Ammonium in aqueous fluids to 600 °C, 1.3 GPa: A spectroscopic study on the effects on fluid properties, silica solubility, and K-feldspar to muscovite reactions

The behavior of ammonium, NH₄⁺, in aqueous systems was studied based on Raman spectroscopic experiments to 600 °C and about 1.3 GPa. Spectra obtained at ambient conditions revealed a strong reduction of the dynamic three-dimensional network of water with addition of ammonium chloride, particularly at small solute concentrations. The differential scattering cross section of the ν₁-NH₄⁺ Raman band in these solutions was found to be similar to that of salammoniac.The Raman band of silica monomers at ∼780 cm⁻¹ was present in all spectra of the fluid at high temperatures in hydrothermal diamond-anvil cell experiments with H₂O ± NH₄Cl and quartz or the assemblage quartz + kyanite + K-feldspar ± muscovite/tobelite. However, these spectra indicated that dissolved silica is less polymerized in ammonium chloride solutions than in comparable experiments with water. Quantification based on the normalized integrated intensity of the H₄SiO₄⁰ band showed that the silica solubility in experiments with H₂O + NH₄Cl was significantly lower than that in equimolal NaCl solutions. This suggests that ammonium causes a stronger decrease in the activity of water in chloridic solutions than sodium.The Raman spectra of the fluid also showed that a significant fraction of ammonium was converted to ammonia, NH₃, in all experiments at temperatures above 300 °C. This indicates a shift towards acidic conditions for experiments without a buffering mineral assemblage. The estimated pH of the fluid was ∼2 at 600 °C, 0.26 GPa, 6.6 m initial NH₄Cl, based on the ratio of the integrated ν₁-NH₃ and ν₁-NH₄⁺ intensities and the HCl⁰ dissociation constant. The NH₃/NH₄⁺ ratio increased with temperature and decreased with pressure. This implies that more ammonium should be retained in K-bearing minerals coexisting with chloridic fluids upon high-P low-T metamorphism. At 500 °C, 0.73 GPa, ammonium partitions preferentially into the fluid, as constrained from infrared spectroscopy on the muscovite and from mass balance.The conversion of K-feldspar to muscovite proceeded much faster in experiments with NH₄Cl solutions than in comparable experiments with water. This is interpreted as being caused by enhancement of the rate-limiting alumina solubility, suggesting complexation of Al with NH₄. Nucleation and growth of mica at the expense of K-feldspar and NH₄⁺/K⁺ exchange between fluid and K-feldspar occurred simultaneously, but incorporation of NH₄⁺ into K-feldspar was distinctly faster than K-feldspar consumption.     

The age of the Saltpan impact crater,South Africa

Abstract— The 1.13-km-diameter Pretoria Saltpan impact crater is located about 40 km NNW of Pretoria, South Africa. The crater is situated in 2.05 Ga old Nebo granite of the Bushveld Complex that is locally intruded by about 1.3 Ga old volcanic rocks. In 1988, a borehole was drilled in the center of the crater. At depths >90 m, breccias were found that contained minerals with characteristic shock-metamorphic features, thus confirming the impact origin of the crater. Fragments of impact glass were recovered from the melt breccias and several hundred sub-millimeter-sized glass fragments were subjected to fission track analysis. The measurements were complicated by the inhomogeneous composition of the impact glasses, but analysis of a large number of tracks yielded an age of 220 ± 52 ka for the Saltpan crater.     

摄影测量与遥感之发展趋势和展望

0引言摄影测量与遥感的原理可定义为:确定物体表面反射或发射某特定波长的电磁辐射特性(如:能量、相位、极化、传播时间等),并由这些测量值中提取物体及其表面的几何特征(如位     

Derivation of planetary topography using multi-image shape-from-shading

In many cases, the derivation of high-resolution digital terrain models (DTMs) from planetary surfaces using conventional digital image matching is a problem. The matching methods need at least one stereo pair of images with sufficient texture. However, many space missions provide only a few stereo images and planetary surfaces often possess insufficient texture.This paper describes a method for the generation of high-resolution DTMs from planetary surfaces, which has the potential to overcome the described problem. The suggested method, developed by our group, is based on shape-from-shading using an arbitrary number of digital optical images, and is termed “multi-image shape-from-shading” (MI-SFS). The paper contains an explanation of the theory of MI-SFS, followed by a presentation of current results, which were obtained using images from NASA's lunar mission Clementine, and constitute the first practical application with our method using extraterrestrial imagery. The lunar surface is reconstructed under the assumption of different kinds of reflectance models (e.g. Lommel-Seeliger and Lambert). The represented results show that the derivation of a high-resolution DTM of real digital planetary images by means of MI-SFS is feasible.     

Establishing the link between the Chesapeake Bay impact structure and the North American tektite strewn field: The Sr‐Nd isotopic evidence

