and Platyclymenia. Size distribution of specimens of Prolobites from three studied localities show that, unlike in the co-occurring ammonoid species, most of the material belongs to adult individuals. The morphometric analysis of Prolobites delphinus (Sandberger & Sandberger 1851) demonstrates the intraspecific variability including variants with elliptical coiling and that dimorphism is not detectable. The Prolobites material shows close resemblance to spawning populations of Recent coleoids such as the squid Todarodes filippovae Adam 1975. Possible mass spawning events are discussed in the context of the size distribution and limited geographic range of Prolobites. Finally, the potential fecundity and brooding behaviour of Prolobites is hypothesized using the examples of post spawning egg care in Recent coleoids.     

Distribution and characteristics of marine habitats in a subpolar bay based on hydroacoustics and bed shear stress estimates—Potter Cove,King George Island,Antarctica

Marine habitats worldwide are increasingly pressurized by climate change, especially along the Antarctic Peninsula. Well-studied areas in front of rapidly retreating tidewater glaciers like Potter Cove are representative for similar coastal environments and, therefore, shed light on habitat formation and development on not only a local but also regional scale. The objective of this study was to provide insights into habitat distribution in Potter Cove, King George Island, Antarctica, and to evaluate the associated environmental processes. Furthermore, an assessment concerning the future development of the habitats is provided. To describe the seafloor habitats in Potter Cove, an acoustic seabed discrimination system (RoxAnn) was used in combination with underwater video images and sediment samples. Due to the absence of wave and current measurements in the study area, bed shear stress estimates served to delineate zones prone to sediment erosion. On the basis of the investigations, two habitat classes were identified in Potter Cove, namely soft-sediment and stone habitats that, besides influences from sediment supply and coastal morphology, are controlled by sediment erosion. A future expansion of the stone habitat is predicted if recent environmental change trends continue. Possible implications for the Potter Cove environment, and other coastal ecosystems under similar pressure, include changes in biomass and species composition.     

Can a Training Image Be a Substitute for a Random Field Model?

In most multiple-point simulation algorithms, all statistical features are provided by one or several training images (TI) that serve as a substitute for a random field model. However, because in practice the TI is always of finite size, the stochastic nature of multiple-point simulation is questionable. This issue is addressed by considering the case of a sequential simulation algorithm applied to a binary TI that is a genuine realization of an underlying random field. At each step, the algorithm uses templates containing the current target point as well as all previously simulated points. The simulation is validated by checking that all statistical features of the random field (supported by the simulation domain) are retrieved as an average over a large number of outcomes. The results are as follows. It is demonstrated that multiple-point simulation performs well whenever the TI is a complete (infinitely large) realization of a stationary, ergodic random field. As soon as the TI is restricted to a limited domain, the statistical features cannot be obtained exactly, but integral range techniques make it possible to predict how much the TI should be extended to approximate them up to a prespecified precision. Moreover, one can take advantage of extending the TI to reduce the number of disruptions in the execution of the algorithm, which arise when no conditioning template can be found in the TI.     

Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite

The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO₂. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.     

The age of the Roter Kamm impact crater,Namibia: Constraints from 40Ar-39Ar,K-Ar,Rb-Sr,fission track,and 10Be-26Al studies

Abstract The well-preserved 2.5 km diameter Roter Kamm impact crater is located in the Namib desert in Namibia. The impact has occurred in Precambrian granitic and granodioritic orthogneisses of the 1200–900 Ma old Namaqualand Metamorphic Complex which were partly covered by Gariep metasediments; the granites are invaded by quartz veins and quartz-feldspar-pegmatites. Previous geological field evidence suggested a crater age of about 5–10 Ma. In order to constrain this age, we selected a set of basement rocks (granites, granodiorites) exposed at the crater rim and studied the Rb-Sr, K-Ar, ⁴⁰Ar-³⁹Ar, and ¹⁰Be-²⁶Al isotopic systems as well as apatite fission track ages of these samples. The Rb-Sr isotopic systematics confirm the derivation of these samples from the Namaqualand basement (age about 1.29 Ga), which underwent Damaran orogenesis at about 650 Ma. No basement rocks with Rb-Sr ages younger than about 410 Ma were identified. The K-Ar ages of pseudotachylite and melt breccia samples show that these samples are dominated by incompletely degassed fragments of basement rocks, with some retaining their original metamorphic ages of about 470 Ma. The apatite fission track ages range from 20–28 Ma, which may be interpreted as an extension of the 25 Ma Burdigalian peneplanation event, or as incomplete resetting of the apatite fission tracks during the impact event. The ¹⁰Be and ²⁶Al exposure age of a quartz sample isolated from a quartz-pegmatite was found to be 150 ka; it is likely that the exposure of the sample began after material covering it had been removed by erosion 150 ka ago. Two glassy fractions extracted from a rim granite were dated by ⁴⁰Ar-³⁹Ar analysis. One sample gives practically a plateau age of 3.7 ± 0.3 Ma, while the other gives a minimum age of 3.6 Ma. The best available age estimate for the Roter Kamm crater is therefore 3.7 ± 0.3 Ma.     