Abstract— The Chesapeake Bay impact structure, which is about 35 Ma old, has previously been proposed as the possible source crater of the North American tektites (NAT). Here we report major and trace element data as well as the first Sr‐Nd isotope data for drill core and outcrop samples of target lithologies, crater fill breccias, and post‐impact sediments of the Chesapeake Bay impact structure. The unconsolidated sediments, Cretaceous to middle Eocene in age, have ?_Sr^{t = 35.7 Ma} of +54 to +272, and ?_Nd^{t = 35.7 Ma} ranging from ?6.5 to ?10.8; one sample from the granitic basement with a T^Nd_CHUR model age of 1.36 Ga yielded an ?_Sr^{t = 35.7 Ma} of +188 and an ?_Nd^{t = 35.7 Ma} of ?5.7. The Exmore breccia (crater fill) can be explained as a mix of the measured target sediments and the granite, plus an as‐yet undetermined component. The post‐impact sediments of the Chickahominy formation have slightly higher T^Nd_CHUR model ages of about 1.55 Ga, indicating a contribution of some older materials. Newly analyzed bediasites have the following isotope parameters: +104 to +119 (?_Sr^{t = 35.7 Ma}), ?5.7 (?_Nd^{t = 35.7 Ma}), 0.47 Ga (T^Sr_UR), and 1.15 Ga (T^Nd_CHUR), which is in excellent agreement with previously published data for samples of the NAT strewn field. Target rocks with highly radiogenic Sr isotopic composition, as required for explaining the isotopic characteristics of Deep Sea Drilling Project (DSDP) site 612 tektites, were not among the analyzed sample suite. Based on the new isotope data, we exclude any relation between the NA tektites and the Popigai impact crater, although they have identical ages within 2s? errors. The Chesapeake Bay structure, however, is now clearly constrained as the source crater for the North American tektites, although the present data set obviously does not include all target lithologies that have contributed to the composition of the tektites.     

Asteroid impact effects on Snowball Earth

Several Snowball Earth periods, in which the Earth has been (almost) totally glaciated, are known from Earth history. Neither the trigger for the initiation, nor the reason for the ending of such phases, are well understood. Here we discuss some mechanical effects of the impact of asteroids 5–10 km in diameter on the Snowball Earth environment. An impact of this scale is the largest impact that is statistically predictable for 10–60 Myr time periods. The impact cratering itself (shock waves, impact crater formation) is not powerful enough to change the natural climate evolution path on Earth. However, the products of impact (mainly—water vapor) can be quickly distributed over a substantial part of the globe, influencing the global circulation (e.g., facilitating cloud formation). It is a question for future studies to confirm if such an event (which is possible statistically during this interval) may or may not have influenced the global climate of the Snowball Earth, and/or contributed to deglaciation.     

10Be content in clasts from fallout suevitic breccia in drill cores from the Bosumtwi impact crater,Ghana: Clues to preimpact target distribution

Rocks from drill cores LB‐07A (crater fill) and LB‐08A (central uplift) into the Bosumtwi impact crater, Ghana, were analyzed for the presence of the cosmogenic radionuclide ¹⁰Be. The aim of the study was to determine the extent to which target rocks of various depths were mixed during the formation of the crater‐filling breccia, and also to detect meteoric water infiltration within the impactite layer. ¹⁰Be abundances above background were found in two (out of 24) samples from the LB‐07A core, and in none of five samples from the LB‐08A core. After excluding other possible explanations for an elevated ¹⁰Be signal, we conclude that it is most probably due to a preimpact origin of those clasts from target rocks close to the surface. Our results suggest that in‐crater breccias were well mixed during the impact cratering process. In addition, the lack of a ¹⁰Be signal within the rocks located very close to the lake sediment–impactite boundary suggests that infiltration of meteoric water below the postimpact crater floor was limited. This may suggest that the infiltration of the meteoric water within the crater takes place not through the aerial pore‐space, but rather through a localized system of fractures.     

Heating rate profiles in galaxy clusters

In recent years, evidence has accumulated suggesting that the gas in galaxy clusters is heated by non-gravitational processes. Here, we calculate the heating rates required to maintain a physically motivated mass flow rate, in a sample of seven galaxy clusters. We employ the spectroscopic mass deposition rates as an observational input along with temperature and density data for each cluster. On energetic grounds, we find that thermal conduction could provide the necessary heating for A2199, Perseus, A1795 and A478. However, the suppression factor of the classical Spitzer value is a different function of radius for each cluster. Based on the observations of plasma bubbles, we also calculate the duty cycles for each active galactic nucleus (AGN), in the absence of thermal conduction, which can provide the required energy input. With the exception of Hydra-A, it appears that each of the other AGNs in our sample requires duty cycles of roughly 10⁶–10⁷ yr to provide their steady-state heating requirements. If these duty cycles are unrealistic, this may imply that many galaxy clusters must be heated by very powerful Hydra-A type events interspersed between more frequent smaller scale outbursts. The suppression factors for the thermal conductivity required for combined heating by AGN and thermal conduction are generally acceptable. However, these suppression factors still require 'fine-tuning' of the thermal conductivity as a function of radius. As a consequence of this work, we present the AGN duty cycle as a cooling flow diagnostic.     

Proton Irradiation of Centaur,Kuiper Belt,and Oort Cloud Objects at Plasma to Cosmic Ray Energy

Times for accumulation of chemically significant dosages on icy surfaces of Centaur, Kuiper Belt, and Oort Cloud objects from plasma and energetic ions depend on irradiation position within or outside the heliosphere. Principal irradiation components include solar wind plasma ions, pickup ions from solar UV ionization of interstellar neutral gas, energetic ions accelerated by solar and interplanetary shocks, including the putative solar wind termination shock, and galactic cosmic ray ions from the Local Interstellar Medium (LISM). We present model flux spectra derived from spacecraft data and models for eV to GeV protons at 40 AU, a termination shock position at 85 AU, and in the LISM. Times in years to accumulate dosages ～100 eV per molecule are computed from the spectra as functions of sensible surface depth less than one centimeter at unit density.The collisional resurfacing model of Luu and Jewitt is reconsidered in thecontext of depth-dependent dosage rates from plasma, suprathermal,and higher energy protons, and global exposure, by micrometeoroiddust grain impacts, of moderately irradiated red material below athin crust of heavily irradiated neutral material. This material should be more visible on dynamically `cold’ objects in the ～40 AU region.