High-pressure behaviour along the jadeite NaAlSi2O6–aegirine NaFeSi2O6 solid solution up to 10 GPa

The volume variation as a function of pressure along the jadeite–aegirine solid solution was determined at room temperature up to pressures between 6.5 and 9.7 GPa by single-crystal X-ray diffraction. The unit-cell volumes collected at room pressure for the different compositions indicate a slight deviation from linearity along the join. The pressure–volume data have been fitted using a third-order Birch-Murnaghan equation of state (BM3-EoS). The bulk modulus, K _T0, varies from 134.0(7) GPa for pure jadeite to 116.1(5) GPa for pure aegirine. Its evolution with composition along the join is not linear and can be described by the following second order polynomial:

Excess of bottom-released methane in an Arctic shelf sea polynya in winter

Latent heat polynyas are regions generating strong ice formation, convection and extensive water mass formation. Here we report on the effects of these processes on resuspension of sediments and subsequent methane release from the seafloor and on the resulting excess methane concentration in surface water on a polar shelf during winter. The study is based on measurements of concentration and δ¹³C values of methane, water temperature, salinity, light transmission and sea ice data collected in March 2003 in Storfjorden, southern Svalbard. In winter, strong and persistent northeasterly winds create polynyas in eastern Storfjorden and cause ice formation. The resulting brine-enriched water cascades from the Storfjordbanken into the central depression thereby enhancing the turbulence near the seafloor. A distinct benthic nepheloid layer was observed reflecting the resuspension of sediments by the cascading dense bottom water. High concentrations of ¹³C-depleted methane suggest submarine discharge of methane with the resuspended sediments. As the source of the submarine methane, we propose recent bacterial methanogenesis near the sediment surface because of extremely high accumulation rates of organic carbon in Storfjorden. Convective mixing transports newly released methane from the bottom to the sea surface. This eventually results in an excess concentration in surface water with respect to the atmospheric equilibrium, and a sea-air flux of methane during periods of open water. When a new ice cover is formed, methane becomes trapped in the water column and subsequently oxidized. Thus, the residual methane is strongly enriched in ¹³C in relation to the δ¹³_CCH4${\delta }^{13}{\mathrm{C}}_{{\mathrm{CH}}_4}$ signature of atmospheric methane. Our results show that latent heat polynyas may induce a direct pathway for biogases like methane from sediments to the atmosphere through coupling of biogeochemical and oceanographic processes. Extrapolating these processes to all Arctic ocean polynyas, we estimate a transfer of CH₄ between 0.005 and 0.02 Tg yr⁻¹. This is not a large contribution but the fluxes from the polynyas are 20–200 times larger than the ocean average and the methane evasion process in polynyas is certainly one that can be altered under climate change.     

Burying receivers for improved time‐lapse seismic repeatability: CO2CRC Otway field experiment

4D seismic is widely used to remotely monitor fluid movement in subsurface reservoirs. This technique is especially effective offshore where high survey repeatability can be achieved. It comes as no surprise that the first 4D seismic that successfully monitored the CO₂ sequestration process was recorded offshore in the Sleipner field, North Sea. In the case of land projects, poor repeatability of the land seismic data due to low S/N ratio often obscures the time‐lapse seismic signal. Hence for a successful on shore monitoring program improving seismic repeatability is essential. Stage 2 of the CO2CRC Otway project involves an injection of a small amount (around 15,000 tonnes) of CO₂/CH₄ gas mixture into a saline aquifer at a depth of approximately 1.5 km. Previous studies at this site showed that seismic repeatability is relatively low due to variations in weather conditions, near surface geology and farming activities. In order to improve time‐lapse seismic monitoring capabilities, a permanent receiver array can be utilised to improve signal to noise ratio and hence repeatability. A small‐scale trial of such an array was conducted at the Otway site in June 2012. A set of 25 geophones was installed in 3 m deep boreholes in parallel to the same number of surface geophones. In addition, four geophones were placed into boreholes of 1–12 m depth. In order to assess the gain in the signal‐to‐noise ratio and repeatability, both active and passive seismic surveys were carried out. The surveys were conducted in relatively poor weather conditions, with rain, strong wind and thunderstorms. With such an amplified background noise level, we found that the noise level for buried geophones is on average 20 dB lower compared to the surface geophones. The levels of repeatability for borehole geophones estimated around direct wave, reflected wave and ground roll are twice as high as for the surface geophones. Both borehole and surface geophones produce the best repeatability in the 30–90 Hz frequency range. The influence of burying depth on S/N ratio and repeatability shows that significant improvement in repeatability can be reached at a depth of 3 m. The level of repeatability remains relatively constant between 3 and 12 m depths.